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Contributions of steady heat conduction to the rate of chemical reaction

Kim Hyeon-Deuk·Hisao Hayakawa
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Abstract

We have derived the effect of steady heat flux on the rate of chemical reaction based on the line-of-centers model using the explicit velocity distribution function of the steady-state Boltzmann equation for hard-sphere molecules to second order. It is found that the second-order velocity distribution function plays an essential role for the calculation of it. We have also compared our result with those from the steady-state Bhatnagar-Gross-Krook(BGK) equation and information theory, and found no qualitative differences among them.

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Kim Hyeon-Deuk, Hisao Hayakawa. 2003-02-27. Contributions of steady heat conduction to the rate of chemical reaction. https://doi.org/10.1063/1.1764089

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