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Boris A. Zon

Publications and source records attributed to Boris A. Zon.

3 recordsLinked to original sources

Nonlinear Model of non-Debye Relaxation

We present a simple nonlinear relaxation equation which contains the Debye equation as a particular case. The suggested relaxation equation results in power-law decay of fluctuations. This equation contains a parameter defining the frequency dependence of the dielectric permittivity similarly to the well-known one-parameter phenomenological equations of Cole-Cole, Davidson-Cole and Kohlrausch-Williams-Watts. Unlike these models, the obtained dielectric permittivity (i) obeys to the Kramers-Kronig relation; (ii) has proper behaviour at large frequency; (iii) its imaginary part, conductivity, shows a power-law frequency dependence σ~ ω^n where n<1 corresponds to empirical Jonscher's universal relaxation law while n>1 is also observed in several experiments. The nonlinear equation proposed may be useful in various fields of relaxation theory.

physics.chem-ph

Threshold and high-frequency behavior of dipole-bound anion photodetachment

An explicit analytic description is given for dipole-bound anion (DBA) as an excess electron bound to the molecular neutral due to its dipole moment. The calculated DBA photodetachment cross-section displays $\proptoω^{-2}$ behavior for large $ω$, in complete accordance with the experimental data [Bailey \textit{et al.}, J. Chem. Phys \textbf{104}, 6976 (1996)]. At the threshold the photodetachment cross-section displays the Gailitis--Damburg oscillations.

physics.chem-ph