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arXiv · 2602.11397

Vibrational Quantum-State-Controlled Reactivity in the O2+ + C3H4 Reaction

C. Zagorec-Marks·G. S. Kocheril·T. Kieft·O. A. Krohn·C. Martí·T. P. Softley·J. Zádor·H. J. Lewandowski
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Abstract

Quantum-state-controlled reactivity is a long-standing goal in the field of physical chemistry. In this work, we explore the vibrational-state-dependent behavior of the ion-molecule reaction between O2+ in distinct vibrational states and two isomers of C3H4, allene (H2C3H2) and propyne (H3C3H). While most products are formed regardless of the vibrational state of O2+, the branching ratios are influenced by vibrational excitation, and a new product, C2O+, appears exclusively in the excited-state reactions. This selective formation of C2O+ demonstrates that vibrational excitation can effectively activate a reaction pathway, providing direct evidence of quantum-state control in reactivity. These results represent an important step towards the goal of quantum-state-controlled chemistry in molecular systems.

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C. Zagorec-Marks, G. S. Kocheril, T. Kieft, O. A. Krohn, C. Martí, T. P. Softley, J. Zádor, H. J. Lewandowski. 2026-02-11. Vibrational Quantum-State-Controlled Reactivity in the O2+ + C3H4 Reaction. https://arxiv.org/abs/2602.11397

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