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arXiv · 2610.10401

Interface Doping Mechanism of p-Type Conductivity in Mist-CVD-Grown LiGa5O8 Thin Films

Dong Su Yu·Shashu Tomar·Zixiu Huang·Kaitian Zhang·Sarker Md. Sadman·Vijay Gopal Thirupakuzi Vangipuram·Ye Lin·Walter R. L. Lambrecht·Roberto C. Myers·Hongping Zhao
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Abstract

LiGa5O8 is an ultrawide-bandgap oxide semiconductor that has recently been experimentally demonstrated to exhibit p-type conductivity; however, the origin of the observed p-type transport remains poorly understood. In this work, we investigate the origin of p-type conductivity by systematically comparing the electrical, compositional, and structural properties of mist chemical vapor deposition (mist-CVD) grown LiGa5O8 thin films exhibiting either p-type conductivity or insulating behavior under different growth conditions. The p-conductive films exhibit room-temperature hole concentrations on the order of 10^18 cm^-3. The emergence of p-type conductivity is found to be strongly correlated with the elemental composition of the films, with X-ray photoelectron spectroscopy (XPS) revealing a reduced Li/Ga ratio in the p-conductive films, indicative of a Li-deficient composition. Raman spectroscopy and X-ray diffraction (XRD) further reveal signatures of \b{eta}-Ga2O3 in the p-conductive films that are absent in the insulating films, demonstrating the formation of a secondary \b{eta}-Ga2O3 phase. Considering the reported type-II band alignment between LiGa5O8 and \b{eta}-Ga2O3, together with theoretically predicted acceptor levels associated Li vacancies (V_Li) in LiGa5O8, the formation of mixed LiGa5O8/\b{eta}-Ga2O3 phases is proposed to facilitate electron transfer from the \b{eta}-Ga2O3 valence band to acceptor states in LiGa5O8, thereby promoting hole accumulation and p-type conductivity.

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Dong Su Yu, Shashu Tomar, Zixiu Huang, Kaitian Zhang, Sarker Md. Sadman, Vijay Gopal Thirupakuzi Vangipuram, Ye Lin, Walter R. L. Lambrecht, Roberto C. Myers, Hongping Zhao. 2026-10-07. Interface Doping Mechanism of p-Type Conductivity in Mist-CVD-Grown LiGa5O8 Thin Films. https://arxiv.org/abs/2610.10401

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