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Conformational Transitions of Non-Grafted Polymers Near an Adsorbing Substrate

Michael Bachmann·Wolfhard Janke
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Abstract

We have performed multicanonical chain-growth simulations of a polymer interacting with an adsorbing surface. The polymer, which is not explicitly anchored at the surface, experiences a hierarchy of phase transitions between conformations binding and non-binding with the substrate. We discuss the phase diagram in the temperature-solubility plane and highlight the transition ``path'' through the free-energy landscape.

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Michael Bachmann, Wolfhard Janke. 2005-02-04. Conformational Transitions of Non-Grafted Polymers Near an Adsorbing Substrate. https://doi.org/10.1103/physrevlett.95.058102

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