arXiv subjects

A. V. Pronin

Publications and source records attributed to A. V. Pronin.

At least 19 recordsLinked to original sources

arXiv2025

Optical conductivity and band gap in the double-Weyl candidate SrSi2 at ambient pressure

We probe the possible double-Weyl state in cubic SrSi2 using optical spectroscopy. The complex optical conductivity was measured in a frequency range from 70 to 22 000 cm-1 at temperatures down to 10 K at ambient pressure. The optical response of SrSi2 can be well separated into the intraband (free carriers) and interband contributions. Additionally, four infrared-active phonons are detected. As follows from the optical spectra, the free-carrier density decreases with decreasing temperature, consistent with an activation behaviour. Experimental interband conductivity juxtaposed with ab initio calculations shows that conventional density-functional theory fails to describe the electronic structure of SrSi2 in the vicinity of the Fermi level. A semi-local exchange-correlation potential allows a much better agreement with the experiment, resulting in the trivial (gapped) band structure of SrSi2. The direct gap estimated from the measurements is approximately 40 meV.

cond-mat.mes-hall↗

arXiv2024

Interlayer charge transfer induced by electronic instabilities in the natural van der Waals hetrostructure 4H$_b$-TaS$_2$

The natural van der Waals heterostructure 4H$_b$-TaS$_2$ composed of alternating 1T- and 1H-TaS$_2$ layers serves as a platform for investigating the electronic correlations and layer-dependent properties of novel quantum materials. The temperature evolution of the conductivity spectra $σ(ω)$ obtained through infrared spectroscopy elucidates the influence of band modifications associated with the charge-density-wave (CDW) superlattice on the 1T layer, resulting in a room-temperature energy gap, $Δ_{\rm CDW}\approx$ 0.35 eV. However, there is no gap associated to the 1H layer. Supported by density functional theory calculations, we attribute the behavior of interband transitions to the convergence of the layers, which amplifies the charge transfer from the 1T to the 1H layers, progressing as the temperature decreases. This phenomenon leads to an enhanced low-energy spectral weight and carrier density. The presence of an energy gap and the temperature-tunable charge transfer within the bulk of 4H$_b$-TaS$_2$ driven by layer-dependent CDW states contribute to a more comprehensive understanding of other complex compounds of transition-metal dichalcogenides.

cond-mat.mes-hall↗

arXiv2024

Intriguing Low-Temperature Phase in the Antiferromagnetic Kagome Metal FeGe

The properties of kagome metals are governed by the interdependence of band topology and electronic correlations resulting in remarkably rich phase diagrams. Here, we study the temperature evolution of the bulk electronic structure of the antiferromagnetic kagome metal FeGe using infrared spectroscopy. We uncover drastic changes in the low-energy interband absorption at the 100 K structural phase transition that has been linked to a charge-density-wave (CDW) instability. We explain this effect by the minuscule Fe displacement in the kagome plane, which results in parallel bands in the vicinity of the Fermi level. In contrast to conventional CDW materials, however, the spectral weight shifts to low energies, ruling out the opening of a CDW gap in FeGe.

cond-mat.str-el↗

arXiv2023

Magneto-optical response of the Weyl semimetal NbAs: Experimental results and hyperbolic-band computations

The magneto-optical properties of (001)-oriented NbAs single crystals have been studied in the spectral range from 5 to 150 meV and in magnetic fields of up to 13 T. A rich spectrum of inter-Landau-level transitions is revealed by these measurements. The transitions follow a square-root-like dependence with magnetic field, but the simple linear-band approximation is unable to accurately reproduce the observed behavior of the transitions in applied fields. We argue that the detected magneto-optical spectra should be related to crossing hyperbolic bands, which form the W1 cones. We propose a model Hamiltonian, which describes coupled hyperbolic bands and reproduces the shape of the relevant bands in NbAs. The magneto-optical spectra computed from this Hamiltonian nicely reproduce our observations. We conclude that the hyperbolic-band approach is a minimal model to adequately describe the magneto-optical response of NbAs and that the chiral (conical) bands do not explicitly manifest themselves in the spectra.

cond-mat.mes-hall↗

arXiv2023

Exchange gap in GdPtBi probed by magneto-optics

We measured the magneto-reflectivity spectra (4 - 90 meV, 0 - 16 T) of the triple-point semimetal GdPtBi and found them to demonstrate two unusual broad features emerging in field. The electronic bands of GdPtBi are expected to experience large exchange-mediated shifts, which lends itself to a description via effective Zeeman splittings with a large g factor. Based on this approach, along with an ab initio band structure analysis, we propose a model Hamiltonian that describes our observations well and allows us to estimate the effective g factor, g* = 95. We conclude that we directly observe the exchange-induced $Γ_{8}$ band inversion in GdPtBi by means of infrared spectroscopy.

cond-mat.mes-hall↗

arXiv2021

Broadband optical conductivity of the chiral multifold semimetal PdGa

We present an optical conductivity study of the multifold semimetal PdGa, performed in a broad spectral range (100 - 20000 cm-1; 12 meV - 2.5 eV) down to T = 10 K. The conductivity at frequencies below 4000 cm-1 is dominated by free carriers while at higher frequencies interband transitions provide the major contribution. The spectra do not demonstrate a significant temperature evolution: only the intraband part changes as a function of temperature with the plasma frequency remaining constant. The interband contribution to the conductivity exhibits a broad peak at around 5500 cm-1 and increases basically monotonously at frequencies above 9000 cm-1. The band-structure-based computations reproduce these features of the interband conductivity and predict its linear-in-frequency behavior as frequency diminishes.

cond-mat.mes-hall↗

arXiv2020

Revealing excess protons in the infrared spectrum of liquid water

The most common species in liquid water, next to neutral H$_2$O molecules, are the H$_3$O$^+$ and OH$^-$ ions. In a dynamic picture, their exact concentrations depend on the time scale at which these are probed. Here, using a spectral-weight analysis, we experimentally resolve the fingerprints of the elusive fluctuations-born short-living H$_3$O$^+$, DH$_2$O$^+$, HD$_2$O$^+$, and D$_3$O$^+$ ions in the IR spectra of light (H$_2$O), heavy (D$_2$O), and semi-heavy (HDO) water. We find that short-living ions, with concentrations reaching $\sim 2\%$ of the content of water molecules, coexist with long-living pH-active ions on the picosecond timescale, thus making liquid water an effective ionic liquid in femtochemistry.

cond-mat.mtrl-sci↗

arXiv2020

Magneto-optics of a Weyl semimetal beyond the conical band approximation: the case study of TaP

Landau-level spectroscopy, the optical analysis of electrons in materials subject to a strong magnetic field, is a versatile probe of the electronic band structure and has been successfully used in the identification of novel states of matter such as Dirac electrons, topological materials or Weyl semimetals. The latter arise from a complex interplay between crystal symmetry, spin-orbit interaction and inverse ordering of electronic bands. Here, we report on unusual Landau-level transitions in the monopnictide TaP that decrease in energy with increasing magnetic field. We show that these transitions arise naturally at intermediate energies in time-reversal-invariant Weyl semimetals where the Weyl nodes are formed by a partially gapped nodal-loop in the band structure. We propose a simple theoretical model for electronic bands in these Weyl materials that captures the collected magneto-optical data to great extent.

cond-mat.mes-hall↗

arXiv2020

Optical conductivity of multifold fermions: the case of RhSi

We measured the reflectivity of the multifold semimetal RhSi in a frequency range from 80 to 20000 cm$^{-1}$ (10 meV - 2.5 eV) at temperatures down to 10 K. The optical conductivity, calculated from the reflectivity, is dominated by the free-carrier (Drude) contribution below 1000 cm$^{-1}$ (120 meV) and by interband transitions at higher frequencies. The temperature-induced changes in the spectra are generally weak: only the Drude bands narrow upon cooling, with an unscreened plasma frequency that is constant with temperature at approximately 1.4 eV, in agreement with a weak temperature dependence of the free-carrier concentration determined by Hall measurements. The interband portion of conductivity exhibits two linear-in-frequency regions below 5000 cm$^{-1}$ ($\sim$ 600 meV), a broad flat maximum at around 6000 cm$^{-1}$ (750 meV), and a further increase starting around 10000 cm$^{-1}$ ($\sim$ 1.2 eV). We assign the linear behavior of the interband conductivity to transitions between the linear bands near the band crossing points. Our findings are in accord with the predictions for the low-energy conductivity behavior in multifold semimetals and with earlier computations based on band structure calculations for RhSi.

cond-mat.mes-hall↗

arXiv2020

Nodal Semimetals: A Survey on Optical Conductivity

Among different topological and related phases of condensed matter, nodal semimetals occupy a special place - the electronic band topology in these materials is related to three-dimensional bulk, rather than to surface, states. A great variety of different realizations of electronic band crossings (the nodes) leads to a plethora of different electronic properties, ranging from the chiral anomaly to solid-state realizations of a black-hole horizon. The different nodal phases have similar low-energy band structure and quasiparticle dynamics, which both can be accessed experimentally by a number of methods. Optical measurements with their large penetration depth and high energy resolution are ideally suited as such a bulk probe; especially at low energies where other spectroscopic methods often lack the required resolution. In this contribution, we review recent optical-conductivity studies of different nodal semimetals, discuss possible limitations of such measurements, and provide a comparison between the experimental results, simple theoretical models, and band-structure-based calculations.

cond-mat.mes-hall↗

arXiv2019

Magneto-optical probe of the fully gapped Dirac band in ZrSiS

We present a far-infrared magneto-optical study of the gapped nodal-line semimetal ZrSiS in magnetic fields $B$ up to 7 T. The observed field-dependent features, which represent intra- (cyclotron resonance) and interband transitions, develop as $\sqrt{B}$ in increasing field and can be consistently explained within a simple 2D Dirac band model with a gap of 26 meV and an averaged Fermi velocity of $3\times10^{5}$ m/s. This indicates a rather narrow distribution of these parameters along the in-plane portions of the nodal line in the Brillouin zone. A field-induced feature with an energy position that does not depend on $B$ is also detected in the spectra. Possible origins of this feature are discussed.

cond-mat.mes-hall↗

arXiv2018

Linear-in-frequency optical conductivity in GdPtBi due to transitions near the triple points

The complex optical conductivity of the half-Heusler compound GdPtBi is measured in a frequency range from 20 to 22 000 cm$^{-1}$ (2.5 meV - 2.73 eV) at temperatures down to 10 K in zero magnetic field. We find the real part of the conductivity, $σ_{1}(ω)$, to be almost perfectly linear in frequency over a broad range from 50 to 800 cm$^{-1}$ ($\sim$ 6 - 100 meV) for $T \leq 50$ K. This linearity strongly suggests the presence of three-dimensional linear electronic bands with band crossings (nodes) near the chemical potential. Band-structure calculations show the presence of triple points, where one doubly degenerate and one nondegenerate band cross each other in close vicinity of the chemical potential. From a comparison of our data with the optical conductivity computed from the band structure, we conclude that the observed nearly linear $σ_{1}(ω)$ originates as a cumulative effect from all the transitions near the triple points.

cond-mat.mes-hall↗

arXiv2018

Optical conductivity of the Weyl semimetal NbP

The optical properties of (001)-oriented NbP single crystals have been studied in a wide spectral range from 6 meV to 3 eV from room temperature down to 10 K. The itinerant carriers lead to a Drude-like contribution to the optical response; we can further identify two pronounced phonon modes and interband transitions starting already at rather low frequencies. By comparing our experimental findings to the calculated interband optical conductivity, we can assign the features observed in the measured conductivity to certain interband transitions. In particular, we find that transitions between the electronic bands spilt by spin-orbit coupling dominate the interband conductivity of NbP below 100 meV. At low temperatures, the momentum-relaxing scattering rate of the itinerant carriers in NbP is very small, leading to macroscopic characteristic length scales of the momentum relaxation of approximately 0.5 $μ$m.

cond-mat.mes-hall↗

arXiv2017

Flat optical conductivity in ZrSiS due to two-dimensional Dirac bands

ZrSiS exhibits a frequency-independent interband conductivity $σ(ω) = \rm{const}(ω) \equiv σ_{\rm{flat}}$ in a broad range from 250 to 2500 cm$^{-1}$ (30 - 300 meV). This makes ZrSiS similar to (quasi)two-dimensional Dirac electron systems, such as graphite and graphene. We assign the flat optical conductivity to the transitions between quasi-two-dimensional Dirac bands near the Fermi level. In contrast to graphene, $σ_{\rm{flat}}$ is not supposed to be universal but related to the length of the nodal line in the reciprocal space, $k_{0}$. When $σ_{\rm{flat}}$ and $k_{0}$ are connected by a simple model, we find good agreement between experiment and theory. Due to the spin-orbit coupling, the discussed Dirac bands in ZrSiS possess a small gap $Δ$, for which we determine an upper bound max($Δ$) = 30 meV from our optical measurements. At low temperatures the momentum-relaxation rate collapses, and the characteristic length scale of momentum relaxation is of the order of microns below 50 K.

cond-mat.mes-hall↗

arXiv2017

Two-channel conduction in YbPtBi

We investigated transport, magnetotransport, and broadband optical properties of the half-Heusler compound YbPtBi. Hall measurements evidence two types of charge carriers: highly mobile electrons with a temperature-dependent concentration and low-mobile holes; their concentration stays almost constant within the investigated temperature range from 2.5 to 300 K. The optical spectra (10 meV - 2.7 eV) can be naturally decomposed into contributions from intra- and interband absorption processes, the former manifesting themselves as two Drude bands with very different scattering rates, corresponding to the charges with different mobilities. These results of the optical measurements allow us to separate the contributions from electrons and holes to the total conductivity and to implement a two-channel-conduction model for description of the magnetotransport data. In this approach, the electron and hole mobilities are found to be around 50000 and 10 cm$^{2}$/Vs at the lowest temperatures (2.5 K), respectively.

cond-mat.str-el↗

arXiv2017

Reentrant phases in electron-doped $\text{EuFe}_2\text{As}_2$: spin glass and superconductivity

We report evidence for a reentrant spin glass phase in electron-doped $\text{EuFe}_2\text{As}_2$ single crystals and first traces of the superconductivity re-entrance in optics. In the close-to-optimal doped $\text{Eu}(\text{Fe}_{0.91}\text{Ir}_{0.09})_2\text{As}_2$ and $\text{Eu}(\text{Fe}_{0.93}\text{Rh}_{0.07})_2\text{As}_2$ samples two magnetic transitions are observed below the superconducting critical temperature $T_c \approx 21$~K: the canted $A$-type antiferromagnetic order of the $\text{Eu}^{2+}$ ions sets in around $17\,\text{K}$; the spin glass behavior occurs another $2\,\text{K}$ lower in temperature. In addition, strong evidence for an additional transition is found far below the spin glass temperature. Our extensive optical and magnetic investigations provide new insight into the interplay of local magnetism and superconductivity in these systems and elucidate the effect of the spin-glass phase on the reentrant superconducting state.

cond-mat.supr-con↗

arXiv2016

Interband optical conductivity of the [001]-oriented Dirac semimetal Cd3As2

We measured the optical reflectivity of [001]-oriented $n$-doped Cd$_{3}$As$_{2}$ in a broad frequency range (50 - 22000 cm$^{-1}$) for temperatures from 10 to 300 K. The optical conductivity, $σ(ω) = σ_{1}(ω) + {\rm i}σ_{2}(ω)$, is isotropic within the (001) plane; its real part follows a power law, $σ_{1}(ω) \propto ω^{1.65}$, in a large interval from 2000 to 8000 cm$^{-1}$. This behavior is caused by interband transitions between two Dirac bands, which are effectively described by a sublinear dispersion relation, $E(k) \propto \lvert k \rvert ^{0.6}$. The momentum-averaged Fermi velocity of the carriers in these bands is energy dependent and ranges from $1.2 \times 10^{5}$ to $3 \times 10^{5}$ m/s, depending on the distance from the Dirac points. We detect a gaplike feature in $σ_{1}(ω)$ and associate it with the Fermi level positioned around $100$ meV above the Dirac points.

cond-mat.mes-hall↗

arXiv2016

Pressure-dependent optical investigations of $α$-(BEDT-TTF)$_2$I$_3$: tuning charge order and narrow gap towards a Dirac semimetal

Infrared optical investigations of $α$-(BEDT-TTF)$_2$I$_3$ have been performed in the spectral range from 80 to 8000~cm$^{-1}$ down to temperatures as low as 10~K by applying hydrostatic pressure. In the metallic state, $T > 135$~K, we observe a 50\% increase in the Drude contribution as well as the mid-infrared band due to the growing intermolecular orbital overlap with pressure up to 11~kbar. In the ordered state, $T<T_{\rm CO}$, we extract how the electronic charge per molecule varies with temperature and pressure: Transport and optical studies demonstrate that charge order and metal-insulator transition coincide and consistently yield a linear decrease of the transition temperature $T_{\rm CO}$ by $8-9$~K/kbar. The charge disproportionation $Δρ$ diminishes by $0.017~e$/kbar and the optical gap $Δ$ between the bands decreases with pressure by -47~cm$^{-1}$/kbar. In our high-pressure and low-temperature experiments, we do observe contributions from the massive charge carriers as well as from massless Dirac electrons to the low-frequency optical conductivity, however, without being able to disentangle them unambiguously.

cond-mat.str-el↗