arXiv subjects

A. Fujimori

Publications and source records attributed to A. Fujimori.

At least 109 records · Page 6Linked to original sources

arXiv2010

Mass renormalization in the band width-controlled Mott-Hubbard systems SrVO3 and CaVO3 studied by angle-resolved photoemission spectroscopy

Ca1-xSrxVO3 is a Mott-Hubbard-type correlated electron system whose bandwidth can be varied by the V-O-V bond angle, but the actual effect of bandwidth control on the electronic structure has been controversial in previous photoemission experiments. In this work, band dispersions and Fermi surfaces of SrVO3 and CaVO3 are studied by angle-resolved photoemission spectroscopy. Near the Fermi level (EF), three bands forming cylindricalFermi surfaces derived from the three V 3d t2g orbitals have been observed. The observed band widths for both compounds are almost half of those predicted by local-density-approximation band-structure calculation, confirming mass renormalization caused by electron correlation. It has been clearly demonstrated that the width of the d band in CaVO3 is narrower than that in SrVO3, qualitatively consistent with the result of band-structure calculation. Roles of the orthorhombic lattice distortion and electron correlation in the observed band narrowing are discussed.

cond-mat.str-el↗

arXiv2010

Evolution of the electronic structure from the insulator to the superconductor in Bi2Sr2-xLax(Ca,Y)Cu2O8+d

La-doped and Y-doped Bi2Sr2CaCu2O8+d (Bi2212) compounds Bi2Sr2-xLax(Ca,Y)Cu2O8+d, which range from the insulator to the deeply underdoped superconductor, have been studied by angle-resolved photoemission spectroscopy. We have observed that the lower Hubbard band (LHB) of the parent insulator is gradually shifted upward with doping without significantly changing the band dispersions, which implies a downward shift of the chemical potential with hole doping. This behaviour is analogous to Bi2Sr2-xLaxCuO6+d (Bi2201) and Ca2-xNaxCuO2Cl2 (Na-CCOC) but is different from La2-xSrxCuO4 (LSCO), where the LHB stays well below the chemical potential and does not move while its intensity quickly diminishes in the underdoped region.

cond-mat.supr-con↗

arXiv2010

Characteristic electronic structure and its doping evolution in lightly-doped to underdoped YBa2Cu3Oy

We have performed an angle resolved photoemission spectroscopy (ARPES) study of lightly-doped to underdoped YBa2Cu3Oy (YBCO) untwinned single crystals and a core-level x-ray photoemission spectroscopy (XPS) study of YBCO single and polycrystals. In the zone diagonal (nodal) direction, dispersive quasi-particle (QP) features crossing the Fermi level were observed down to the hole concentration of ~ 4%, which explains the metallic transport of the lightly-doped YBCO. The chemical potential shift estimated from XPS was more rapid than in the Bi2212 cuprates. Upon hole doping, very rapid spectral weight transfer from high binding energies to the QP feature, even faster than La2-xSrxCuO4, was observed.

cond-mat.supr-con↗

arXiv2010

Indication of antiferromagnetic interaction between paramagnetic Co ions in the diluted magnetic semiconductor Zn$_{1-x}$Co$_{x}$O

The magnetic properties of Zn$_{1-x}$Co$_x$O ($x=0.07$ and 0.10) thin films, which were homo-epitaxially grown on a ZnO(0001) substrates with varying relatively high oxygen pressure, have been investigated using x-ray magnetic circular dichroism (XMCD) at Co $2p$ core-level absorption edge. The line shapes of the absorption spectra are the same in all the films and indicate that the Co$^{2+}$ ions substitute for the Zn sites. The magnetic-field and temperature dependences of the XMCD intensity are consistent with the magnetization measurements, indicating that except for Co there are no additional sources for the magnetic moment, and demonstrate the coexistence of paramagnetic and ferromagnetic components in the homo-epitaxial Zn$_{1-x}$Co$_{x}$O thin films, in contrast to the ferromagnetism in the hetero-epitaxial Zn$_{1-x}$Co$_{x}$O films studied previously. The analysis of the XMCD intensities using the Curie-Weiss law reveals the presence of antiferromagnetic interaction between the paramagnetic Co ions. Missing XMCD intensities and magnetization signals indicate that most of Co ions are non-magnetic probably because they are strongly coupled antiferromagnetically with each other. Annealing in a high vacuum reduces both the paramagnetic and ferromagnetic signals. We attribute the reductions to thermal diffusion and aggregation of Co ions with antiferromagnetic nanoclusters in Zn$_{1-x}$Co$_{x}$O.

cond-mat.mtrl-sci↗

arXiv2009

Chemical potential jump between hole- and electron-doped sides of ambipolar high-Tc cuprate

In order to study an intrinsic chemical potential jump between the hole- and electron-doped high-Tc superconductors, we have performed core-level X-ray photoemission spectroscopy (XPS) measurements of Y0.38La0.62Ba1.74La0.26Cu3Oy (YLBLCO), into which one can dope both holes and electrons with maintaining the same crystal structure. Unlike the case between the hole-doped system La_2-xSrxCuO4 and the electron-doped system Nd_2-xCexCuO4, we have estimated the true chemical potential jump between the hole- and electron-doped YLBLCO to be ~0.8 eV, which is much smaller than the optical gaps of 1.4-1.7 eV reported for the parent insulating compounds. We attribute the reduced jump to the indirect nature of the charge-excitation gap as well as to the polaronic nature of the doped carriers.

cond-mat.supr-con↗

arXiv2009

Bulk 5f electronic states in uranium monochalcogenide US

We have investigated the electronic states of the uranium monochalcogenide US, which is a typical ferromagnetic uranium compound, using soft x-ray photoemission spectroscopy (SX-PES). In early ultraviolet photoemission spectroscopy studies, two peak structures of the U 5f states were observed and have been interpreted that one has an itinerant character around the Fermi level (EF) and the other located below EF has a character of localized U 5f electrons. In this study, the intrinsic bulk valence-band spectrum of US was first deduced by estimating the contribution of surface states to the valence-band spectrum using core-level photoemission spectra. We conclude that the electronic structure of US can be basically described by the itinerant nature of the U 5f electrons from comparison with theoretical valence-band spectra obtained by band-structure calculation in the local-density approximation.

cond-mat.str-el↗

arXiv2009

4f-derived Fermi Surfaces of CeRu2(Si[1-x]Ge[x])2 near the Quantum Critical Point: Resonant Soft X-ray ARPES Study

Angle-resolved photoelectron spectroscopy in the Ce 3d-4f excitation region was measured for the paramagnetic state of CeRu2Si2, CeRu2(Si0.82Ge0.18)2, and LaRu2Si2 to investigate the changes of the 4$f$ electron Fermi surfaces around the quantum critical point. While the difference of the Fermi surfaces between CeRu2Si2 and LaRu2Si2 was experimentally confirmed, a strong 4f-electron character was observed in the band structures and the Fermi surfaces of CeRu2Si2 and CeRu2(Si0.82Ge0.18)2, consequently indicating a delocalized nature of the 4$f$ electrons in both compounds. The absence of Fermi surface reconstruction across the critical composition suggests that SDW quantum criticality is more appropriate than local quantum criticality in CeRu2(Si[1-x]Ge[x])2.

cond-mat.str-el↗

arXiv2009

Madelung potentials and covalency effect in strained La$_{1-x}$Sr$_x$MnO$_3$ thin films studied by core-level photoemission spectroscopy

We have investigated the shifts of the core-level photoemission spectra of La$_{0.6}$Sr$_{0.4}$MnO$_3$ thin films grown on three kinds of substrates, SrTiO$_3$, (LaAlO$_3$)$_{0.3}$-(SrAl$_{0.5}$Ta$_{0.5}$O$_3$)$_{0.7}$, and LaAlO$_3$. The experimental shifts of the La 4d and Sr 3d core levels are almost the same as the calculation, which we attribute to the absence of covalency effects on the Madelung potentials at these atomic sites due to the nearly ionic character of these atoms. On the other hand, the experimental shifts of the O $1s$ and Mn $2p$ core levels are negligibly small, in disagreement with the calculation. We consider that this is due to the strong covalent character of the Mn-O bonds.

cond-mat.str-el↗

arXiv2009

Enhanced superconducting gaps in the tri-layer high-$T_c$ cuprate Bi$_2$Sr$_2$Ca$_2$Cu$_3$O$_{10+δ}$

We have investigated the optimally doped tri-layer cuprate Bi$_2$Sr$_2$Ca$_2$Cu$_3$O$_{10+δ}$ (Bi2223) by angle-resolved photoemission spectroscopy, and observed energy bands and Fermi surfaces originated from the outer and inner CuO$_2$ planes (OP and IP) separately. The OP band is overdoped (hole density $\sim$ 0.26/Cu) with a large d-wave gap of $Δ_0$ $\sim$ 43 meV while the IP is underdoped ($\sim$ 0.06/Cu) with an even large gap of $Δ_0$ $\sim$ 60 meV. We propose that the enhancement of the $Δ_0$ of IP is due to the minimal influence of out-of-plane disorder and that the OP gap is then enhanced through interlayer coupling, most likely a proximity effect from the IP.

cond-mat.supr-con↗

arXiv2009

Coherent quasi-particles-to-incoherent hole-carriers crossover in underdoped cuprates

In underdoped cuprates, only a portion of the Fermi surface survives as Fermi arcs due to pseudogap opening. In hole-doped La$_{2}$CuO$_4$, we have deduced the "coherence temperature" $T_{coh}$ of quasi-particles on the Fermi arc above which the broadened leading edge position in angle-integrated photoemission spectra is shifted away from the Fermi level and the quasi-particle concept starts to lose its meaning. $T_{coh}$ is found to rapidly increase with hole doping, an opposite behavior to the pseudogap temperature $T^*$. The superconducting dome is thus located below both $T^*$ and $T_{coh}$, indicating that the superconductivity emerges out of the coherent Fermionic quasi-particles on the Fermi arc. $T_{coh}$ remains small in the underdoped region, indicating that incoherent charge carriers originating from the Fermi arc are responsible for the apparently metallic transport at high temperatures.

cond-mat.supr-con↗

arXiv2009

Effects of out-of-plane disorder on the nodal quasiparticle and superconducting gap in single-layer Bi$_2$Sr$_{1.6}Ln_{0.4}$CuO$_{6+δ}$ ($Ln$ = La, Nd, Gd)

How out-of-plane disorder affects the electronic structure has been investigated for the single-layer cuprates Bi$_2$Sr$_{1.6}$$Ln$$_{0.4}$CuO$_{6+δ}$ ($Ln$ = La, Nd, Gd) by angle-resolved photoemission spectroscopy. We have observed that, with increasing disorder, while the Fermi surface shape and band dispersions are not affected, the quasi-particle width increases, the anti-nodal gap is enhanced and the superconducting gap in the nodal region is depressed. The results indicate that the superconductivity is significantly depressed by out-of-plane disorder through the enhancement of the anti-nodal gap and the depression of the superconducting gap in the nodal region.

cond-mat.supr-con↗

arXiv2009

Electronic structure and magnetism of the diluted magnetic semiconductor Fe-doped ZnO nano-particles

We have studied the electronic structure of Zn$_{0.9}$Fe$_{0.1}$O nano-particles, which have been reported to show ferromagnetism at room temperature, by x-ray photoemission spectroscopy (XPS), resonant photoemission spectroscopy (RPES), x-ray absorption spectroscopy (XAS) and x-ray magnetic circular dichroism (XMCD). From the experimental and cluster-model calculation results, we find that Fe atoms are predominantly in the Fe$^{3+}$ ionic state with mixture of a small amount of Fe$^{2+}$ and that Fe$^{3+}$ ions are dominant in the surface region of the nano-particles. It is shown that the room temperature ferromagnetism in the Zn$_{0.9}$Fe$_{0.1}$O nano-particles is primarily originated from the antiferromagnetic coupling between unequal amounts of Fe$^{3+}$ ions occupying two sets of nonequivalent positions in the region of the XMCD probing depth of $\sim$ 2-3 nm.

cond-mat.mtrl-sci↗

arXiv2009

Underlying Fermi surface of Sr$_{14-x}$Ca$_x$Cu$_{24}$O$_{41}$ in two-dimensional momentum space observed by angle-resolved photoemission spectroscopy

We have performed an angle-resolved photoemission study of the two-leg ladder system Sr$_{14-x}$Ca$_x$Cu$_{24}$O$_{41}$ with $x$= 0 and 11. "Underlying Fermi surfaces" determined from low energy spectral weight mapping indicates the quasi-one dimensional nature of the electronic structure. Energy gap caused by the charge density wave has been observed for $x$=0 and the gap tends to close with Ca substitution. The absence of a quasi-particle peak even in $x$=11 is in contrast to the two-dimensional high-$T_c$ cuprates, implying strong carrier localization related to the hole crystalization.

cond-mat.str-el↗

arXiv2009

Differences in the high-energy kink between hole- and electron-doped high-$T_{\rm c}$ superconductors

We have performed an angle-resolved photoemission spectroscopy (ARPES) study of Nd$_{1.85}$Ce$_{0.15}$CuO$_{4}$ (NCCO) in order to elucidate the origin of the high-energy kink (HEK) observed in the high-$T_{\rm c}$ superconductors (HTSCs). The energy scale of the HEK in NCCO is large compared with that in hole-doped HTSCs, consistent with previous ARPES studies. From measurement in a wide momentum region, we have demonstrated that between the hole- and electron-doped HTSCs the energy position of the HEK is shifted approximately by the amount of the chemical potential difference. Also, we have found that around $(π, 0)$ the HEK nearly coincides with the band bottom while around the node the band reaches the incoherent region and the HEK appears at the boundary between the coherent and incoherent regions.

cond-mat.supr-con↗

arXiv2008

Universal versus Material-Dependent Two-Gap Behaviors in the High-Tc Cuprates: Angle-Resolved Photoemission Study of La2-xSrxCuO4

We have investigated the doping and temperature dependences of the pseudogap/superconducting gap in the single-layer cuprate La$_{2-x}$Sr$_x$CuO$_4$ by angle-resolved photoemission spectroscopy. The results clearly exhibit two distinct energy and temperature scales, namely, the gap around ($π$,0) of magnitude $Δ^*$ and the gap around the node characterized by the d-wave order parameter $Δ_0$, like the double-layer cuprate Bi2212. In comparison with Bi2212 having higher $T_c$'s, $Δ_0$ is smaller, while $Δ^*$ and $T^*$ are similar. This result suggests that $Δ^*$ and $T^*$ are approximately material-independent properties of a single CuO$_2$ plane, in contrast the material-dependent $Δ_0$, representing the pairing strength.

cond-mat.str-el↗

arXiv2008

Systematic tight-binding analysis of ARPES spectra of transition-metal oxides

We have performed systematic tight-binding (TB) analyses of the angle-resolved photoemission spectroscopy (ARPES) spectra of transition-metal (TM) oxides A$M$O$_3$ ($M=$ Ti, V, Mn, and Fe) with the perovskite-type structure and compared the obtained parameters with those obtained from configuration-interaction (CI) cluster-model analyses of photoemission spectra. The values of $ε_d-ε_p$ from ARPES are found to be similar to the charge-transfer energy $Δ$ from O $2p$ orbitals to empty TM 3d orbitals and much larger than $Δ-U/2$ ($U$: on-site Coulomb energy) expected for Mott-Hubbard-type compounds including SrVO$_3$. $ε_d-ε_p$ values from {\it ab initio} band-structure calculations show similar behaviors to those from ARPES. The values of the $p-d$ transfer integrals to describe the global electronic structure are found to be similar in all the estimates, whereas additional narrowing beyond the TB description occurs in the ARPES spectra of the $d$ band.

cond-mat.str-el↗

arXiv2008

Modulation Doping of a Mott Quantum Well by a Proximate Polar Discontinuity

We present evidence for hole injection into LaAlO3/LaVO3/LaAlO3 quantum wells near a polar surface of LaAlO3 (001). As the surface is brought in proximity to the LaVO3 layer, an exponential drop in resistance and a decreasing positive Seebeck coefficient is observed below a characteristic coupling length of 10-15 unit cells. We attribute this behavior to a crossover from an atomic reconstruction of the AlO2-terminated LaAlO3 surface to an electronic reconstruction of the vanadium valence. These results suggest a general approach to tunable hole-doping in oxide thin film heterostructures.

cond-mat.str-el↗

arXiv2008

Appearance of Universal Metallic Dispersion in a Doped Mott Insulator

We have investigated the dispersion renormalization $Z_{disp}$ in La$_{2-x}$Sr$_x$CuO$_4$ (LSCO) over the wide doping range of $x=0.03-0.30$, for binding energies extending to several hundred meV's. Strong correlation effects conspire in such a way that the system exhibits an LDA-like dispersion which essentially `undresses' ($Z_{disp}\to 1$) as the Mott insulator is approached. Our finding that the Mott insulator contains `nascent' or `preformed' metallic states with a vanishing spectral weight offers a challenge to existing theoretical scenarios for cuprates.

cond-mat.str-el↗