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Specific Heat of the beta-Pyrochlore Oxide Superconductors CsOs2O6 and RbOs2O6

Zenji Hiroi·Shigeki Yonezawa·Takaki Muramatsu·Jun-Ichi Yamaura·Yuji Muraoka
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Abstract

Two beta-pyrochlore oxide superconductors, CsOs2O6 and RbOs2O6, are studied thermodynamically by measuring specific heat on polycrystalline samples. It is found that a Sommerfeld coefficient ? is nearly equal, 20 mJ/K2 mol Os, in the two oxides with different superconducting transition temperatures; Tc = 3.3 K and 6.3 K, respectively. This suggests that the density of states at the Fermi level is not a crucial parameter to determine the Tc of the beta-pyrochlore oxide superconductors, which is incompatible with the general expectation for a conventional BCS-type superconductor. Anomalous lattice contributions to specific heat at low temperature are also reported, which may come from nearly localized phonon modes associated with the rattling of the alkali metal ions weakly bound in an oversized cage formed by OsO6 octahedra.

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Zenji Hiroi, Shigeki Yonezawa, Takaki Muramatsu, Jun-Ichi Yamaura, Yuji Muraoka. 2005-07-29. Specific Heat of the beta-Pyrochlore Oxide Superconductors CsOs2O6 and RbOs2O6. https://doi.org/10.1143/jpsj.74.1255

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