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Rules for transition rates in nonequilibrium steady states

R. M. L. Evans
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Abstract

Just as transition rates in a canonical ensemble must respect the principle of detailed balance, constraints exist on transition rates in driven steady states. I derive those constraints, by maximum information-entropy inference, and apply them to the steady states of driven diffusion and a sheared lattice fluid. The resulting ensemble can potentially explain nonequilibrium phase behaviour and, for steady shear, gives rise to stress-mediated long-range interactions.

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R. M. L. Evans. 2004-02-20. Rules for transition rates in nonequilibrium steady states. https://doi.org/10.1103/physrevlett.92.150601

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