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Spin singlet pairing in the superconducting state of NaxCoO2\cdot1.3H2O: evidence from a ^{59}Co Knight shift in a single crystal

Guo-qing Zheng·Kazuaki Matano·D. P. Chen·C. T. Lin
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Abstract

We report a ^{59}Co Knight shift measurement in a single crystal of the cobalt oxide superconductor Na_{x}CoO_2\cdot1.3H_2O (T_c=4.25 K). We find that the shift due to the spin susceptibility, K^s, is substantially large and anisotropic, with the spin shift along the a-axis K^s_a being two times that along the c-axis K^s_c. The shift decreases with decreasing temperature (T) down to T\sim100 K, then becomes a constant until superconductivity sets in. Both K^s_a and K^s_c decrease below T_c. Our results indicate unambiguously that the electron pairing in the superconducting state is in the spin singlet form.

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Guo-qing Zheng, Kazuaki Matano, D. P. Chen, C. T. Lin. 2006-05-09. Spin singlet pairing in the superconducting state of NaxCoO2\cdot1.3H2O: evidence from a ^{59}Co Knight shift in a single crystal. https://doi.org/10.1103/physrevb.73.180503

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