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A. Derevianko

Publications and source records attributed to A. Derevianko.

At least 37 records · Page 2Linked to original sources

Magnetic-dipole transitions in highly-charged ions as a basis of ultra-precise optical clocks

We evaluate the feasibility of using magnetic-dipole (M1) transitions in highly-charged ions as a basis of an optical atomic clockwork of exceptional accuracy. We consider a range of possibilities, including M1 transitions between clock levels of the same fine-structure and hyperfine-structure manifolds. In highly charged ions these transitions lie in the optical part of the spectra and can be probed with lasers. The most direct advantage of our proposal comes from the low degeneracy of clock levels and the simplicity of atomic structure in combination with negligible quadrupolar shift. We demonstrate that such clocks can have projected fractional accuracies below the $10^{-20}-10^{-21}$ level for all common systematic effects, such as black-body radiation, Zeeman, AC-Stark and quadrupolar shifts. Notice that usually-employed hyperfine clock transitions lie in the microwave spectral region. Our proposal moves such transitions to the optical domain. As the hyperfine transition frequencies depend on the fine-structure constant, electron-to-proton mass ratio, and nuclear magnetic moment, our proposal expands the range of experimental schemes for probing space and time variations of fundamental constants.

physics.atom-ph↗

Relativistic many-body calculations of van der Waals coefficients for Yb-Li and Yb-Rb dimers

We derive the relativistic formulas for the van der Waals coefficients of Yb-alkali dimers that correlate to ground and excited separated-atom limits. We calculate $C_6$ and $C_8$ coefficients of particular experimental interest. We also derive a semi-empirical formula that expresses the $C_8$ coefficient of heteronuclear $A+B$ dimers in terms of the $C_6$ and $C_8$ coefficients of homonuclear dimers and the static dipole and quadrupole polarizabilities of the atomic states $A$ and $B$. We report results of calculation of the $C_6$ coefficients for the Yb-Rb $^3/!P_1^o+5s\, ^2/!S_{1/2}$ and $^1/!S_0+5p\, ^2/!P^o_{1/2}$ dimers, and the $C_8$ coefficients for the Yb-Li $^1/!S_0+2s\, ^2/!S_{1/2}$ and Yb-Rb $^1/!S_0+5s\, ^2/!S_{1/2}$ dimers. Uncertainties are estimated for all predicted properties.

physics.atom-ph↗

Long range interactions of ytterbium in mixed quantum gases

We present methods for accurate evaluation of van der Waals coefficients of dimers with excited atoms that have a strong decay channel. We calculate C_6 coefficients for the Yb-Yb 1S_0+ 3P_{0,1}, 3P_0+3P_0 and Yb-Rb 3P_1+5s, 1S_0+ 5p_{1/2} dimers and C_8 coefficients for the Yb-Yb 1S_0+1S_0, 1S_0+3P_1 and Yb-Rb 1S_0+5s dimers. We evaluate uncertainties of all properties.

physics.atom-ph↗

Long range interaction coefficients for ytterbium dimers

We evaluate the electric-dipole and electric-quadrupole static and dynamic polarizabilities for the 6s^2 ^1S_0, 6s6p ^3P_0, and 6s6p ^3P_1 states and estimate their uncertainties. A methodology is developed for an accurate evaluation of the van der Waals coefficients of dimers involving excited state atoms with strong decay channel to the ground state. This method is used for evaluation of the long range interaction coefficients of particular experimental interest, including the C_6 coefficients for the Yb-Yb ^1S_0+^3P_{0,1} and ^3P_0+^3P_0 dimers and C_8 coefficients for the ^1S_0+^1S_0 and ^1S_0+^3P_1 dimers.

physics.atom-ph↗

High-precision atomic clocks with highly charged ions: nuclear spin-zero $f^{12}$-shell ions

Optical atomic clocks using highly-charged ions hold an intriguing promise of metrology at the 19th significant figure. Here we study transitions within the $4f^{12}$ ground-state electronic configuration of highly charged ions. We consider isotopes lacking hyperfine structure and show that the detrimental effects of coupling of electronic quadrupole moments to gradients of trapping electric field can be effectively reduced by using specially chosen virtual clock transitions. The estimated systematic fractional clock accuracy is shown to be below $10^{-19}$.

physics.atom-ph↗

Ion clock and search for the variation of the fine structure constant using optical transitions in Nd$^{13+}$ and Sm$^{15+}$

We study ultranarrow $5s_{1/2}$ - $4f_{5/2}$ transitions in Nd$^{13+}$ and Sm$^{15+}$ and demonstrate that they lie in the optical region. The transitions are insensitive to external perturbations. At the same time they are sensitive to the variation of the fine structure constant $α$. The fractional accuracy of the frequency of the transitions can be smaller than $10^{-19}$, which may provide a basis for atomic clocks of superb accuracy. Sensitivity to the variation of $α$ approaches $10^{-20}$ per year.

physics.atom-ph↗

Coupled-cluster calculations of properties of Boron atom as a monovalent system

We present relativistic coupled-cluster (CC) calculations of energies, magnetic-dipole hyperfine constants, and electric-dipole transition amplitudes for low-lying states of atomic boron. The trivalent boron atom is computationally treated as a monovalent system. We explore performance of the CC method at various approximations. Our most complete treatment involves singles, doubles and the leading valence triples. The calculations are done using several approximations in the coupled-cluster (CC) method. The results are within 0.2-0.4% of the energy benchmarks. The hyperfine constants are reproduced with 1-2% accuracy.

physics.atom-ph↗

Femtosecond pulses and dynamics of molecular photoexcitation: RbCs example

We investigate the dynamics of molecular photoexcitation by unchirped femtosecond laser pulses using RbCs as a model system. This study is motivated by a goal of optimizing a two-color scheme of transferring vibrationally-excited ultracold molecules to their absolute ground state. In this scheme the molecules are initially produced by photoassociation or magnetoassociation in bound vibrational levels close to the first dissociation threshold. We analyze here the first step of the two-color path as a function of pulse intensity from the low-field to the high-field regime. We use two different approaches, a global one, the 'Wavepacket' method, and a restricted one, the 'Level by Level' method where the number of vibrational levels is limited to a small subset. The comparison between the results of the two approaches allows one to gain qualitative insights into the complex dynamics of the high-field regime. In particular, we emphasize the non-trivial and important role of far-from-resonance levels which are adiabatically excited through 'vertical' transitions with a large Franck-Condon factor. We also point out spectacular excitation blockade due to the presence of a quasi-degenerate level in the lower electronic state. We conclude that selective transfer with femtosecond pulses is possible in the low-field regime only. Finally, we extend our single-pulse analysis and examine population transfer induced by coherent trains of low-intensity femtosecond pulses.

physics.atom-ph↗

A Single-Ion Nuclear Clock for Metrology at the 19th Decimal Place

The 7.6(5) eV nuclear magnetic-dipole transition in a single 229Th3+ ion may provide the foundation for an optical clock of superb accuracy. A virtual clock transition composed of stretched states within the 5F5/2 electronic ground level of both nuclear ground and isomeric manifolds is proposed. It is shown to offer unprecedented systematic shift suppression, allowing for clock performance with a total fractional inaccuracy approaching 1 x 10^-19.

physics.atom-ph↗

Resolving all-order method convergence problems for atomic physics applications

The development of the relativistic all-order method where all single, double, and partial triple excitations of the Dirac-Hartree-Fock wave function are included to all orders of perturbation theory led to many important results for study of fundamental symmetries, development of atomic clocks, ultracold atom physics, and others, as well as provided recommended values of many atomic properties critically evaluated for their accuracy for large number of monovalent systems. This approach requires iterative solutions of the linearized coupled-cluster equations leading to convergence issues in some cases where correlation corrections are particularly large or lead to an oscillating pattern. Moreover, these issues also lead to similar problems in the CI+all-order method for many-particle systems. In this work, we have resolved most of the known convergence problems by applying two different convergence stabilizer methods, reduced linear equation (RLE) and direct inversion of iterative subspace (DIIS). Examples are presented for B, Al, Zn$^+$, and Yb$^+$. Solving these convergence problems greatly expands the number of atomic species that can be treated with the all-order methods and is anticipated to facilitate many interesting future applications.

physics.atom-ph↗

Hyperfine-mediated static polarizabilities of monovalent atoms and ions

We apply relativistic many-body methods to compute static differential polarizabilities for transitions inside the ground-state hyperfine manifolds of monovalent atoms and ions. Knowing this transition polarizability is required in a number of high-precision experiments, such as microwave atomic clocks and searches for CP-violating permanent electric dipole moments. While the traditional polarizability arises in the second-order of interaction with the externally-applied electric field, the differential polarizability involves additional contribution from the hyperfine interaction of atomic electrons with nuclear moments. We derive formulas for the scalar and tensor polarizabilities including contributions from magnetic dipole and electric quadrupole hyperfine interactions. Numerical results are presented for Al, Rb, Cs, Yb$^+$, Hg$^+$, and Fr.

physics.atom-ph↗

Differential Light Shift Cancellation in a Magnetic-Field-Insensitive Transition of $^{87}$Rb

We demonstrate near-complete cancellation of the differential light shift of a two-photon magnetic-field-insensitive microwave hyperfine (clock) transition in $^{87}$Rb atoms trapped in an optical lattice. Up to $95(2)%$ of the differential light shift is canceled while maintaining magnetic-field insensitivity. This technique should have applications in quantum information and frequency metrology.

quant-ph↗

Possibility of "magic" co-trapping of two atomic species in optical lattices

Much effort has been devoted to removing differential Stark shifts for atoms trapped in specially tailored "magic" optical lattices, but thus far work has focused on a single trapped atomic species. In this work, we extend these ideas to include two atomic species sharing the same optical lattice. We show qualitatively that, in particular, scalar J = 0 divalent atoms paired with non-scalar state atoms have the necessary characteristics to achieve such Stark shift cancellation. We then present numerical results on "magic" trapping conditions for 27Al paired with 87Sr, as well as several other divalent atoms.

physics.atom-ph↗

Axio-electric effect

Using the relativistic Hartree-Fock approximation, we calculate the rates of atomic ionization by absorption of axions of the energies up to 100 keV and for an arbitrary value of the axion mass. We present numerical results for atoms used in the low radioactive background searches of dark matter (e.g. Ar, Ge and Xe), as well as the analytical formula which fits numerical calculations for the absorption cross sections and can be applied for other atoms, molecules and condensed matter systems. Using the cross-sections for the axio-electric effect, we derive the counting rates induced by solar axions and set limits on the axion coupling constants.

hep-ph↗

Precision determination of weak charge of $^{133}$Cs from atomic parity violation

We discuss results of the most accurate to-date test of the low-energy electroweak sector of the standard model of elementary particles. Combining previous measurements with our high-precision calculations we extracted the weak charge of the 133Cs nucleus, Q_W = -73.16(29)_exp (20)_th [S.G. Porsev, K. Beloy, and A. Derevianko, Phys. Rev. Lett. {\bf 102}, 181601 (2009)]. The result is in perfect agreement with Q_W^{SM} predicted by the standard model, Q_W^{SM} =-73.16(3), and confirms energy-dependence (or running) of the electroweak interaction and places constraints on a variety of new physics scenarios beyond the standard model. In particular, we increase the lower limit on the masses of extra Z-bosons predicted by models of grand unification and string theories. This paper provides additional details to the Letter. We discuss large-scale calculations in the framework of the coupled-cluster method, including full treatment of single, double, and valence triple excitations. To determine the accuracy of the calculations we computed energies, electric-dipole amplitudes, and hyperfine-structure constants. An extensive comparison with high-accuracy experimental data was carried out.

hep-ph↗

Relativistic many-body calculation of low-energy dielectronic resonances in Be-like carbon

We apply relativistic configuration-interaction method coupled with many-body perturbation theory (CI+MBPT) to describe low-energy dielectronic recombination. We combine the CI+MBPT approach with the complex rotation method (CRM) and compute the dielectronic recombination spectrum for Li-like carbon recombining into Be-like carbon. We demonstrate the utility and evaluate the accuracy of this newly-developed CI+MBPT+CRM approach by comparing our results with the results of the previous high-precision study of the CIII system [Mannervik et al., Phys. Rev. Lett. 81, 313 (1998)].

physics.atom-ph↗

Upper Limit on the Magnetic Dipole Contribution to the 5p-8p Transition in Rb by Use of Ultracold Atom Spectroscopy

We report on hyperfine-resolved spectroscopic measurements of the electric-dipole forbidden 5$p_{3/2} \to 8p_{1/2}$ transition in a sample of ultracold $^{87}$Rb atoms. The hyperfine selection rules enable the weak magnetic-dipole (M1) contribution to the transition strength to be distinguished from the much stronger electric-quadrupole (E2) contribution. An upper limit on the M1 transition strength is determined that is about 50 times smaller than an earlier experimental determination. We also calculate the expected value of the M1 matrix element and find that it is less than the upper limit extracted from the experiment.

physics.atom-ph↗

Dynamic polarizabilities and related properties of clock states of ytterbium atom

We carry out relativistic many-body calculations of the static and dynamic dipole polarizabilities of the ground $6s^2 ^1S_0$ and the first excited $6s6p ^3P^o_0$ states of Yb. With these polarizabilities, we compute several properties of Yb relevant to optical lattice clocks operating on the $6s^2 ^1S_0 - 6s6p ^3P^o_0$ transition. We determine (i) the first four {\em magic} wavelengths of the laser field for which the frequency of the clock transition is insensitive to the laser intensity. While the first magic wavelength is known, we predict the second, the third and the forth magic wavelengths to be 551 nm, 465 nm, and 413 nm. (ii) We reevaluate the effect of black-body radiation on the frequency of the clock transition, the resulting clock shift at $T=300 \mathrm{K}$ being $-1.41(17)$ Hz. (iii) We compute long-range interatomic van der Waals coefficients (in a.u.) $C_6(6s^2 ^1S_0 +6s^2 ^1S_0) = 1909(160)$, $C_6(6s^2 ^1S_0 + 6s6p ^3P_0) =2709(338) $, and $C_6(6s6p ^3P_0 + 6s6p ^3P_0) =3886(360) $. Finally, we determine the atom-wall interaction coefficients (in a.u.), $C_3 (6s^2 ^1S_0) =3.34$ and $C_3 (6s6p ^3P_0) =3.68$. We also address and resolve a disagreement between previous calculations of the static polarizability of the ground state.

physics.atom-ph↗