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Charge inversion in colloidal systems

Rene Messina·Christian Holm·Kurt Kremer
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Abstract

We investigate spherical macroions in the strong Coulomb coupling regime within the primitive model in salt-free environment. Molecular dynamics (MD) simulations are used to elucidate the effect of $discrete$ macroion charge distribution on charge inversion. A systematic comparison is made with the charge inversion obtained in the conventional continuous charge distribution. Furthermore the effect of multivalent counterions is reported.

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Rene Messina, Christian Holm, Kurt Kremer. 2002-01-08. Charge inversion in colloidal systems. https://doi.org/10.1016/s0010-4655(02)00288-6

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