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A. Manchado

Publications and source records attributed to A. Manchado.

At least 37 records · Page 2Linked to original sources
arXiv2020

Petroleum, coal and other organics in space

The petroleum and coal models of the unidentified infrared emissions (UIE), sometimes referred also as unidentified infrared bands (UIBs) has been reviewed mainly based on the work of the authors with the inclusion of unpublished results. It is shown that the petroleum and coal model of the UIE converges and merges quite well with the MAON (Mixed Aromatic Aliphatic Organic Nanoparticles) model of the UIE. It is shown that the thermal treatment of various substrates like PAHs, alkylated PAHs but also mixed aliphatic/olefinic substrates leads invariable to carbonaceous materials matching the infrared spectrum of anthracite coal or certain petroleum fractions. Thus, the experimental thermal processing (which under space conditions could be equivalent to the expected processing by shock waves or high energy radiation) of mixed aromatic/aliphatic organic matter can be used to match also the UIE evolution. Another way to simulate the thermal/radiation processing of organic matter in space, can be achieved through the carbon arc. Simple substrates processed in this way produce carbon soot and a plethora of organic molecules. Fullerenes are found in space both through mid-infrared and optical spectroscopy and it is very likely that other complex related species such as endohedral fullerenes (i.e. fullerenes with a metal, heteroatom or molecules inside the cage) may be formed in space. After all, their formation requires the same conditions as those needed for fullerene formation provided that also a metal vapour (e.g. interstellar/circumstellar gas) is available. The last part of this review is thus dedicated to the recent results on the study and characterization of an endohedral C60 derivative containing lithium inside the cage.

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arXiv2019

The Central Star of NGC 2346 as a Clue to Binary Evolution through the Common Envelope Phase

We present an analysis of the binary central star of the planetary nebula NGC 2346 based on archival data from the International Ultraviolet Explorer (IUE), and new low- and high-resolution optical spectra (3700 - 7300Å). By including in the spectral analysis the contribution of both stellar and nebular continuum, we reconciled long-time discrepant UV and optical diagnostics and derive $E(B-V)=0.18\pm0.01$. We re-classified the companion star as A5IV by analyzing the wings of the Balmer absorption lines in the high-resolution ($R=67\,000$) optical spectra. Using the distance to the nebula of 1400 pc from Gaia DR2, we constructed a photoionization model based on abundances and line intensities derived from the low-resolution optical spectra, and obtained a temperature of $T_{\rm eff}=130\,000$K and a luminosity $L=170$L$_\odot$ for the ionizing star, consistent with the UV continuum. This analysis allows us to better characterize the binary system's evolution. We conclude that the progenitor star of NGC 2346 has experienced a common envelope phase, in which the companion star has accreted mass and evolved off the main-sequence.

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arXiv2019

H-band discovery of additional Second-Generation stars in the Galactic Bulge Globular Cluster NGC 6522 as observed by APOGEE and Gaia

We present elemental abundance analysis of high-resolution spectra for five giant stars, deriving Fe, Mg, Al, C, N, O, Si and Ce abundances, and spatially located within the innermost regions of the bulge globular cluster NGC 6522, based on H-band spectra taken with the multi-object APOGEE-north spectrograph from the SDSS-IV Apache Point Observatory Galactic Evolution Experiment (APOGEE) survey. Of the five cluster candidates, two previously unremarked stars are confirmed to have second-generation (SG) abundance patterns, with the basic pattern of depletion in C and Mg simultaneous with enrichment in N and Al as seen in other SG globular cluster populations at similar metallicity. } In agreement with the most recent optical studies, the NGC 6522 stars analyzed exhibit (when available) only mild overabundances of the s-process element Ce, contradicting the idea of the NGC 6522 stars being formed from gas enriched by spinstars and indicating that other stellar sources such as massive AGB stars could be the primary intra-cluster medium polluters. The peculiar abundance signature of SG stars have been observed in our data, confirming the presence of multiple generations of stars in NGC 6522.

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arXiv2019

Exploring circumstellar effects on the lithium and calcium abundances in massive Galactic O-rich AGB stars

We previously explored the circumstellar effects on the Rb and Zr abundances in massive Galactic O-rich AGB stars. Here we are interested in the role of the extended atmosphere in the case of Li and Ca. Li is an important indicator of HBB while the total Ca in these stars could be affected by neutron captures. The Li abundances were previously studied with hydrostatic models, while the Ca abundances have been determined for the first time. We use a modified version of Turbospectrum and consider the presence of a gaseous circumstellar envelope and radial wind. The new Li abundances derived with the pseudo-dynamical models are very similar to those obtained from hydrostatic models (the average difference is 0.18 dex), with no difference for Ca. The Li and Ca content in these stars is only slightly affected by the presence of a circumstellar envelope. We also found that the Li I and Ca I line profiles are not very sensitive to variations of the model wind parameters. The new Li abundances confirm the Li-rich nature of the sample stars, supporting the activation of HBB in massive Galactic AGB stars. This is in good agreement with the theoretical predictions for solar metallicity AGB models from ATON, Monash, and NuGrid/MESA but is at odds with the FRUITY database, which predicts no HBB leading to the production of Li. Most sample stars display nearly solar Ca abundances that are consistent with the available s-process nucleosynthesis models for solar metallicity massive AGB stars, which predict overproduction of 46Ca relatively to the other Ca isotope and the creation of the radiactive isotope 41Ca but no change in the total Ca abundance. A minority of the stars seem to show a significant Ca depletion (by up to 1.0 dex). Possible explanations are offered to explain their apparent and unexpected Ca depletion.

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arXiv2018

GTC/CanariCam mid-IR imaging of the fullerene-rich Planetary Nebula IC 418: searching for the spatial distribution of fullerene-like molecules

We present seeing-limited narrow-band mid-IR GTC/CanariCam images of the spatially extended fullerene-containing planetary nebula (PN) IC 418. The narrow-band images cover the C60 fullerene band at 17.4 μm, the polycyclic aromatic hydrocarbon like (PAH-like) feature at 11.3 μm, the broad 9-13 μm feature, and their adjacent continua at 9.8 and 20.5 μm. We study the relative spatial distribution of these complex species, all detected in the Spitzer and Infrared Space Observatory (ISO) spectra of IC 418, with the aim of getting observational constraints to the formation process of fullerenes in H-rich circumstellar environments. A similar ring-like extended structure is seen in all narrow-band filters, except in the dust continuum emission at 9.8 μm, which peaks closer to the central star. The continuum-subtracted images display a clear ring-like extended structure for the carrier of the broad 9-13 μm emission, while the spatial distribution of the (PAH-like) 11.3 μm emission is not so well defined. Interestingly, a residual C60 17.4 μm emission (at about 4-σ from the sky background) is seen when subtracting the dust continuum emission at 20.5 μm. This residual C60 emission, if real, might have several interpretations; the most exciting being perhaps that other fullerene-based species like hydrogenated fullerenes with very low H-content may contribute to the observed 17.4 μm emission. We conclude that higher sensitivity mid-IR images and spatially resolved spectroscopic observations (especially in the Q-band) are necessary to get some clues about fullerene formation in PNe.

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arXiv2017

Rubidium and zirconium abundances in massive Galactic asymptotic giant branch stars revisited

Luminous Galactic OH/IR stars have been identified as massive (>4-5 M_s) AGB stars experiencing HBB and Li production. Their Rb abundances and [Rb/Zr] ratios derived from hydrostatic model atmospheres, are significantly higher than predictions from AGB nucleosynthesis models, posing a problem to our understanding of AGB evolution and nucleosynthesis. We report new Rb and Zr abundances in the full sample of massive Galactic AGB stars, previously studied with hydrostatic models, by using more realistic extended model atmospheres. We use a modified version of the spectral synthesis code Turbospectrum and consider the presence of a circumstellar envelope and radial wind. The Rb and Zr abundances are determined from the 7800 A Rb I resonant line and the 6474 A ZrO bandhead, respectively, and we explore the sensitivity of the derived abundances to variations of the stellar (Teff) and wind (M_loss, beta and vexp) parameters in the extended models. The Rb and Zr abundances derived from the best spectral fits are compared with the most recent AGB nucleosynthesis theoretical models. The new Rb abundances are much lower (even 1-2 dex) than those derived with the hydrostatic models, while the Zr abundances are similar. The Rb I line profile and Rb abundance are very sensitive to the M_loss rate but much less sensitive to variations of the wind velocity-law and the vexp(OH). We confirm the earlier preliminary results based on a smaller sample of massive O-rich AGB stars, that the use of extended atmosphere models can solve the discrepancy between the AGB nucleosynthesis theoretical models and the observations of Galactic massive AGB stars. The Rb abundances, however, are still strongly dependent of the M_loss, which is unknown in these AGB stars. Accurate M_loss rates in these massive Galactic AGB stars are needed in order to break the models degeneracy and get reliable Rb abundances in these stars.

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arXiv2016

Rotating Stars and the Formation of Bipolar Planetary Nebulae II: Tidal Spin-up

We present new binary stellar evolution models that include the effects of tidal forces, rotation, and magnetic torques with the goal of testing Planetary Nebulae (PNe) shaping via binary interaction. We explore whether tidal interaction with a companion can spin up the AGB envelope. To do so we have selected binary systems with main sequence masses of 2.5 \Mo and of 0.8 \Mo and evolve them allowing initial separations of 5, 6, 7, and 8 AU. The binary stellar evolution models have been computed all the way to the PNe formation phase or until Roche lobe overflow (RLOF) is reached, whatever happens first. We show that with initial separations of 7 and 8 AU, the binary avoids entering into RLOF, and the AGB star reaches moderate rotational velocities at the surface ($\sim 3.5 $ and $\sim 2 $ \kms respectively) during the inter-pulse phases, but after the thermal pulses it drops to a final rotational velocity of only $\sim 0.03 $ \kms. For the closest binary separations explored, 5 and 6 AU, the AGB star reaches rotational velocities of $\sim 6 $ and $\sim 4 $ \kms respectively when the RLOF is initiated. We conclude that the detached binary models that avoid entering the RLOF phase during the AGB will not shape bipolar PNe, since the acquired angular momentum is lost via the wind during the last two thermal pulses. This study rules out tidal spin-up in non-contact binaries as a sufficient condition to form bipolar PNe.

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arXiv2016

On the formation of molecules and solid-state compounds from the AGB to the PN phases

During the asymptoyic giant branch (AGB) phase, different elements are dredge-up to the stellar surface depending on progenitor mass and metallicity. When the mass loss increases at the end of the AGB, a circumstellar dust shell is formed, where different (C-rich or O-rich) molecules and solid-state compounds are formed. These are further processed in the transition phase between AGB stars and planetary nebulae (PNe) to create more complex organic molecules and inorganic solid-state compounds (e.g., polycyclic aromatic hydrocarbons, fullerenes, and graphene precursors in C-rich environments and oxides and crystalline silicates in O-rich ones). We present an observational review of the different molecules and solid-state materials that are formed from the AGB to the PN phases. We focus on the formation routes of complex fullerene (and fullerene-based) molecules as well as on the level of dust processing depending on metallicity.

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arXiv2016

A search for hydrogenated fullerenes in fullerene-containing planetary nebulae

Detections of C60 and C70 fullerenes in planetary nebulae (PNe) of the Magellanic Clouds and of our own Galaxy have raised the idea that other forms of carbon such as hydrogenated fullerenes (fulleranes like C60H36 and C60H18), buckyonions, and carbon nanotubes, may be widespread in the Universe. Here we present VLT/ISAAC spectra (R ~600) in the 2.9-4.1 microns spectral region for the Galactic PNe Tc 1 and M 1-20, which have been used to search for fullerene-based molecules in their fullerene-rich circumstellar environments. We report the non-detection of the most intense infrared bands of several fulleranes around ~3.4-3.6 microns in both PNe. We conclude that if fulleranes are present in the fullerene-containing circumstellar environments of these PNe, then they seem to be by far less abundant than C60 and C70. Our non-detections together with the (tentative) fulleranes detection in the proto-PN IRAS 01005+7910 suggest that fulleranes may be formed in the short transition phase between AGB stars and PNe but they are quickly destroyed by the UV radiation field from the central star.

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arXiv2015

New H-band Stellar Spectral Libraries for the SDSS-III/APOGEE survey

The Sloan Digital Sky Survey--III (SDSS--III) Apache Point Observatory Galactic Evolution Experiment (APOGEE) has obtained high resolution (R $\sim$ 22,500), high signal-to-noise ratio ($>$ 100) spectra in the H$-$band ($\sim$1.5$-$1.7 $μ$m) for about 146,000 stars in the Milky Way galaxy. We have computed spectral libraries with effective temperature ($T\rm{_{eff}}$) ranging from 3500 to 8000 K for the automated chemical analy\-sis of the survey data. The libraries, used to derive stellar parameters and abundances from the APOGEE spectra in the SDSS--III data release 12 (DR12), are based on ATLAS9 model atmospheres and the ASS$ε$T spectral synthesis code. We present a second set of libraries based on MARCS model atmospheres and the spectral synthesis code Turbospectrum. The ATLAS9/ASS$ε$T ($T\rm{_{eff}}$ = 3500$-$8000 K) and MARCS/Turbospectrum ($T\rm{_{eff}}$ = 3500$-$5500 K) grids cover a wide range of metallicity ($-$2.5 $\leq$ [M/H] $\leq$ $+$0.5 dex), surface gravity (0 $\leq$ log $g$ $\leq$ 5 dex), microturbulence (0.5 $\leq$ $ξ$ $\leq$ 8 km~s$^{-1}$), carbon ($-$1 $\leq$ [C/M] $\leq$ $+$1 dex), nitrogen ($-$1 $\leq$ [N/M] $\leq$ $+$1 dex), and $α$-element ($-$1 $\leq$ [$α$/M] $\leq$ $+$1 dex) variations, having thus seven dimensions. We compare the ATLAS9/ASS$ε$T and MARCS/Turbospectrum libraries and apply both of them to the analysis of the observed H$-$band spectra of the Sun and the K2 giant Arcturus, as well as to a selected sample of well-known giant stars observed at very high-resolution. The new APOGEE libraries are publicly available and can be employed for chemical studies in the H$-$band using other high-resolution spectrographs.

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arXiv2014

A search for diffuse bands in fullerene planetary nebulae: evidence of diffuse circumstellar bands

Large fullerenes and fullerene-based molecules have been proposed as carriers of diffuse interstellar bands (DIBs). The recent detection of the most common fullerenes (C60 and C70) around some planetary nebulae (PNe) now enable us to study the DIBs towards fullerene-rich space environments. We search DIBs in the optical spectra towards three fullerene-containing PNe (Tc 1, M 1-20, and IC 418). Special attention is given to DIBs which are found to be unusually intense towards these fullerene sources. In particular, an unusually strong 4428A absorption feature is a common charateristic of fullerene PNe. Similar to Tc 1, the strongest optical bands of neutral C60 are not detected towards IC 418. Our high-quality (S/N > 300) spectra for PN Tc 1, together with its large radial velocity, permit us to search for the presence of diffuse bands of circumstellar origin, which we refer to as diffuse circumstellar bands (DCBs). We report the first tentative detection of two DCBs at 4428 and 5780 A in the fullerene-rich circumstellar environment around the PN Tc 1. Laboratory and theoretical studies of fullerenes in their multifarious manifestations (carbon onions, fullerene clusters, or even complex species formed by fullerenes and other molecules like PAHs or metals) may help solve the mystery of some of the diffuse band carriers.

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arXiv2014

Circumstellar effects on the Rb abundances in O-rich AGB stars

For the first time we explore the circumstellar effects on the Rb (and Zr) abundance determination in O-rich asymptotic giant branch (AGB) stars by considering the presence of a gaseous circumstellar envelope with a radial wind. A modified version of the spectral synthesis code Turbospectrum was used to deal with extended atmosphere models and velocity fields. The Rb and Zr abundances were determined from the resonant 7800A Rb I line and the 6474A ZrO bandhead, respectively, in five representative O-rich AGB stars with different expansion velocity and metallicity. By using our new dynamical models, the Rb I line profile (photospheric and circumstellar components) is very well reproduced. Interestingly, the derived Rb abundances are much lower (by 1-2 dex) in those O-rich AGB stars showing the higher circumstellar expansion velocities. The Zr abundances, however, remain close to the solar values. The Rb abundances and Rb/Zr ratios derived here significantly alleviate the problem of the present mismatch between the observations of intermediate-mass (4-8 solar masses) Rb-rich AGB stars and the AGB nucleosynthesis theoretical predictions.

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arXiv2014

Single Rotating Stars and the Formation of Bipolar Planetary Nebula

We have computed new stellar evolution models that include the effects of rotation and magnetic torques under different hypothesis. The goal is to test if a single star can sustain in the envelope the rotational velocities needed for the magneto hydrodynamical (MHD) simulations to shape bipolar Planetary Nebulae (PNe) when the high mass-loss rates take place. Stellar evolution models with main sequence masses of 2.5 and 5 Mo, and initial rotational velocities of 250 km/s have been followed all the way to the PNe formation phase. We find that stellar cores have to be spun down using magnetic torques in order to reproduce the rotation rates observed for white dwarfs. During the asymptotic giant branch phase and beyond, the magnetic braking of the core has a practically null effect in increasing the rotational velocity of the envelope since the stellar angular momentum is removed efficiently by the wind. We have, as well, tested best possible case scenarios in rather non-physical contexts to give enough angular momentum to the envelope. We find that we cannot get the envelope of a single star rotating at the speeds needed by the MHD simulations to form bipolar PNe. We conclude that single stellar rotators are unlikely to be the progenitors of bipolar PNe under the current MHD model paradigm.

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arXiv2013

Spectroscopy of fullerenes, fulleranes and PAHs in the UV, visible and near infrared spectral range

The spectra of fullerenes C60 and C70, higher fullerenes C76, C78 and C84 and hydrogenated fullerenes (fulleranes) were studied in laboratory in the UV and in the visible spectral range and could be used for searching and recognizing these molecules in space. Furthermore, the radical cation spectra of all the mentioned fullerene series and also of a series of large and very large polycyclic aromatic hydrocarbons (PAHs) were generated in laboratory and studied in the near infrared spectral range.

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arXiv2013

Infrared spectroscopy of fullerene C60/anthracene adducts

Recent Spitzer Space Telescope observations of several astrophysical environments such as Planetary Nebulae, Reflection Nebulae, and R Coronae Borealis stars show the simultaneous presence of mid-infrared features attributed to neutral fullerene molecules (i.e., C60) and polycyclic aromatic hydrocarbons (PAHs). If C60 fullerenes and PAHs coexist in fullerene-rich space environments, then C60 may easily form adducts with a number of different PAH molecules; at least with catacondensed PAHs. Here we present the laboratory infrared spectra (~2-25 um) of C60 fullerene and anthracene Dies-Alder mono- and bis-adducts as produced by sonochemical synthesis. We find that C60/anthracene Diels-Alder adducts display spectral features strikingly similar to those from C60 (and C70) fullerenes and other unidentified infrared emission features. Thus, fullerene-adducts - if formed under astrophysical conditions and stable/abundant enough - may contribute to the infrared emission features observed in fullerene-containing circumstellar/interstellar environments.

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arXiv2013

The changing nebula around the hot R Coronae Borealis star DY Centauri

Among the distinguishing characteristics of the remarkable hot R Coronae Borealis star DY Cen, which was recently found to be a spectroscopic binary, is the presence of nebular forbidden lines in its optical spectrum. A compilation of photometry from 1970 to the present suggests that the star has evolved to higher effective temperatures. Comparison of spectra from 2010 with earlier spectra show that between 2003 and 2010, the 6717 and 6730 A emission lines of [S II] underwent a dramatic change in their fluxes suggesting an increase in the nebula's electron density of 290 cm-3 to 3140 cm-3 from 1989 to 2010 while the stellar temperature increased from 19500 K to 25000 K. The nebular radius is about 0.02 pc, 60000 times bigger than the semimajor axis of DY Cen binary system. Rapid changes of stellar temperature and its response by the nebula demonstrate stellar evolution in action.

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arXiv2012

Far- and mid-infrared spectroscopy of complex organic matter of astrochemical interest: coal, heavy petroleum fractions, and asphaltenes

The coexistence of a large variety of molecular species (i.e., aromatic, cycloaliphatic and aliphatic) in several astrophysical environments suggests that unidentified IR emission (UIE) occurs from small solid particles containing a mix of aromatic and aliphatic structures (e.g., coal, petroleum, etc.), renewing the astronomical interest on this type of materials. A series of heavy petroleum fractions namely DAE, RAE, BQ-1, and asphaltenes derived from BQ-1 were used together with anthracite coal and bitumen as model compounds in matching the band pattern of the emission features of proto-planetary nebulae (PPNe). All the model materials were examined in the mid-infrared (2.5-16.7 um) and for the first time in the far-infrared (16.7-200 um), and the IR bands were compared with the UIE from PPNe. The best match of the PPNe band pattern is offered by the BQ-1 heavy aromatic oil fraction and by its asphaltenes fraction. Particularly interesting is the ability of BQ-1 to match the band pattern of the aromatic-aliphatic C-H stretching bands of certain PPNe, a result which is not achieved neither by the coal model nor by the other petroleum fractions considered here. This study shows that a new interesting molecular model of the emission features of PPNe are asphaltene molecules which are composed by an aromatic core containing 3-4 condensed aromatic rings surrounded by cycloaliphatic (naphtenic) and aliphatic alkyl chains. It is instead shown the weakness of the model involving a mixture of PAHs for modeling the aromatic IR emission bands. The laboratory spectra of these complex organic compounds represent a unique data set of high value for the astronomical community; e.g., they may be compared with the Herschel Space Observatory spectra (~51-220 um) of several astrophysical environments such as (proto-) PNe, H II regions, reflection nebulae, star forming galaxies, and young stellar objects.

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