SearcharxivSearch

arXiv · cond-mat/0304073

Generalized thermodynamics and kinetic equations: Boltzmann, Landau, Kramers and Smoluchowski

Abstract

We propose a formal extension of thermodynamics and kinetic theories to a larger class of entropy functionals. Kinetic equations associated to Boltzmann, Fermi, Bose and Tsallis entropies are recovered as a special case. This formalism first provides a unifying description of classical and quantum kinetic theories. On the other hand, a generalized thermodynamical framework is justified to describe complex systems exhibiting anomalous diffusion. Finally, a notion of generalized thermodynamics emerges in the context of the the violent relaxation of collisionless stellar systems and two-dimensional vortices due to the existence of Casimir invariants and incomplete relaxation. A thermodynamical analogy can also be developed to analyze the nonlinear dynamical stability of stationary solutions of the Vlasov and 2D Euler-Poisson systems. On general grounds, we suggest that generalized entropies arise due to the existence of ``hidden constraints'' that modify the form of entropy that we would naively expect. Generalized kinetic equations are therefore ``effective'' equations that are introduced heuristically to describe complex systems.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Pierre-Henri Chavanis. 2003-04-03. Generalized thermodynamics and kinetic equations: Boltzmann, Landau, Kramers and Smoluchowski. https://doi.org/10.1016/j.physa.2003.09.061

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

Universal sampling of spin systems across quenched disorder

Statistical physics extracts macroscopic laws by averaging over the many microscopic degrees of freedom of a system. Disordered systems demand a second and far harder average, one over the quenched randomness itself. The classic analytical routes, the replica and cavity methods, become uncontrolled outside mean-field or tree-like limits, and conventional numerical algorithms like parallel tempering require expensive, independent equilibration for every disorder realization. In this work, we introduce a universal neural variational framework that amortizes inference across the disorder ensemble, eliminating both the need for per-instance Markov chain equilibration and the cost of retraining instance-specific variational ansatzes. Built on an encoder-decoder Transformer architecture, after training once, it produces an explicit approximation to the Boltzmann distribution given previously unseen disorder realizations without further optimization. We validate this framework on 2D Edwards-Anderson models, and apply it to the random-bond Ising model, successfully capturing the Binder cumulant crossings near the Nishimori multicritical point. These results shift the object of variational inference from the single instance to the disorder ensemble, opening a route to frustrated many-body systems where instance-by-instance computation is prohibitive.

cond-mat.stat-mech

Information-Theoretic Characterization of Macroscopic Chaos Emerging from the Chemical Master Equation

Open chemical reaction networks exhibit stochastic concentration dynamics at finite system sizes, whereas their macroscopic limit is governed by deterministic rate equations that can display chaos. In this Letter, we show theoretically that a rate of information loss constructed from two-time mutual information recovers the Kolmogorov-Sinai entropy in the deterministic limit. We verify this result through numerical simulations of a Markov jump process for a three-species system involving seven reactions.

cond-mat.stat-mech

Orientational order on non-orientable domains

We study the statistical properties of passive and active many-body systems with orientational degrees of freedom on non-orientable domains. By rephrasing topological constraints as non-local symmetry relations on an orientable double-cover, we show that non-orientability eliminates global rotational soft modes without acting like an external field. In a passive XY model, this results in topological caging, where orientational fluctuations that exhibit conventional diffusive behavior on a torus saturate on a Klein bottle to a finite value that we compute exactly in the thermodynamic limit. In models of active self-propelled particles with orientational degrees of freedom, topological caging persists despite continuously changing interaction neighborhoods. In an active Ising spin model, non-orientability enforces the coexistence of ordered anti-parallel domains with vanishing global polar order, a state that is absent on orientable domains.

cond-mat.stat-mech