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X-ray photoelectron 3s spectra of transition metal oxides

V. R. Galakhov·S. Uhlenbrock·S. Bartkowski·A. V. Postnikov·M. Neumann·L. D. Finkelstein·E. Z. Kurmaev·A. A. Samokhvalov·L. I. Leonyuk
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Abstract

We present metal 3s x-ray photoelectron spectra of different transition metal oxides. The values of the 3s exchange splitting for the 3d metal oxides are given as a function of the 3d electron number in the ground state. The spectra were analysed using the simple two-configuration model of the interatomic configuration mixing. The change of the 3s spectra is ascribed to the change of the charge-transfer energy.

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V. R. Galakhov, S. Uhlenbrock, S. Bartkowski, A. V. Postnikov, M. Neumann, L. D. Finkelstein, E. Z. Kurmaev, A. A. Samokhvalov, L. I. Leonyuk. 1999-03-23. X-ray photoelectron 3s spectra of transition metal oxides. https://arxiv.org/abs/cond-mat/9903354

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