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Indication of intrinsic room-temperature ferromagnetism in Ti1-xCoxO2-d thin film: An x-ray magnetic circular dichroism study

K. Mamiya·T. Koide·A. Fujimori·H. Tokano·H. Manaka·A. Tanaka·H. Toyosaki·T. Fukumura·M. Kawasaki
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Abstract

Soft x-ray magnetic circular dichroism (XMCD) measurements at the Co L2,3 edges of Co doped rutile TiO2 at room temperature have revealed clear multiplet features characteristic of ferromagnetic Co2+ ions coordinated by O2- ions, being in sharp contrast to the featureless XMCD spectrum of Co metal or metallic clusters. The absorption and XMCD spectra agree well with a full atomic-multiplet calculation for the Co2+ high-spin state in the D2h-symmetry crystal field at the Ti site in rutile TiO2. The results indicate that the ferromagnetism arises from the Co2+ ions substituting the Ti4+ ions.

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K. Mamiya, T. Koide, A. Fujimori, H. Tokano, H. Manaka, A. Tanaka, H. Toyosaki, T. Fukumura, M. Kawasaki. 2006-03-07. Indication of intrinsic room-temperature ferromagnetism in Ti1-xCoxO2-d thin film: An x-ray magnetic circular dichroism study. https://doi.org/10.1063/1.2236829

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