Composite Quantum Geometry and Semiclassical Dynamics

Abstract

We derive semiclassical equations of motion for general composite bound states in insulators and semiconductors, covering excitations such as excitons and trions. For neutral composites we find that a uniform external electric field does not couple to a Berry curvature term, contrary to the naive expectation from single-electron dynamics. Instead, a distinct quantum geometric quantity appears generically in the equations of motion. This quantity is the difference between inequivalent Berry connections that can be defined for the composite, generalising the concept of the quantum geometric dipole previously studied for excitons. In the case of charged composites such as trions, we find an additional Berry curvature contribution to the equations of motion. As we demonstrate, however, there is an infinite family of inequivalent composite Berry curvatures, and so care must be taken to make the correct choice that describes the physical dynamics. We explain how this choice should be made dependent on the definition of a spatial centre for the composite. We end by discussing composite dynamics that have no single-electron counterpart. We find that trions in magic-angle twisted bilayer graphene undergo a transverse drift under an applied electric field and that this is driven not only by the Berry curvature contribution but also by the quantum geometric dipole. The interplay of these two geometric contributions further imprints itself on the trion's internal dynamics, causing its dipole moment to oscillate in time.