arXiv subjects

A. F. Hebard

Publications and source records attributed to A. F. Hebard.

At least 19 recordsLinked to original sources

arXiv2018

Far-infrared absorption of undoped and Br-doped carbon nanofiber powder in stacked-cup cone configuration

We carried out room-temperature far-infrared (40--650~cm$^{-1}$) transmission measurements on undoped and bromine-doped powder samples of carbon nanofibers in stacked-cup cone geometry. The transmission spectra of both doped and undoped samples were fit to a Drude-Lorentz model. A single Drude component and a small bandgap (around 8~meV) semiconducting Lorentzian component along with 3 other Lorentz components were essential to get a good fit in the entire measured frequency range. A decreased metallic conductivity along with a red-shift of the lowest semiconducting gap was found after bromine doping. A significant decrease in the scattering rate upon heavy doping has been qualitatively explained as partial ordering of intercalated dopant ions. Absorption spectra were derived from the transmission spectra under the assumption of non-dispersive reflectance. These spectra were compared to Drude-Lorentz model absorption spectra. The free-carrier density of the n-type powder and the electronic mean free path were estimated and compared with previously reported values for single-walled nanotubes and pyrolytic graphite.

cond-mat.mes-hall↗

arXiv2018

Temperature evolution of polaron dynamics and Jahn-Teller distortion modes in strongly correlated La$_{0.67}$Ca$_{0.33}$MnO$_{3}$ manganite film

Reflectivity as a function of temperature for the La$_{0.67}$Ca$_{0.33}$MnO$_{3}$ (LCMO) film has been measured across the metal-insulator phase transition. The optical properties and their temperature dependence were determined in the infrared and visible range by fits to a Drude-Lorentz model, using exact formula for the thin film optics and the measured properties of the substrate. The phonon modes were identified and verified with lattice dynamical calculations for the ideal and distorted perovskite structure of the material. The optical conductivity shows agreement with the double exchange mechanism in conjunction with the Jahn-Teller distortion term in the Hamiltonian. Low temperature metallic phase is dominated by large polaron dynamics, a key component of electron-orbital coupling in a strongly corrrelated system. Free carrier dynamics in the metallic phase is described in terms of coherent heavy polaronic motion in the DC limit with incoherent and asymmetric polaronic background in the mid-IR range. The strength and line width of Jahn-Teller modes has been discussed across the phase transition and their temperature evolution is qualitatively discussed on account of existing electron-phonon coupling. The localized Holstein polaron formation in the high temperature insulative phase is identified as optical conductivity peaks in the visible range above the critical temperature.

cond-mat.str-el↗

arXiv2014

Unusual Shubnikov-de Haas oscillations in BiTeCl

We report measurements of Shubnikov-de Haas (SdH) oscillations in single crystals of BiTeCl at magnetic fields up to 31 T and at temperatures as low as 0.4 K. Two oscillation frequencies were resolved at the lowest temperatures, $F_{1}=65 \pm 4$ Tesla and $F_{2}=156 \pm 5$ Tesla. We also measured the infrared optical reflectance $\left(\cal R(ω)\right)$ and Hall effect; we propose that the two frequencies correspond respectively to the inner and outer Fermi sheets of the Rashba spin-split bulk conduction band. The bulk carrier concentration was $n_{e}\approx1\times10^{19}$ cm$^{-3}$ and the effective masses $m_{1}^{*}=0.20 m_{0}$ for the inner and $m_{2}^{*}=0.27 m_{0}$ for the outer sheet. Surprisingly, despite its low effective mass, we found that the amplitude of $F_{2}$ is very rapidly suppressed with increasing temperature, being almost undetectable above $T\approx4$ K.

cond-mat.mtrl-sci↗

arXiv2014

Temperature-driven band inversion in Pb$_{0.77}$Sn$_{0.23}$Se: Optical and Hall-effect studies

Optical and Hall-effect measurements have been performed on single crystals of Pb$_{0.77}$Sn$_{0.23}$Se, a IV-VI mixed chalcogenide. The temperature dependent (10--300 K) reflectance was measured over 40--7000 cm$^{-1}$ (5--870 meV) with an extension to 15,500 cm$^{-1}$ (1.92 eV) at room temperature. The reflectance was fit to the Drude-Lorentz model using a single Drude component and several Lorentz oscillators. The optical properties at the measured temperatures were estimated via Kramers-Kronig analysis as well as by the Drude-Lorentz fit. The carriers were p-type with the carrier density determined by Hall measurements. A signature of valence intraband transition is found in the low-energy optical spectra. It is found that the valence-conduction band transition energy as well as the free carrier effective mass reach minimum values at 100 K, suggesting temperature-driven band inversion in the material. Density function theory calculation for the electronic band structure also make similar predictions.

cond-mat.str-el↗

arXiv2013

Bulk Fermi surface and electronic properties of Cu$_{0.07}$Bi$_{2}$Se$_{3}$

The electronic properties of Cu$_{0.07}$Bi$_{2}$Se$_{3}$ have been investigated using Shubnikov-de Haas and optical reflectance measurements. Quantum oscillations reveal a bulk, three-dimensional Fermi surface with anisotropy $k^{c}_{F}/k^{ab}_{F}\approx$ 2 and a modest increase in free-carrier concentration and in scattering rate with respect to the undoped Bi$_{2}$Se$_{3}$, also confirmed by reflectivity data. The effective mass is almost identical to that of Bi$_{2}$Se$_{3}$. Optical conductivity reveals a strong enhancement of the bound impurity bands with Cu addition, suggesting that a significant number of Cu atoms enter the interstitial sites between Bi and Se layers or may even substitute for Bi. This conclusion is also supported by X-ray diffraction measurements, where a significant increase of microstrain was found in Cu$_{0.07}$Bi$_{2}$Se$_{3}$, compared to Bi$_{2}$Se$_{3}$.

cond-mat.mtrl-sci↗

arXiv2012

Temperature dependent infrared spectroscopy of the Rashba spin-splitting semiconductor BiTeI

We performed temperature dependent infrared spectroscopy measurements on BiTeI single crystals, which exhibit large Rashba spin-splitting. Similar to a previous optical study, we found electronic excitations in good agreement with spin-split electronic bands. In addition, we report a low energy intraband transition with an onset energy of about 40 meV and an unexpectedly large number of vibrational modes in the far-infrared spectral region. At least some of the modes have asymmetric Fano line-shape. These new observations cannot be explained considering only the bulk band structure or crystal symmetry of BiTeI, and we proposed that the optical response is also affected by the surface topology.

cond-mat.mtrl-sci↗

arXiv2012

Rectification at Graphene-Semiconductor Interfaces: Zero-Gap Semiconductor Based Diodes

Using current-voltage (I-V) and capacitance-voltage (C-V) measurements, we report on the unusual physics and promising technical applications associated with the formation of Schottky barriers at the interface of a one-atom-thick zero-gap semiconductor (graphene) and conventional semiconductors. When chemical vapor deposited graphene is transferred onto n-type Si, GaAs, 4H-SiC and GaN semiconductor substrates, there is a strong van der Waals attraction that is accompanied by charge transfer across the interface and the formation of a rectifying (Schottky) barrier. Thermionic emission theory in conjunction with the Schottky-Mott model within the context of bond-polarization theory provides a surprisingly good description of the electrical properties. Applications, such as to sensors where in forward bias there is exponential sensitivity to changes in the Schottky barrier height due to the presence of absorbates on the graphene or to analogue devices for which Schottky barriers are integral components are promising because of graphene's mechanical stability, its resistance to diffusion, its robustness at high temperatures and its demonstrated capability to embrace multiple functionalities.

cond-mat.mtrl-sci↗

arXiv2011

Ultrapure Multilayer Graphene in Bromine Intercalated Graphite

We investigate the optical properties of bromine intercalated highly orientated pyrolytic graphite (Br-HOPG) and provide a novel interpretation of the data. We observe new absorption features below 620 meV which are absent in the absorption spectrum of graphite. Comparing our results with those of theoretical studies on graphite, single and bilayer graphene as well as recent optical studies of multilayer graphene, we conclude that Br-HOPG contains the signatures of ultrapure bilayer, single layer graphene, and graphite. The observed supermetallic conductivity of Br-HOPG is identified with the presence of very high mobility (~ 121,000 cm2V-1s-1 at room temperature and at very high carrier density) multilayer graphene components in our sample. This could provide a new avenue for single and multilayer graphene research.

cond-mat.mtrl-sci↗

arXiv2010

Growth and characterization of multiferroic BiMnO$_3$ thin films

We have grown epitaxial thin films of multiferroic BiMnO$_3$ using pulsed laser deposition. The films were grown on SrTiO$_3$ (001) substrates by ablating a Bi-rich target. Using x-ray diffraction we confirmed that the films were epitaxial and the stoichiometry of the films was confirmed using Auger electron spectroscopy. The films have a ferromagnetic Curie temperature ($T_C$) of 85$\pm$5 K and a saturation magnetization of 1 $μ_B$/Mn. The electric polarization as a function of electric field ($P-E$) was measured using an interdigital capacitance geometry. The $P-E$ plot shows a clear hysteresis that confirms the multiferroic nature of the thin films.

cond-mat.mtrl-sci↗

arXiv2010

Asymmetric metal-insulator transition in disordered ferromagnetic films

We present experimental data and a theoretical interpretation on the conductance near the metal-insulator transition in thin ferromagnetic Gd films of thickness b approximately 2-10 nm. A large phase relaxation rate caused by scattering of quasiparticles off spin wave excitations renders the dephasing length L_phi < b in the range of sheet resistances considered, so that the effective dimension is d = 3. The observed approximate fractional temperature power law of the conductivity is ascribed to the scaling regime near the transition. The conductivity data as a function of temperature and disorder strength collapse on to two scaling curves for the metallic and insulating regimes. The best fit is obtained for a dynamical exponent z approximately 2.5 and a correlation length critical exponent ν' approximately 1.4 on the metallic side and a localization length exponent νapproximately 0.8 on the insulating side.

cond-mat.dis-nn↗

arXiv2010

Finite size effects with variable range exchange coupling in thin-film Pd/Fe/Pd trilayers

The magnetic properties of thin-film Pd/Fe/Pd trilayers in which an embedded ~1.5 A-thick ultrathin layer of Fe induces ferromagnetism in the surrounding Pd have been investigated. The thickness of the ferromagnetic trilayer is controlled by varying the thickness of the top Pd layer over a range from 8 A to 56 A. As the thickness of the top Pd layer decreases, or equivalently as the embedded Fe layer moves closer to the top surface, the saturated magnetization normalized to area and the Curie temperature decrease whereas the coercivity increases. These thickness-dependent observations for proximity-polarized thin-film Pd are qualitatively consistent with finite size effects that are well known for regular thin-film ferromagnets. The critical exponent $β$ of the order parameter (magnetization) is found to approach the mean field value of 0.5 as the thickness of the top Pd layer increases. The functional forms for the thickness dependences, which are strongly modified by the nonuniform exchange interaction in the polarized Pd, provide important new insights to understanding nanomagnetism in two-dimensions.

cond-mat.mes-hall↗

arXiv2009

Graphite based Schottky diodes formed on Si, GaAs and 4H-SiC substrates

We demonstrate the formation of semimetal graphite/semiconductor Schottky barriers where the semiconductor is either silicon (Si), gallium arsenide (GaAs) or 4H-silicon carbide (4H-SiC). Near room temperature, the forward-bias diode characteristics are well described by thermionic emission, and the extracted barrier heights, which are confirmed by capacitance voltage measurements, roughly follow the Schottky-Mott relation. Since the outermost layer of the graphite electrode is a single graphene sheet, we expect that graphene/semiconductor barriers will manifest similar behavior.

cond-mat.mtrl-sci↗

arXiv2009

Supermetallic conductivity in bromine-intercalated graphite

Exposure of highly oriented pyrolytic graphite to bromine vapor gives rise to in-plane charge conductivities which increase monotonically with intercalation time toward values (for ~6 at% Br) that are significantly higher than Cu at temperatures down to 5 K. Magnetotransport, optical reflectivity and magnetic susceptibility measurements confirm that the Br dopes the graphene sheets with holes while simultaneously increasing the interplanar separation. The increase of mobility (~ 5E4 cm^2/Vs at T=300 K) and resistance anisotropy together with the reduced diamagnetic susceptibility of the intercalated samples suggests that the observed supermetallic conductivity derives from a parallel combination of weakly-coupled hole-doped graphene sheets.

cond-mat.mtrl-sci↗

arXiv2009

Graphite in the bi-layer regime: in-plane transport

An interplay between the increase in the number of carriers and the decrease in the scattering time is expected to result in a saturation of the in-plane resistivity, $ρ_{ab}$, in graphite above room temperature. Contrary to this expectation, we observe a pronounced increase in $ρ_{ab}$ in the interval between 300 and 900 K. We provide a theory of this effect based on intervalley scattering of charge carriers by high-frequency, graphene-like optical phonons.

cond-mat.mtrl-sci↗

arXiv2009

Magnetodielectric Coupling in Nonmagnetic Au/GaAs:Si Schottky Barriers

We report on a heretofore unnoted giant negative magnetocapacitance (>20%) in non-magnetic Au/GaAs:Si Schottky barriers that we attribute to a magnetic field in-duced increase in the binding energy of the shallow donor Si impurity atoms. Depletion capacitance (Cdep) dispersion identifies the impurity ionization and capture processes that give rise to a magnetic field dependent density of ionized impurities. Internal photoemission experiments confirm that the large field-induced shifts in the built-in potential, inferred from 1/Cdep^2 vs voltage measurements, are not due to a field-dependent Schottky barrier height, thus requiring a modification of the abrupt junction approximation that accounts for the observed magnetodielectric coupling.

cond-mat.mtrl-sci↗

arXiv2009

Tunneling magnetoresistance in (La,Pr,Ca)MnO3 nanobridges

The manganite (La,Pr,Ca)MnO3 is well known for its micrometer scale phase separation into coexisting ferromagnetic metallic and antiferromagnetic insulating (AFI) regions. Fabricating bridges with widths smaller than the phase separation length scale has allowed us to probe the magnetic properties of individual phase separated regions. We observe tunneling magnetoresistance across naturally occurring AFI tunnel barriers separating adjacent ferromagnetic regions spanning the width of the bridges. Further, near the Curie temperature, a magnetic field induced metal-to-insulator transition among a discrete number of regions within the narrow bridges gives rise to abrupt and colossal low-field magnetoresistance steps at well defined switching fields.

cond-mat.mtrl-sci↗

arXiv2009

Intrinsic tunneling in phase separated manganites

We present evidence of direct electron tunneling across intrinsic insulating regions in sub-micrometer wide bridges of the phase separated ferromagnet (La,Pr,Ca)MnO$_3$. Upon cooling below the Curie temperature, a predominantly ferromagnetic supercooled state persists where tunneling across the intrinsic tunnel barriers (ITBs) results in metastable, temperature-independent, high-resistance plateaus over a large range of temperatures. Upon application of a magnetic field, our data reveal that the ITBs are extinguished resulting in sharp, colossal, low-field resistance drops. Our results compare well to theoretical predictions of magnetic domain walls coinciding with the intrinsic insulating phase.

cond-mat.str-el↗

arXiv2008

Spin-wave mediated quantum corrections to the conductivity in thin ferromagnetic gadolinium films

We present a study of quantum corrections to the conductivity of thin ferromagnetic gadolinium films. In situ magneto-transport measurements were performed on a series of thin films with thickness d < 135A. For sheet resistances R0 < 4011 Ohm and temperatures T < 30K, we observe a linear temperature dependence of the conductivity in addition to the logarithmic temperature dependence expected from well known quantum corrections in two dimensions. We show that such a linear T-dependence can arise from a spin-wave mediated Altshuler-Aronov type correction.

cond-mat.dis-nn↗