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A. Belloche

Publications and source records attributed to A. Belloche.

At least 73 records · Page 4Linked to original sources

First image of the L1157 molecular jet by the CALYPSO IRAM-PdBI survey

Fast jets are thought to be a crucial ingredient of star formation because they might extract angular momentum from the disk and thus allow mass accretion onto the star. However, it is unclear whether jets are ubiquitous, and likewise, their contribution to mass and angular momentum extraction during protostar formation remains an open question. Our aim is to investigate the ejection process in the low-mass Class 0 protostar L1157. This source is associated with a spectacular bipolar outflow, and the recent detection of high-velocity SiO suggests the occurrence of a jet. Observations of CO 2-1 and SiO 5-4 at 0.8" resolution were obtained with the IRAM Plateau de Bure Interferometer as part of the CALYPSO large program. The jet and outflow structure were fit with a precession model. We derived the column density of CO and SiO, as well as the jet mass-loss rate and mechanical luminosity. High-velocity CO and SiO emission resolve for the first time the first 200 au of the outflow-driving molecular jet. The jet is strongly asymmetric, with the blue lobe 0.65 times slower than the red lobe. This suggests that the large-scale asymmetry of the outflow is directly linked to the jet velocity and that the asymmetry in the launching mechanism has been at work for the past 1800 yr. Velocity asymmetries are common in T Tauri stars, which suggests that the jet formation mechanism from Class 0 to Class II stages might be similar. Our model simultaneously fits the inner jet and the clumpy 0.2 pc scale outflow by assuming that the jet precesses counter-clockwise on a cone inclined by 73 degree to the line of sight with an opening angle of 8 degree on a period of 1640 yr. The estimated jet mass flux and mechanical luminosity are 7.7e-7 Msun/yr, and 0.9 Lsun, indicating that the jet could extract at least 25% of the gravitational energy released by the forming star.

astro-ph.GA↗

Volatile carbon locking and release in protoplanetary disks. A study of TW Hya and HD 100546

The composition of planetary solids and gases is largely rooted in the processing of volatile elements in protoplanetary disks. To shed light on the key processes, we carry out a comparative analysis of the gas-phase carbon abundance in two systems with a similar age and disk mass, but different central stars: HD 100546 and TW Hya. We combine our recent detections of C$^{0}$ in these disks with observations of other carbon reservoirs (CO, C$^{+}$, C$_{2}$H) and gas mass and warm gas tracers (HD, O$^{0}$), as well as spatially resolved ALMA observations and the spectral energy distribution. The disks are modelled with the DALI 2D physical-chemical code. Stellar abundances for HD 100546 are derived from archival spectra. Upper limits on HD emission from HD 100546 place an upper limit on the total disk mass of $\leq0.1\,M_{\odot}$. The gas-phase carbon abundance in the atmosphere of this warm Herbig disk is at most moderately depleted compared to the interstellar medium, with [C]/[H]$_{\rm gas}=(0.1-1.5)\times 10^{-4}$. HD 100546 itself is a $λ\,$Boötis star, with solar abundances of C and O but a strong depletion of rock-forming elements. In the gas of the T Tauri disk TW Hya, both C and O are strongly underabundant, with [C]/[H]$_{\rm gas}=(0.2-5.0)\times 10^{-6}$ and C/O${>}1$. We discuss evidence that the gas-phase C and O abundances are high in the warm inner regions of both disks. Our analytical model, including vertical mixing and a grain size distribution, reproduces the observed [C]/[H]$_{\rm gas}$ in the outer disk of TW Hya and allows to make predictions for other systems.

astro-ph.EP↗

Microphysics and dynamics of the Gamma-Ray Burst 121024A

Aims. The aim of the study is to constrain the physics of gamma-ray bursts (GRBs) by analysing the multi-wavelength afterglow data set of GRB 121024A that covers the full range from radio to X-rays. Methods. Using multi-epoch broad-band observations of the GRB 121024A afterglow, we measured the three characteristic break frequencies of the synchrotron spectrum. We used six epochs of combined XRT and GROND data to constrain the temporal slopes, the dust extinction, the X-ray absorption, and the spectral slope with high accuracy. Two more epochs of combined data from XRT, GROND, APEX, CARMA, and EVLA were used to set constraints on the break frequencies and therefore on the micro-physical and dynamical parameters. Results. The XRT and GROND light curves show a simultaneous and achromatic break at around 49 ks. As a result, the crossing of the synchrotron cooling break is no suitable explanation for the break in the light curve. The multi wavelength data allow us to test two plausible scenarios explaining the break: a jet break, and the end of energy injection. The jet-break scenario requires a hard electron spectrum, a very low cooling break frequency, and a non-spreading jet. The energy injection avoids these problems, but requires $ε_e > 1 (k = 2)$, spherical outflow, and $ε_B < 10^{-9}$. Conclusions. In light of the extreme microphysical parameters required by the energy-injection model, we favour a jet-break scenario where $ν_m < ν_{sa}$ to explain the observations. This scenario gives physically meaningful microphysical parameters, and it also naturally explains the reported detection of linear and circular polarisation.

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Probing the CO and methanol snow lines in young protostars. Results from the CALYPSO IRAM-PdBI survey

Context. "Snow lines", marking regions where abundant volatiles freeze out onto the surface of dust grains, play an important role for planet growth and bulk composition in protoplanetary disks. They can already be observed in the envelopes of the much younger, low-mass Class 0 protostars that are still in their early phase of heavy accretion. Aims. We aim at using the information on the sublimation regions of different kinds of ices to understand the chemistry of the envelope, its temperature and density structure, and the history of the accretion process. Methods. As part of the CALYPSO IRAM Large Program, we have obtained observations of C$^{18}$O, N$_2$H$^+$ and CH$_3$OH towards nearby Class 0 protostars with the IRAM Plateau de Bure interferometer at sub-arcsecond resolution. For four of these sources we have modeled the emission using a chemical code coupled with a radiative transfer module. Results. We observe an anti-correlation of C$^{18}$O and N$_2$H$^+$ in NGC 1333-IRAS4A, NGC 1333-IRAS4B, L1157, and L1448C, with N$_2$H$^+$ forming a ring around the centrally peaked C$^{18}$O emission due to N$_2$H$^+$ being chemically destroyed by CO. The emission regions of models and observations match for a CO binding energy of 1200 K, which is higher than the binding energy of pure CO ices ($\sim$855 K). Furthermore, we find very low CO abundances inside the snow lines in our sources, about an order of magnitude lower than the total CO abundance observed in the gas on large scales in molecular clouds before depletion sets in. Conclusions. The high CO binding energy may hint at CO being frozen out in a polar ice environment like amorphous water ice or in non-polar CO$_2$-rich ice. The low CO abundances are comparable to values found in protoplanetary disks, which may indicate an evolutionary scenario where these low values are already established in the protostellar phase. (Abbr. Version)

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Spectroscopic study and astronomical detection of doubly 13C-substituted ethyl cyanide

We have performed a spectral line survey called EMoCA toward Sagittarius B2(N) between 84 and 114 GHz with ALMA. Line intensities of the main isotopic species of ethyl cyanide and its singly 13C-substituted isotopomers observed toward the hot molecular core Sgr B2(N2) suggest that the doubly 13C-substituted isotopomers should be detectable also. We want to determine the spectroscopic parameters of all three doubly 13C-substituted isotopologues of ethyl cyanide to search for them in our ALMA data. We investigated the laboratory rotational spectra of the three species between 150 and 990 GHz. We searched for emission lines produced by these species in the ALMA spectrum of Sgr B2(N2). We modeled their emission as well as the emission of the 12C and singly 13C-substituted isotopologues assuming local thermodynamic equilibrium. We identified more than 5000 rotational transitions, pertaining to more than 3500 different transition frequencies, in the laboratory for each of the three isotopomers. The quantum numbers reach J ~ 115 and K_a ~ 35, resulting in accurate spectroscopic parameters and accurate rest frequency calculations beyond 1000 GHz for strong to moderately weak transitions of either isotopomer. All three species are unambiguously detected in our ALMA data. The 12C/13C column density ratio of the isotopomers with one 13C atom to the ones with two 13C atoms is about 25. Ethyl cyanide is the second molecule after methyl cyanide for which isotopologues containing two 13C atoms have been securely detected in the interstellar medium. The model of our ethyl cyanide data suggests that we should be able to detect vibrational satellites of the main species up to at least v_19 = 1 at 1130 K and up to v_13 + v_21 = 2 at 600 K for the isotopologues with one 13C atom in our present ALMA data. Such satellites may be too weak to be identified unambiguously for isotopologues with two 13C atoms.

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Exploring molecular complexity with ALMA (EMoCA): Alkanethiols and alkanols in Sagittarius B2(N2)

Over the past five decades, radio astronomy has shown that molecular complexity is a natural outcome of interstellar chemistry, in particular in star forming regions. However, the pathways that lead to the formation of complex molecules are not completely understood and the depth of chemical complexity has not been entirely revealed. In addition, the sulfur chemistry in the dense interstellar medium is not well understood. We want to know the relative abundances of alkanethiols and alkanols in the Galactic Center source Sagittarius B2(N2), the northern hot molecular core in Sgr B2(N), whose relatively small line widths are favorable for studying the molecular complexity in space. We investigated spectroscopic parameter sets that were able to reproduce published laboratory rotational spectra of ethanethiol and studied effects that modify intensities in the predicted rotational spectrum of ethanol. We used the Atacama Large Millimeter Array (ALMA) in its Cycles~0 and 1 for a spectral line survey of Sagittarius B2(N) between 84 and 114.4 GHz. These data were analyzed by assuming local thermodynamic equilibrium (LTE) for each molecule. Our observations are supplemented by astrochemical modeling; a new network is used for the first time that includes reaction pathways for alkanethiols. The column density ratios involving methanol, ethanol, and methanethiol in Sgr B2(N2) are similar to values reported for Orion KL, but those involving ethanethiol are significantly different and suggest that the detection of ethanethiol reported toward Orion KL is uncertain. Our chemical model presently does not permit the prediction of sufficiently accurate column densities of alkanethiols or their ratios among alkanethiols and alkanols. Therefore, additional observational results are required to establish the level of C2H5SH in the dense and warm interstellar medium with certainty.

astro-ph.GA↗

Deuterium Fractionation in the Ophiuchus Molecular Cloud

Aims. We measure the deuterium fraction, RD, and the CO-depletion factor, fd, toward a number of starless and protostellar cores in the L1688 region of the Ophiuchus molecular cloud complex and search for variations based upon environmental differences across L1688. The kinematic properties of the dense gas traced by the N2H+ and N2D+ (1-0) lines are also discussed. Methods. RD has been measured via observations of the J=1-0 transition of N2H+ and N2D+ toward 33 dense cores in different regions of L1688. fd estimates have been done using C17O(1-0) and 850 micron dust continuum emission from the SCUBA survey. All line observations were carried out with the IRAM 30 meter antenna. Results. The dense cores show large (2-40%) deuterium fractions, with significant variations between the sub-regions of L1688. The CO-depletion factor also varies from one region to another (1-7). Two different correlations are found between deuterium fraction and CO-depletion factor: cores in regions A, B2 and I show increasing RD with increasing fd, similar to previous studies of deuterium fraction in pre-stellar cores; cores in regions B1, B1B2, C, E, F and H show a steeper RD-fd correlation, with large deuterium fractions occurring in fairly quiescent gas with relatively low CO freeze-out factors. These are probably recently formed, centrally concentrated starless cores which have not yet started the contraction phase toward protostellar formation. We also find that the deuterium fraction is affected by the amount of turbulence, dust temperature and distance from heating sources in all regions of L1688, although no clear trend is found.

astro-ph.SR↗

Exploring Molecular Complexity with ALMA (EMoCA): Deuterated complex organic molecules in Sagittarius B2(N2)

Deuteration is a powerful tracer of the history of the cold prestellar phase in star forming regions. Apart from methanol, little is known about deuterium fractionation of complex organic molecules in the interstellar medium, especially in high mass star forming regions. We use a spectral line survey performed with ALMA to search for deuterated complex organic molecules toward the hot molecular core Sgr B2(N2). Population diagrams and integrated intensity maps are constructed to fit rotational temperatures and emission sizes for each molecule. Column densities are derived by modelling the full spectrum under the LTE assumption. The results are compared to predictions of two astrochemical models that treat the deuteration process. We report the detection of CH2DCN toward Sgr B2(N2) with a deuteration level of 0.4%, and tentative detections of CH2DOH, CH2DCH2CN, the chiral molecule CH3CHDCN, and DC3N with levels in the range 0.05%-0.12%. A stringent deuteration upper limit is obtained for CH3OD (<0.07%). Upper limits in the range 0.5-1.8% are derived for the three deuterated isotopologues of vinyl cyanide, the four deuterated species of ethanol, and CH2DOCHO. Ethyl cyanide is less deuterated than methyl cyanide by at least a factor five. Except for methyl cyanide, the measured deuteration levels lie at least a factor four below the predictions of current astrochemical models. The deuteration levels in Sgr B2(N2) are also lower than in Orion KL by a factor of a few up to a factor ten. The discrepancy between the deuteration levels of Sgr B2(N2) and the predictions of chemical models, and the difference between Sgr B2(N2) and Orion KL may both be due to the higher kinetic temperatures that characterize the Galactic Center region compared to nearby clouds. Alternatively, they may result from a lower overall abundance of deuterium itself in the Galactic Center region by up to a factor ten.

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Jet multiplicity in the proto-binary system NGC1333-IRAS4A. The detailed CALYPSO IRAM-PdBI view

Owing to the paucity of sub-arcsecond (sub)mm observations required to probe the innermost regions of newly forming protostars, several fundamental questions are still being debated, such as the existence and coevality of close multiple systems. We study the physical and chemical properties of the jets and protostellar sources in the NGC1333-IRAS4A proto-binary system using continuum emission and molecular tracers of shocked gas. We observed NGC1333-IRAS4A in the SiO(6-5), SO(6_5-5_4), and CO(2-1) lines and the continuum emission at 1.3, 1.4, and 3 mm using the IRAM Plateau de Bure Interferometer in the framework of the CALYPSO large program. We clearly disentangle for the first time the outflow emission from the two sources A1 and A2. The two protostellar jets have very different properties: the A1 jet is faster, has a short dynamical timescale (<10^3 yr), and is associated with H2 shocked emission, whereas the A2 jet, which dominates the large-scale emission, is associated with diffuse emission, bends, and emits at slower velocities. The observed bending of the A2 jet is consistent with the change of propagation direction observed at large scale and suggests jet precession on very short timescales (~200-600 yr). In addition, a chemically rich spectrum with emission from several COMs (e.g. HCOOH, CH3OCHO, CH3OCH3) is only detected towards A2. Finally, very high-velocity shocked emission (~50 km s^-1) is observed along the A1 jet. An LTE analysis shows that SiO, SO, and H2CO abundances in the gas phase are enhanced up to (3-4)x10^{-7}, (1.4-1.7)x10^{-6}, and (3-7.9)x10^{-7}, respectively. The intrinsic different properties of the jets and driving sources in NGC1333-IRAS4A suggest different evolutionary stages for the two protostars, with A1 being younger than A2, in a very early stage of star formation previous to the hot-corino phase.

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Outflow forces in intermediate mass star formation

Intermediate mass protostarsprovide a bridge between theories of low- and high-mass star formation. Emerging molecular outflows can be used to determine the influence of fragmentation and multiplicity on protostellar evolution through the correlation of outflow forces of intermediate mass protostars with the luminosity. The aim of this paper is to derive outflow forces from outflows of six intermediate mass protostellar regions and validate the apparent correlation between total luminosity and outflow force seen in earlier work, as well as remove uncertainties caused by different methodology. By comparing CO 6--5 observations obtained with APEX with non-LTE radiative transfer model predictions, optical depths, temperatures, densities of the gas of the molecular outflows are derived. Outflow forces, dynamical timescales and kinetic luminosities are subsequently calculated. Outflow parameters, including the forces, were derived for all sources. Temperatures in excess of 50 K were found for all flows, in line with recent low-mass results. However, comparison with other studies could not corroborate conclusions from earlier work on intermediate mass protostars which hypothesized that fragmentation enhances outflow forces in clustered intermediate mass star formation. Any enhancement in comparison with the classical relation between outflow force and luminosity can be attributed the use of a higher excitation line and improvement in methods; They are in line with results from low-mass protostars using similar techniques. The role of fragmentation on outflows is an important ingredient to understand clustered star formation and the link between low and high-mass star formation. However, detailed information on spatial scales of a few 100 AU, covering all individual members is needed to make the necessary progress.

astro-ph.SR↗

Star formation in Chamaeleon I and III: a molecular line study of the starless core population

The Chamaeleon clouds are excellent targets for low-mass star formation studies. Cha I and II are actively forming stars while Cha III shows no sign of ongoing star formation. We aim to determine the driving factors that have led to the very different levels of star formation activity in Cha I and III and examine the dynamical state and possible evolution of the starless cores within them. Observations were performed in various molecular transitions with APEX and Mopra. Five cores are gravitationally bound in Cha I and one in Cha III. The infall signature is seen toward 8-17 cores in Cha I and 2-5 cores in Cha III, which leads to a range of 13-28% of the cores in Cha I and 10-25% of the cores in Cha III that are contracting and may become prestellar. Future dynamical interactions between the cores will not be dynamically significant in either Cha I or III, but the subregion Cha I North may experience collisions between cores within ~0.7 Myr. Turbulence dissipation in the cores of both clouds is seen in the high-density tracers N2H+ 1-0 and HC3N 10-9. Evidence of depletion in the Cha I core interiors is seen in the abundance distributions of C17O, C18O, and C34S. Both contraction and static chemical models indicate that the HC3N to N2H+ abundance ratio is a good evolutionary indicator in the prestellar phase for both gravitationally bound and unbound cores. In the framework of these models, we find that the cores in Cha III and the southern part of Cha I are in a similar evolutionary stage and are less chemically evolved than the central region of Cha I. The measured HC3N/N2H+ abundance ratio and the evidence for contraction motions seen towards the Cha III starless cores suggest that Cha III is younger than Cha I Centre and that some of its cores may form stars in the future. The cores in Cha I South may on the other hand be transient structures. (abridged)

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First results from the CALYPSO IRAM-PdBI survey. I. Kinematics of the inner envelope of NGC1333-IRAS2A

The structure and kinematics of Class 0 protostars on scales of a few hundred AU is poorly known. Recent observations have revealed the presence of Keplerian disks with a diameter of 150-180 AU in L1527-IRS and VLA1623A, but it is not clear if such disks are common in Class 0 protostars. Here we present high-angular-resolution observations of two methanol lines in NGC1333-IRAS2A. We argue that these lines probe the inner envelope, and we use them to study the kinematics of this region. Our observations suggest the presence of a marginal velocity gradient normal to the direction of the outflow. However, the position velocity diagrams along the gradient direction appear inconsistent with a Keplerian disk. Instead, we suggest that the emission originates from the infalling and perhaps slowly rotating envelope, around a central protostar of 0.1-0.2 M$_\odot$. If a disk is present, it is smaller than the disk of L1527-IRS, perhaps suggesting that NGC1333-IRAS2A is younger.

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First results from the CALYPSO IRAM-PdBI survey. II. Resolving the hot corino in the Class 0 protostar NGC 1333-IRAS2A

We investigate the origin of complex organic molecules (COMs) in the gas phase around the low-mass Class~0 protostar NGC1333-IRAS2A, to determine if the COM emission lines trace an embedded disk, shocks from the protostellar jet, or the warm inner parts of the protostellar envelope. In the framework of the CALYPSO (Continuum And Lines in Young ProtoStellar Objects) IRAM Plateau de Bure survey, we obtained large bandwidth spectra at sub-arcsecond resolution towards NGC 1333-IRAS2A. We identify the emission lines towards the central protostar and perform Gaussian fits to constrain the size of the emitting region for each of these lines, tracing various physical conditions and scales. The emission of numerous COMs such as methanol, ethylene glycol, and methyl formate is spatially resolved by our observations. This allows us to measure, for the first time, the size of the COM emission inside the protostellar envelope, finding that it originates from a region of radius 40-100 AU, centered on the NGC 1333-IRAS2A protostellar object. Our analysis shows no preferential elongation of the COM emission along the jet axis, and therefore does not support the hypothesis that COM emission arises from shocked envelope material at the base of the jet. Down to similar sizes, the dust continuum emission is well reproduced with a single envelope model, and therefore does not favor the hypothesis that COM emission arises from the thermal sublimation of grains embedded in a circumstellar disk. Finally, the typical scale $\sim$60 AU observed for COM emission is consistent with the size of the inner envelope where $T_{\rm{dust}} > 100$ K is expected. Our data therefore strongly suggest that the COM emission traces the hot corino in IRAS2A, i.e., the warm inner envelope material where the icy mantles of dust grains evaporate because they are passively heated by the central protostellar object.

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First results from the CALYPSO IRAM-PdBI survey - III. Monopolar jets driven by a proto-binary system in NGC1333-IRAS2A

Context: The earliest evolutionary stages of low-mass protostars are characterised by hot and fast jets which remove angular momentum from the circumstellar disk, thus allowing mass accretion onto the central object. However, the launch mechanism is still being debated. Aims: We would like to exploit high-angular (~ 0.8") resolution and high-sensitivity images to investigate the origin of protostellar jets using typical molecular tracers of shocked regions, such as SiO and SO. Methods: We mapped the inner 22" of the NGC1333-IRAS2A protostar in SiO(5-4), SO(65-54), and the continuum emission at 1.4 mm using the IRAM Plateau de Bure interferometer in the framework of the CALYPSO IRAM large program. Results: For the first time, we disentangle the NGC1333-IRAS2A Class 0 object into a proto-binary system revealing two protostars (MM1, MM2) separated by ~ 560 AU, each of them driving their own jet, while past work considered a single protostar with a quadrupolar outflow. We reveal (i) a clumpy, fast (up to |V-VLSR| > 50 km/s), and blueshifted jet emerging from the brightest MM1 source, and (ii) a slower redshifted jet, driven by MM2. Silicon monoxide emission is a powerful tracer of high-excitation (Tkin > 100 K; n(H2) > 10^5 cm-3) jets close to the launching region. At the highest velocities, SO appears to mimic SiO tracing the jets, whereas at velocities close to the systemic one, SO is dominated by extended emission, tracing the cavity opened by the jet. Conclusions: Both jets are intrinsically monopolar, and intermittent in time. The dynamical time of the SiO clumps is < 30-90 yr, indicating that one-sided ejections from protostars can take place on these timescales.

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The dynamical state of the First Hydrostatic Core Candidate Cha-MMS1

Observations of First Hydrostatic Core candidates, a theoretically predicted evolutionary link between the prestellar and protostellar phases, are vital for probing the earliest phases of star formation. We aim to determine the dynamical state of the First Hydrostatic Core candidate Cha-MMS1. We observed Cha-MMS1 in various transitions with the APEX and Mopra telescopes. The molecular emission was modeled with a radiative transfer code to derive constraints on the envelope kinematics. We derive an internal luminosity of 0.08 - 0.18 Lsol. An average velocity gradient of 3.1(0.1) km/s/pc over 0.08 pc is found perpendicular to the filament in which Cha-MMS1 is embedded. The gradient is flatter in the outer parts and at the innermost 2000 - 4000 AU. These features suggest solid-body rotation beyond 4000 AU and slower, differential rotation beyond 8000 AU. The origin of the flatter gradient in the innermost parts is unclear. The classical infall signature is detected in HCO+ 3-2 and CS 2-1. The radiative transfer modeling indicates a uniform infall velocity in the outer parts of the envelope. An infall velocity field scaling with r^(-0.5) is consistent with the data for r < 9000 AU. The infall velocities are 0.1 - 0.2 km/s at r > 3300 AU and 0.04 - 0.6 km/s at r < 3300 AU. Both the internal luminosity of Cha-MMS1 and the infall velocity field in its envelope are consistent with predictions of MHD simulations for the first core phase. There is no evidence for a fast, large-scale outflow stemming from Cha-MMS1 but excess emission from the high-density tracers CS 5-4, CO 6-5, and CO 7-6 suggests the presence of higher-velocity material at the inner core. Its internal luminosity excludes Cha-MMS1 being a prestellar core. The kinematical properties of its envelope are consistent with Cha-MMS1 being a first core candidate or a very young Class 0 protostar.(abridged).

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The IRAM-30m line survey of the Horsehead PDR: II. First detection of the l-C3H+ hydrocarbon cation

We present the first detection of the l-C3H+ hydrocarbon in the interstellar medium. The Horsehead WHISPER project, a millimeter unbiased line survey at two positions, namely the photo-dissociation region (PDR) and the nearby shielded core, revealed a consistent set of eight unidentified lines toward the PDR position. Six of them are detected with a signal-to-noise ratio from 6 to 19, while the two last ones are tentatively detected. Mostly noise appears at the same frequency toward the dense core, located less than 40" away. We simultaneously fit 1) the rotational and centrifugal distortion constants of a linear rotor, and 2) the Gaussian line shapes located at the eight predicted frequencies. The observed lines can be accurately fitted with a linear rotor model, implying a 1Sigma ground electronic state. The deduced rotational constant value is Be= 11244.9512 +/- 0.0015 MHz, close to that of l-C3H. We thus associate the lines to the l-C3H+ hydrocarbon cation, which enables us to constrain the chemistry of small hydrocarbons. A rotational diagram is then used to infer the excitation temperature and the column density. We finally compare the abundance to the results of the Meudon PDR photochemical model.

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The quest for complex molecules in space: Laboratory spectroscopy of n-butyl cyanide, n-C4H9CN, in the millimeter wave region and its astronomical search in Sagittarius B2(N)

The saturated n-propyl cyanide was recently detected in Sagittarius B2(N). The next larger unbranched alkyl cyanide is n-butyl cyanide. We provide accurate rest frequency predictions beyond the millimeter wave range to search for this molecule in the Galactic center source Sagittarius B2(N) and facilitate its detection in space. We investigated the laboratory rotational spectrum of $n$-butyl cyanide between 75 GHz and 348 GHz. We searched for emission lines produced by the molecule in our sensitive IRAM 30 m molecular line survey of Sagittarius B2(N). We identified more than one thousand rotational transitions in the laboratory for each of the three conformers for which limited data had been obtained previously in a molecular beam microwave study. The quantum number range was greatly extended to J ~ 120 or more and Ka > 35, resulting in accurate spectroscopic parameters and accurate rest frequency calculations up to about 500 GHz for strong to moderately weak transitions of the two lower energy conformers. Upper limits to the column densities of N <= 3 x 10E15 cm-2 and 8 x 10E15 cm-2 were derived towards Sagittarius B2(N) for the two lower energy conformers, anti-anti and gauche-anti, respectively. Our present data will be helpful for identifying n-butyl cyanide at millimeter or longer wavelengths with radio telescope arrays such as ALMA, NOEMA, or EVLA. In particular, its detection in Sagittarius B2(N) with ALMA seems feasible.

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Detection of OD towards the low-mass protostar IRAS16293-2422

Although water is an essential and widespread molecule in star-forming regions, its chemical formation pathways are still not very well constrained. Observing the level of deuterium fractionation of OH, a radical involved in the water chemical network, is a promising way to infer its chemical origin. We aim at understanding the formation mechanisms of water by investigating the origin of its deuterium fractionation. This can be achieved by observing the abundance of OD towards the low-mass protostar IRAS16293-2422, where the HDO distribution is already known. Using the GREAT receiver on board SOFIA, we observed the ground-state OD transition at 1391.5 GHz towards the low-mass protostar IRAS16293-2422. We also present the detection of the HDO 111-000 line using the APEX telescope. We compare the OD/HDO abundance ratio inferred from these observations with the predictions of chemical models. The OD line is detected in absorption towards the source continuum. This is the first detection of OD outside the solar system. The SOFIA observation, coupled to the observation of the HDO 111-000 line, provides an estimate of the abundance ratio OD/HDO ~ 17-90 in the gas where the absorption takes place. This value is fairly high compared with model predictions. This may be reconciled if reprocessing in the gas by means of the dissociative recombination of H2DO+ further fractionates OH with respect to water. The present observation demonstrates the capability of the SOFIA/GREAT instrument to detect the ground transition of OD towards star-forming regions in a frequency range that was not accessible before. Dissociative recombination of H2DO+ may play an important role in setting a high OD abundance. Measuring the branching ratios of this reaction in the laboratory will be of great value for chemical models.

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