Record nonlinear conversion efficiency in the production of high spectral purity vacuum ultraviolet laser at 148 nm

Abstract

Coherent vacuum-ultraviolet (VUV) lasers are indispensable for precision measurement, quantum optics, and materials science. Recent high-resolution spectroscopy of the Th-229 nuclear clock transition near 148 nm highlights the urgent demand for intense, narrow-linewidth VUV lasers for advancing metrology and testing fundamental physics. However, existing VUV generation schemes typically require enhancement cavities [C. Zhang et al., Opt. Lett. 47, 5591-5594 (2022)], atomic resonances [Q. Xiao et al., Nature 650, 852-856 (2026)], or random quasi-phase-matched nonlinear crystals [V. Lal et al., Optica 12, 1971-1974 (2025)]. Here, we demonstrate a VUV frequency comb via cascaded frequency doubling of a 2400 nm Cr:ZnS comb to its 16th harmonic in nonlinear crystals. The final stage employs a bulk-grown, spatially uniform quasi-phase matched (QPM) crystal developed by IPG, combining VUV transparency, high $\chi^2$ nonlinearity, and power scalability. Using this QPM crystal we generate a VUV frequency comb with 40 $\mu$W average power (1 nW per mode at 80 MHz mode spacing) with a conversion efficiency order of magnitude higher than other known methods. These results establish a scalable route to compact VUV sources via direct frequency doubling, opening a path toward a robust continuous-wave nuclear clock laser.