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arXiv · 2604.19758

ThermoQA: A Three-Tier Benchmark for Evaluating Thermodynamic Reasoning in Large Language Models

Kemal Düzkar
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Abstract

We present ThermoQA, a benchmark of 293 open-ended engineering thermodynamics problems in three tiers: property lookups (110 Q), component analysis (101 Q), and full cycle analysis (82 Q). Ground truth is computed programmatically from CoolProp 7.2.0, covering water, R-134a, and variable-cp air. Six frontier LLMs are evaluated across three independent runs each. The composite leaderboard is led by Claude Opus 4.6 (94.1%), GPT-5.4 (93.1%), and Gemini 3.1 Pro (92.5%). Cross-tier degradation ranges from 2.8 pp (Opus) to 32.5 pp (MiniMax), confirming that property memorization does not imply thermodynamic reasoning. Supercritical water, R-134a refrigerant, and combined-cycle gas turbine analysis serve as natural discriminators with 40-60 pp performance spreads. Multi-run sigma ranges from +/-0.1% to +/-2.5%, quantifying reasoning consistency as a distinct evaluation axis. Dataset and code are open-source at https://huggingface.co/datasets/olivenet/thermoqa

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Kemal Düzkar. 2026-03-25. ThermoQA: A Three-Tier Benchmark for Evaluating Thermodynamic Reasoning in Large Language Models. https://arxiv.org/abs/2604.19758

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