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Ginzburg-Landau theory of the liquid-solid interface and nucleation for hard-spheres

James F. Lutsko
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Abstract

The Ginzburg-Landau free energy functional for hard-spheres is constructed using the Fundamental Measure Theory approach to Density Functional Theory as a starting point. The functional is used to study the liquid-fcc solid planer interface and the properties of small solid clusters nucleating within a liquid. The surface tension for planer interfaces agrees well with simulation and it is found that the properties of the solid clusters are consistent with classical nucleation theory.

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BibTeXRIS

James F. Lutsko. 2006-03-27. Ginzburg-Landau theory of the liquid-solid interface and nucleation for hard-spheres. https://doi.org/10.1103/physreve.74.021603

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