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arXiv · cond-mat/0103592

Micellization in the presence of polyelectrolyte

N. Lemke·Jeferson J. Arenzon·Yan Levin
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Abstract

We present a simple model to study micellization of amphiphiles condensed on a rodlike polyion. Although the mean field theory leads to a first order micellization transition for sufficiently strong hydrophobic interactions, the simulations show that no such thermodynamic phase transition exists. Instead, the correlations between the condensed amphiphiles can result in a structure formation very similar to micelles.

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N. Lemke, Jeferson J. Arenzon, Yan Levin. 2001-03-28. Micellization in the presence of polyelectrolyte. https://doi.org/10.1016/s0378-4371(01)00337-5

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