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Threshold and high-frequency behavior of dipole-bound anion photodetachment

Vladislav E. Chernov·Boris A. Zon
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Abstract

An explicit analytic description is given for dipole-bound anion (DBA) as an excess electron bound to the molecular neutral due to its dipole moment. The calculated DBA photodetachment cross-section displays $\proptoω^{-2}$ behavior for large $ω$, in complete accordance with the experimental data [Bailey \textit{et al.}, J. Chem. Phys \textbf{104}, 6976 (1996)]. At the threshold the photodetachment cross-section displays the Gailitis--Damburg oscillations.

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Vladislav E. Chernov, Boris A. Zon. 2003-03-20. Threshold and high-frequency behavior of dipole-bound anion photodetachment. https://arxiv.org/abs/physics/0303081

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