arXiv subjects

A. Belloche

Publications and source records attributed to A. Belloche.

At least 55 records · Page 3Linked to original sources

arXiv2020

Angular momentum profiles of Class 0 protostellar envelopes

[abridged] Understanding how the infalling gas redistribute most of its initial angular momentum inherited from prestellar cores before reaching the stellar embryo is a key question. Disk formation has been naturally considered as a possible solution to this "angular momentum problem". However, how the initial angular momentum of protostellar cores is distributed and evolves during the main accretion phase and the beginning of disk formation has largely remained unconstrained up to now. In the framework of the IRAM CALYPSO survey, we used high dynamic range C$^{18}$O (2-1) and N$_2$H$^+$ (1-0) observations to quantify the distribution of specific angular momentum along the equatorial axis in a sample of 12 Class 0 protostellar envelopes from scales ~50 to 10000 au. The radial distributions of specific angular momentum in the CALYPSO sample suggest two distinct regimes within protostellar envelopes: the specific angular momentum decreases as $j \propto r^{1.6 \pm 0.2}$ down to ~1600 au and then tends to become relatively constant around 6 $\times$ 10$^{-4}$ km s$^{-1}$ pc down to ~50 au. The values of specific angular momentum measured in the inner Class 0 envelopes, namely that of the material directly involved in the star formation process ($<$1600 au), is on the same order of magnitude as what is inferred in small T-Tauri disks. Thus, disk formation appears to be a direct consequence of angular momentum conservation during the collapse. Our analysis reveals a dispersion of the directions of velocity gradients at envelope scales $>$1600 au, suggesting that they may not be related to rotational motions of the envelopes. We conclude that the specific angular momentum observed at these scales could find its origin in core-forming motions (infall, turbulence) or trace an imprint of the initial conditions for the formation of protostellar cores.

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arXiv2020

Exploring molecular complexity with ALMA (EMoCA): Complex isocyanides in Sgr B2(N)

We used the EMoCA survey data to search for isocyanides in Sgr B2(N2) and their corresponding cyanide analogs. We then used the coupled three-phase chemical kinetics code MAGICKAL to simulate their chemistry. Several new species, and over 100 new reactions have been added to the network. In addition, a new single-stage simultaneous collapse/warm-up model has been implemented, thus eliminating the need for the previous two-stage models. A variable, visual extinction-dependent $ζ$ was also incorporated into the model and tested. We report the tentative detection of CH$_3$NC and HCCNC in Sgr B2(N2), which represents the first detection of both species in a hot core of Sgr B2. Our updated chemical models can reproduce most observed NC:CN ratios reasonably well depending on the physical parameters chosen. The model that performs best has an extinction-dependent cosmic-ray ionization rate that varies from ~2 $\times$ 10$^{-15}$ s$^{-1}$ at the edge of the cloud to ~1 $\times$ 10$^{-16}$ s$^{-1}$ in the center. Models with higher extinction-dependent $ζ$ than this model generally do not agree as well, nor do models with a constant $ζ$ greater than the canonical value of 1.3 $\times$ 10$^{-17}$ s$^{-1}$ throughout the source. Radiative transfer models are run using results of the best-fit chemical model. Column densities produced by the radiative transfer models are significantly lower than those determined observationally. Inaccuracy in the observationally determined density and temperature profiles is a possible explanation. Excitation temperatures are well reproduced for the true ``hot core'' molecules, but are more variable for other molecules such as HC$_3$N, for which fewer lines exist in ALMA Band 3.

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arXiv2020

Questioning the spatial origin of complex organic molecules in young protostars with the CALYPSO survey

Complex organic molecules (COMs) have been detected in a few Class 0 protostars but their origin is not well understood. Going beyond studies of individual objects, we want to investigate the origin of COMs in young protostars on a statistical basis. We use the CALYPSO survey performed with the IRAM PdBI to search for COMs at high angular resolution in a sample of 26 solar-type protostars, including 22 Class 0 and four Class I objects. Methanol is detected in 12 sources and tentatively in one source, which represents half of the sample. Eight sources (30%) have detections of at least three COMs. We find a strong chemical differentiation in multiple systems with five systems having one component with at least three COMs detected but the other component devoid of COM emission. The internal luminosity is found to be the source parameter impacting the most the COM chemical composition of the sources, while there is no obvious correlation between the detection of COM emission and that of a disk-like structure. A canonical hot-corino origin may explain the COM emission in four sources, an accretion-shock origin in two or possibly three sources, and an outflow origin in three sources. The CALYPSO sources with COM detections can be classified into three groups on the basis of the abundances of oxygen-bearing molecules, cyanides, and CHO-bearing molecules. These chemical groups correlate neither with the COM origin scenarii, nor with the evolutionary status of the sources if we take the ratio of envelope mass to internal luminosity as an evolutionary tracer. We find strong correlations between molecules that are a priori not related chemically (for instance methanol and methyl cyanide), implying that the existence of a correlation does not imply a chemical link. [abridged]

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arXiv2020

Searching for kinematic evidence of Keplerian disks around Class 0 protostars with CALYPSO

The formation of protoplanetary disks is not well understood. To understand how and when these disks are formed, it is crucial to characterize the kinematics of the youngest protostars at a high angular resolution. Here we study a sample of 16 Class 0 protostars to measure their rotation profile at scales from 50 to 500~au and search for Keplerian rotation. We used high-angular-resolution line observations obtained with the Plateau de Bure Interferometer as part of the CALYPSO large program. From $\mathrm{^{13}CO}$ ($J=2-1$), $\mathrm{C^{18}O}$ ($J=2-1$) and SO ($N_{j}=5_{6}-4_{5}$) moment maps, we find that seven sources show rotation about the jet axis at a few hundred au scales: SerpS-MM18, L1448-C, L1448-NB, L1527, NGC1333- IRAS2A, NGC1333-IRAS4B, and SVS13-B. We analyzed the kinematics of these sources in the $uv$ plane to derive the rotation profiles down to 50~au scales. We find evidence for Keplerian rotation in only two sources, L1527 and L1448-C. Overall, this suggests that Keplerian disks larger than 50 au are uncommon around Class 0 protostars. However, in some of the sources, the line emission could be optically thick and dominated by the envelope emission. Due to the optical thickness of these envelopes, some of the disks could have remained undetected in our observations.

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arXiv2019

The dynamically young outflow of the Class 0 protostar Cha-MMS1

On the basis of its low luminosity, its chemical composition, and the absence of a large-scale outflow, the dense core Cha-MMS1 located in the Chamaeleon I molecular cloud was proposed as a first hydrostatic core (FHSC) candidate a decade ago. Our goal is to test this hypothesis by searching for a slow, compact outflow driven by Cha-MMS1 that would match the predictions of MHD simulations for this short phase of star formation. We use the Atacama Large Millimetre/submillimetre Array (ALMA) to map Cha-MMS1 at high angular resolution in CO 3-2 and 13CO 3-2 as well as in continuum emission. We report the detection of a bipolar outflow emanating from the central core, along a (projected) direction roughly parallel to the filament in which Cha-MMS1 is embedded and perpendicular to the large-scale magnetic field. The morphology of the outflow indicates that its axis lies close to the plane of the sky. We measure velocities corrected for inclination of more than 90km/s which is clearly incompatible with the expected properties of a FHSC outflow. Several properties of the outflow are determined and compared to previous studies of Class 0 and Class I protostars. The outflow of Cha-MMS1 has a much smaller momentum force than the outflows of other Class 0 protostars. In addition, we find a dynamical age of 200-3000yr indicating that Cha-MMS1 might be one of the youngest ever observed Class 0 protostars. While the existence of the outflow suggests the presence of a disk, no disk is detected in continuum emission and we derive an upper limit of 55au to its radius. We conclude that Cha-MMS1 has already gone through the FHSC phase and is a young Class 0 protostar, but it has not brought its outflow to full power yet.

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arXiv2019

Rotational spectrum of isotopic methyl mercaptan, (13)CH3SH, in the laboratory and towards Sagittarius B2(N2)

Methyl mercaptan (CH3SH) is a known interstellar molecule with abundances high enough that the detection of some of its minor isotopologues is promising. The present study aims at providing accurate spectroscopic parameters for the (13)CH3SH isotopologue to facilitate its identification in the interstellar medium at millimetre and submillimetre wavelengths. Through careful analysis of recent CH3SH spectra from 49-510 GHz and 1.1-1.5 THz recorded at natural isotopic composition, extensive assignments were possible not only for the ground torsional state of (13)CH3SH, but also in the first and second excited states. The torsion-rotation spectrum displays complex structure due to the large-amplitude internal rotation of the (13)CH3 group, similar to the main and other minor isotopic species of methyl mercaptan. The assigned transition frequencies have been fitted to within experimental error with a 52-parameter model employing the RAM36 programme. With predictions based on this fit, (13)CH3SH was searched for in spectra from the Atacama Large Millimetre/submillimetre Array (ALMA) towards the Galactic centre source Sgr B2(N2). Several transitions were expected to be observable, but all of them turned out to be severely blended with emission from other species, which prevents us from identifying (13)CH3SH in this source.

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arXiv2019

SPARKS II.: Complex organic molecules in accretion shocks around a hot core precursor

Classical hot cores are rich in molecular emission, and they show a high abundance of complex organic molecules (COMs). The emergence of molecular complexity is poorly constrained in the early evolution of hot cores. Using the Atacama Large Millimeter Array we put observational constraints on the physical location of COMs in a high-mass protostellar envelope associated with the G328.2551-0.5321 clump. The protostar is single down to ~400au scales and we resolve the emission region of COMs. Using thermodynamic equilibrium modelling of the available 7.5 GHz bandwidth around ~345 GHz, we detect emission from 10 COMs, and identify a line of deuterated water (HDO). The most extended emission originates from methanol, methyl formate and formamide. Together with HDO, these molecules are found to be associated with both the accretion shocks and the inner envelope, for which we estimate a moderate temperature of $T_{\rm kin}\sim$110 K. Our findings reveal a significant difference in the distribution of COMs. O-bearing COMs, such as ethanol, acetone, and ethylene glycol are almost exclusively found and show a higher abundance towards the accretion shocks with $T_{\rm kin}\sim$180 K. Whereas N-bearing COMs with a CN group, such as vinyl and ethyl cyanide peak on the central position, thus the protostar and the accretion disk. This is the first observational evidence for a large column density of COMs seen towards accretion shocks at the centrifugal barrier at the inner envelope. Since the molecular composition is dominated by that of the accretion shocks and the radiatively heated hot inner region is very compact, we propose this source to be a precursor to a classical, radiatively heated hot core.

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arXiv2019

Re-exploring Molecular Complexity with ALMA (ReMoCA): Interstellar detection of urea

Urea, NH2C(O)NH2, is a molecule of great importance in organic chemistry and biology. Two searches for urea in the interstellar medium were reported in the past, but neither were conclusive. We want to take advantage of the increased sensitivity and angular resolution provided by ALMA to search for urea toward the hot cores embedded in the high-mass star forming region Sgr B2(N). We use the new spectral line survey ReMoCA performed toward Sgr B2(N) with ALMA in its observing cycle 4. The spectra are analyzed under the LTE approximation. We construct a full synthetic spectrum that includes all the molecules identified so far. We use new spectroscopic predictions for urea in its vibrational ground state and first vibrationally excited state to search for this complex organic molecule in the ReMoCA data set. We employ the gas-grain chemical kinetics model MAGICKAL to interpret the astronomical observations. We report the secure detection of urea toward the hot core Sgr B2(N1) at a position called N1S slightly offset from the continuum peak, which avoids obscuration by the dust.. We derive a column density of 2.7x10^16 cm-2 for urea, two orders of magnitude lower than formamide, and one order of magnitude below methyl isocyanate, acetamide, and N-methylformamide. The latter molecule is reliably identified toward N1S with 60 clearly detected lines, confirming an earlier claim of its tentative interstellar detection. We report the first interstellar detections of NH2CH18O and 15NH2CHO. We also report the nondetection of urea toward the secondary hot core Sgr B2(N2) with an abundance relative to the other four species at least one order of magnitude lower than toward the main hot core. Our chemical model roughly reproduces the relative abundances of formamide, methyl isocyanate, acetamide, and N-methylformamide, but it overproduces urea by at least one order of magnitude.

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arXiv2019

The complex chemistry of hot cores in Sagittarius B2(N): Influence of cosmic-ray ionization and thermal history

As the number of complex organic molecules (COMs) detected in the interstellar medium increases, it becomes important to place meaningful constraints on the formation pathways of these species. The molecular cloud SgrB2(N) is host to several hot molecular cores in the early stage of star formation, where a great variety of COMs are detected in the gas phase. Because of its exposure to the extreme conditions of the the Galactic center region, SgrB2(N) is one of the best targets to study the impact of environmental conditions on the production of COMs. Our main goal is to characterize the physico-chemical evolution of SgrB2(N)'s sources in order to explain their chemical differences and constrain their environmental conditions. The chemical composition of SgrB2(N)'s hot cores, N2, N3, N4, and N5 is derived by modeling their 3mm emission spectra extracted from the EMoCA imaging spectral line survey performed with ALMA. We derive the density distribution in the envelope of the sources based on the masses computed from the ALMA dust continuum emission maps. We use the radiative transfer code RADMC-3D to compute temperature profiles based on the COM rotational temperatures derived from population diagrams. We use published results of 3D RMHD simulations of high-mass star formation to estimate the time evolution of the sources properties. We employ the chemical code MAGICKAL to compute time-dependent chemical abundances in the sources and investigate how physical properties and environmental conditions influence the production of COMs. We find that chemical models with a cosmic-ray ionization rate of 7e-16s-1 best reproduce the abundances with respect to methanol of ten COMs observed toward SgrB2(N2-N5). We also show that COMs still form efficiently on dust grains with minimum dust temperatures in the prestellar phase as high as 15K, but that minimum temperatures higher than 25K are excluded.

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arXiv2019

Small-scale physical and chemical structure of diffuse and translucent molecular clouds along the line of sight to Sgr B2

The diffuse and translucent molecular clouds traced in absorption along the line of sight to strong background sources have so far been investigated mainly in the spectral domain because of limited angular resolution or small sizes of the background sources. We aim to resolve and investigate the spatial structure of molecular clouds traced by several molecules detected in absorption along the line of sight to SgrB2(N). We have used spectral line data from the EMoCA survey performed with ALMA, taking advantage of the high sensitivity and angular resolution. We identify, on the basis of the spectral analysis of c-C3H2 across the field of view, 15 main velocity components along the line of sight to SgrB2(N) and several components in the envelope of SgrB2. The c-C3H2 column densities reveal two categories of clouds. Clouds in Category I (3 kpc arm, 4 kpc arm, and some GC clouds) have smaller c-C3H2 column densities, smaller linewidths, and smaller widths of their column density PDFs than clouds in Category II (Scutum arm, Sgr arm, and other GC clouds). To investigate the spatial structure we derive opacity maps for the following molecules: c-C3H2, H13CO+, 13CO, HNC, HN13C, HC15N, CS, C34S, 13CS, SiO, SO, and CH3OH. These maps reveal that most molecules trace relatively homogeneous structures that are more extended than the field of view defined by the background continuum emission (about 15", that is 0.08-0.6pc depending on the distance). SO and SiO show more complex structures with smaller clumps of size ~5-8". Our analysis suggests that the driving of the turbulence is mainly solenoidal in the investigated clouds. On the basis of HCO+, we conclude that most line-of-sight clouds towards SgrB2 are translucent, including all clouds where complex organic molecules were recently detected. We also conclude that CCH and CH are good probes of H2 in both diffuse and translucent clouds.

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arXiv2018

Characterizing young protostellar disks with the CALYPSO IRAM-PdBI survey: large Class 0 disks are rare

Understanding the formation mechanisms of protoplanetary disks and multiple systems, and their pristine properties, is a key question for modern astrophysics. The properties of the youngest disks, embedded in rotating infalling protostellar envelopes, have largely remained unconstrained up to now. In the framework of the IRAM-PdBI CALYPSO survey, we have obtained sub-arcsecond observations of the dust continuum emission at 231 GHz and 94 GHz, for a sample of 16 solar-type Class 0 protostars. In an attempt to identify disk-like structures embedded at small scales in the protostellar envelopes, we model the dust continuum emission visibility profiles using both Plummer-like envelope models and envelope models including additional Gaussian disk-like components. Our analysis shows that in the CALYPSO sample, 11 of the 16 Class 0 protostars are better reproduced by models including a disk-like dust continuum component contributing to the flux at small scales, but less than 25% of these candidate protostellar disks are resolved at radii > 60 au. Including all available literature constraints on Class 0 disks at subarcsecond scales, we show that our results are representative: most (> 72% in a sample of 26 protostars) Class 0 protostellar disks are small and emerge only at radii < 60 au. Our multiplicity fraction at scales 100-5000 au is in global agreement with the multiplicity properties of Class I protostars at similar scales. We confront our observational constraints on the disk size distribution in Class 0 protostars to the typical disk properties from protostellar formation models. Because they reduce the centrifugal radius, and produce a disk size distribution peaking at radii <100 au during the main accretion phase, magnetized models of rotating protostellar collapse are favored by our observations.

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arXiv2018

The search for high-mass protostars with ALMA revealed up to kilo-parsec scales (SPARKS): I. Indication for a centrifugal barrier in the environment of a single high-mass envelope

The formation of the most massive O-type stars is poorly understood. We present a case study of a young massive clump from the ATLASGAL survey, G328.2551-0.5321. It exhibits a bolometric luminosity of 1.3$\times$10$^4$ L$_{\odot}$ corresponding to a current protostellar mass of $\sim$11 and 16 M$_{\odot}$. We analyze high angular-resolution observations with ALMA at $\sim$0.17" corresponding a physical scale of $\sim$400 au in dust continuum and molecular lines. The dust continuum emission reveals a single high-mass protostellar envelope and shows evidence for a marginally resolved continuum source. We detect a rotational line of CH$_3$OH within its $v_{\rm t}$=1 torsionally excited state revealing two bright peaks of emission spatially offset from the dust continuum peak, and exhibiting a distinct velocity component $\pm$4.5 km s$^{-1}$ offset compared to the source $v_{\rm lsr}$. Local thermodynamic equilibrium analysis suggests N(CH$_3$OH)=1.2$-$2$\times$10$^{19}$ cm$^{-2}$, and kinetic temperatures of 160$-$200 K at the position of these peaks. Their velocity shifts correspond well to the expected Keplerian velocity around a central object with 15M$_{\odot}$ consistent with the mass estimate based on the source's bolometric luminosity. We propose a picture where the CH$_3$OH emission peaks trace the accretion shocks around the centrifugal barrier, pinpointing the interaction region between the collapsing envelope and an accretion disk. Because the HC$_3$N $v_{\rm 7}$=1e ($J$=38-37) line shows compact emission, and a velocity pattern consistent with models of Keplerian rotation, we suggest that this could be a new tracer for compact accretion disks around high-mass protostars. The estimated physical properties of the accretion disk suggest a specific angular momentum several times larger than typically observed towards low-mass protostars.

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arXiv2017

Complex organic molecules in diffuse clouds along the line of sight to Sgr B2

Up to now, mostly relatively simple molecules have been detected in interstellar diffuse molecular clouds in our galaxy, but more complex species have been reported in the diffuse/translucent medium of a z = 0.89 spiral galaxy. We aim at searching for complex organic molecules (COMs) in diffuse molecular clouds along the line of sight to Sgr B2(N), taking advantage of the high sensitivity and angular resolution of the Atacama Large Millimeter/submillimeter Array (ALMA). We use data acquired as part of the EMoCA survey performed with ALMA. To analyse the absorption features of the molecules detected towards the ultracompact HII region K4 in Sgr B2(N), we calculate synthetic spectra for these molecules and fit their column densities, line widths, centroid velocities, and excitation temperatures. We report the detection of CH3OH, CH3CN, CH3CHO, HC3N, and NH2CHO in Galactic center (GC) diffuse clouds and CH3OH and CH3CN in a diffuse cloud in the Scutum arm. The chemical composition of one of the diffuse GC clouds is found to be similar to the one of the diffuse/translucent medium of the z=0.89 spiral galaxy. The chemical processes leading to chemical complexity in the diffuse molecular ISM appear to have remained similar since z=0.89. As proposed in previous studies, the presence of COMs in diffuse molecular clouds may result from a cyclical interstellar process of cloud contraction and expansion between diffuse and dense states.

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arXiv2017

Organic molecules, ions, and rare isotopologues in the remnant of the stellar-merger candidate, CK Vulpeculae (Nova 1670)

CK Vul is a star whose outburst was observed in 1670-72. A stellar-merger event was proposed to explain its ancient eruption. Aims: We aim to investigate the composition of the molecular gas recently discovered in the remnant of CK Vul. Methods: We observed millimeter and submillimeter-wave spectra of CK Vul using the IRAM 30m and APEX telescopes. Radiative-transfer modeling of the observed molecular features was performed to yield isotopic ratios for various elements. Results: The spectra of CK Vul reveal a very rich molecular environment of low excitation ($T_{\rm ex} \lesssim$12 K). Atomic carbon and twenty seven different molecules, including two ions, were identified. They range from simple diatomic to complex polyatomic species of up to 7 atoms large. The chemical composition of the molecular gas is indicative of carbon and nitrogen-driven chemistry but oxides are also present. Additionally, the abundance of F may be enhanced. The spectra are rich in isotopologues that are very rare in most known sources. All stable isotopes of C, N, O, Si, and S are observed and their isotopic ratios are derived. Conclusions: The composition of the remnant's molecular gas is most peculiar and gives rise to a very unique millimeter and submillimeter spectrum. The observation of ions and complex molecules suggests the presence of a photoionizing source but its nature (a central star or shocks) remains unknown. The elemental and isotopic composition of the gas cannot be easily reconciled with standard nucleosynthesis but processing in hot CNO cycles and partial He burning can explain most of the chemical peculiarities. The isotopic ratios of CK Vul are remarkably close to those of presolar nova grains but the link of Nova 1670 to objects responsible for these grains is unclear.

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arXiv2017

Exploring molecular complexity with ALMA (EMoCA): Detection of three new hot cores in Sagittarius B2(N)

The SgrB2 molecular cloud contains several sites forming high-mass stars. SgrB2(N) is one of its main centers of activity. It hosts several compact and UCHII regions, as well as two known hot molecular cores (SgrB2(N1) and SgrB2(N2)), where complex organic molecules are detected. Our goal is to use the high sensitivity of ALMA to characterize the hot core population in SgrB2(N) and shed a new light on the star formation process. We use a complete 3 mm spectral line survey conducted with ALMA to search for faint hot cores in SgrB2(N). We report the discovery of three new hot cores that we call SgrB2(N3), SgrB2(N4), and SgrB2(N5). The three sources are associated with class II methanol masers, well known tracers of high-mass star formation, and SgrB2(N5) also with a UCHII region. The chemical composition of the sources and the column densities are derived by modelling the whole spectra under the assumption of LTE. The H2 column densities are computed from ALMA and SMA continuum emission maps. The H2 column densities of these new hot cores are found to be 16 up to 36 times lower than the one of the main hot core Sgr B2(N1). Their spectra have spectral line densities of 11 up to 31 emission lines per GHz, assigned to 22-25 molecules. We derive rotational temperatures around 140-180 K for the three new hot cores and mean source sizes of 0.4 for SgrB2(N3) and 1.0 for SgrB2(N4) and SgrB2(N5). SgrB2(N3) and SgrB2(N5) show high velocity wing emission in typical outflow tracers, with a bipolar morphology in their integrated intensity maps suggesting the presence of an outflow, like in SgrB2(N1). The associations of the hot cores with class II methanol masers, outflows, and/or UCHII regions tentatively suggest the following age sequence: SgrB2(N4), SgrB2(N3), SgrB2(N5), SgrB2(N1). The status of SgrB2(N2) is unclear. It may contain two distinct sources, a UCHII region and a very young hot core.

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arXiv2017

Exploring molecular complexity with ALMA (EMoCA): Simulations of branched carbon-chain chemistry in Sgr B2(N)

Using mm-wavelength data from ALMA, the EMoCA spectral line survey revealed the presence of both the straight-chain and branched forms of propyl cyanide (C$_3$H$_7$CN) toward the Galactic Center star-forming source Sgr B2(N2). This was the first interstellar detection of a branched aliphatic molecule. Through computational methods, we seek to explain the observed $i$:$n$ ratio for propyl cyanide, and to predict the abundances of the four different forms of the homologous nitrile, butyl cyanide (C$_4$H$_9$CN). We also investigate whether other molecules will show a similar degree of branching, by modeling alkanes up to pentane (C$_5$H$_{12}$). We use a coupled three-phase chemical kinetics model to simulate the chemistry of Sgr B2(N2), using an updated chemical network that includes grain-surface/ice-mantle formation routes for branched nitriles and alkanes. We use the EMoCA survey data to search for the straight-chain form of butyl cyanide toward Sgr B2(N2). The observed $i$:$n$ ratio for propyl cyanide is reproduced by the models. Butyl cyanide is predicted to show similar abundances to propyl cyanide, and to exhibit strong branching, with the $sec$ form clearly dominant over all others. The addition of CN to acetylene and ethene is found to be important to the production of vinyl, ethyl, propyl, and butyl cyanide. We report a non-detection of $n$-C$_4$H$_9$CN toward Sgr B2(N2), with an abundance at least 1.7 times lower than that of $n$-C$_3$H$_7$CN. This value is within the range predicted by the chemical models. The models indicate that the degree of branching rises with increasing molecular size. The efficiency of CN addition to unsaturated hydrocarbons boosts the abundances of nitriles in the model, and enhances the ratio of straight-to-branched molecule production. The predicted abundance of $s$-C$_4$H$_9$CN makes it a good candidate for future detection toward Sgr B2(N2).

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arXiv2017

Rotational spectroscopy, tentative interstellar detection, and chemical modelling of N-methylformamide

N-methylformamide, CH3NHCHO, may be an important molecule for interstellar pre-biotic chemistry because it contains a peptide bond. The rotational spectrum of the most stable trans conformer of CH3NHCHO is complicated by strong torsion-rotation interaction due to the low barrier of the methyl torsion. We use two absorption spectrometers in Kharkiv and Lille to measure the rotational spectra over 45--630 GHz. The analysis is carried out using the Rho-axis method and the RAM36 code. We search for N-methylformamide toward the hot molecular core Sgr B2(N2) using a spectral line survey carried out with ALMA. The astronomical results are put into a broader astrochemical context with the help of a gas-grain chemical kinetics model. The laboratory data set for the trans conformer of CH3NHCHO consists of 9469 line frequencies with J <= 62, including the first assignment of the rotational spectra of the first and second excited torsional states. All these lines are fitted within experimental accuracy. We report the tentative detection of CH3NHCHO towards Sgr B2(N2). We find CH3NHCHO to be more than one order of magnitude less abundant than NH2CHO, a factor of two less abundant than CH3NCO, but only slightly less abundant than CH3CONH2. The chemical models indicate that the efficient formation of HNCO via NH + CO on grains is a necessary step in the achievement of the observed gas-phase abundance of CH3NCO. Production of CH3NHCHO may plausibly occur on grains either through the direct addition of functional-group radicals or through the hydrogenation of CH3NCO. Provided the detection of CH3NHCHO is confirmed, the only slight underabundance of this molecule compared to its more stable structural isomer acetamide and the sensitivity of the model abundances to the chemical kinetics parameters suggest that the formation of these two molecules is controlled by kinetics rather than thermal equilibrium.

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arXiv2017

Glycolaldehyde in Perseus young solar analogs

Aims: In this paper we focus on the occurrence of glycolaldehyde (HCOCH2OH) in young solar analogs by performing the first homogeneous and unbiased study of this molecule in the Class 0 protostars of the nearby Perseus star forming region. Methods: We obtained sub-arcsec angular resolution maps at 1.3mm and 1.4mm of glycolaldehyde emission lines using the IRAM Plateau de Bure (PdB) interferometer in the framework of the CALYPSO IRAM large program. Results: Glycolaldehyde has been detected towards 3 Class 0 and 1 Class I protostars out of the 13 continuum sources targeted in Perseus: NGC1333-IRAS2A1, NGC1333-IRAS4A2, NGC1333-IRAS4B1, and SVS13-A. The NGC1333 star forming region looks particularly glycolaldehyde rich, with a rate of occurrence up to 60%. The glycolaldehyde spatial distribution overlaps with the continuum one, tracing the inner 100 au around the protostar. A large number of lines (up to 18), with upper-level energies Eu from 37 K up to 375 K has been detected. We derived column densities > 10^15 cm^-2 and rotational temperatures Trot between 115 K and 236 K, imaging for the first time hot-corinos around NGC1333-IRAS4B1 and SVS13-A. Conclusions: In multiple systems glycolaldehyde emission is detected only in one component. The case of the SVS13-A+B and IRAS4-A1+A2 systems support that the detection of glycolaldehyde (at least in the present Perseus sample) indicates older protostars (i.e. SVS13-A and IRAS4-A2), evolved enough to develop the hot-corino region (i.e. 100 K in the inner 100 au). However, only two systems do not allow us to firmly conclude whether the primary factor leading to the detection of glycolaldehyde emission is the environments hosting the protostars, evolution (e.g. low value of Lsubmm/Lint), or accretion luminosity (high Lint).

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