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Competition of percolation and phase separation in a fluid of adhesive hard spheres

Mark A. Miller·Daan Frenkel
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Abstract

Using a combination of Monte Carlo techniques, we locate the liquid--vapor critical point of adhesive hard spheres. We find that the critical point lies deep inside the gel region of the phase diagram. The (reduced) critical temperature and density are $τ_c=0.1133\pm0.0005$ and $ρ_c=0.508\pm0.01$. We compare these results with the available theoretical predictions. Using a finite-size scaling analysis, we verify that the critical behavior of the adhesive hard sphere model is consistent with that of the 3D Ising universality class.

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Mark A. Miller, Daan Frenkel. 2003-01-28. Competition of percolation and phase separation in a fluid of adhesive hard spheres. https://doi.org/10.1103/physrevlett.90.135702

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