Scanless quantum Fourier-transform mid-infrared spectroscopy for solids and surface analysis

Abstract

Quantum infrared (IR) spectroscopy is a novel technique based on nonlinear interferometry and quantum sensing with undetected photons. In this approach, spectrally far-separated correlated photon pairs are used for detection and probing, respectively. Hence, the probing wavelength domain (mid-IR) is substantially different from the detection spectral range (near-IR), which enables shot-noise-limited and cost-effective sensing schemes attractive for applied metrology. In this paper, we implement and employ a custom-built scanless quantum Fourier-transform mid-IR (sQFTIR) microspectrometer for chemical characterization and analysis of solids and interfaces. The sQFTIR system employs spectral-domain acquisition, without the need to scan the optical delay. This results in enhanced sensitivity and short measurement times and therefore enables rapid spectral acquisitions in 100~ms spanning a spectral band from 3000 cm$^{-1}$ - 2400 cm$^{-1}$. The capabilities of our approach are demonstrated for hyperspectral mid-IR imaging of dried pharmaceuticals (insulin on a gold surface) and investigation of a security feature on a banknote. Furthermore, we demonstrate hyperspectral imaging and spectroscopy through a turbid ceramic medium.