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Adsorption of a binary mixture of monomers with nearest-neighbour cooperative effects

A. Prados·J. J. Brey
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Abstract

A model for the adsorption of a binary mixture on a one-dimensional infinite lattice with nearest neighbour cooperative effects is considered. The particles of the two species are both monomers but differ in the repulsive interaction experienced by them when trying to adsorb. An exact expression for the coverage of the lattice is derived. In the jamming limit, it is a monotonic function of the ratio between the attempt frequencies of the two species, varying between the values corresponding to each of the two single species. This is in contrast with the results obtained in other models for the adsorption of particles of different sizes. The structure of the jamming state is also investigated.

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A. Prados, J. J. Brey. 2005-06-28. Adsorption of a binary mixture of monomers with nearest-neighbour cooperative effects. https://doi.org/10.1088/0305-4470%2F38%2F32%2F001

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