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Adrian Sheppard

Publications and source records attributed to Adrian Sheppard.

2 recordsLinked to original sources

Measuring and Modelling Lag in Amorphous Silicon Flat-Panel X-ray Detectors

Detector lag, also referred to as afterglow, is a source of image degradation in flat-panel x-ray detectors, producing temporal artefacts that reduce image quality and quantitative accuracy. In this work, we present a robust and repeatable experimental framework for characterising long-term detector lag (from minutes to hours) under controlled step-up and step-down exposure transitions of particular relevance to tomography. The measured transition curves from an amorphous silicon detector with a CsI:Ti scintillator exhibit unexpected behaviour, with the detector response temporarily overshooting its final equilibrium intensity following step-up transitions, rather than exhibiting the gradual monotonic rise and decay typically expected. These curves were well fitted by multi-exponential functions, providing initial estimates for the depth of the charge traps in the scintillator. These parameters were incorporated into a proposed multi-trap rate equation model that reproduces the overall observed behaviour of both step-up and step-down transitions, including the overshoot that is not captured by previous models. Although discrepancies remain between the model and observation, this work establishes a reproducible methodology for detector lag characterisation and presents an improved physical model that offers greater insight into the mechanisms governing detector lag.

physics.ins-det

The Directionality of Gravitational and Thermal Diffusive Transport in Geologic Fluid Storage

Diffusive transport has implications for the long-term status of underground storage of hydrogen (H$_2$) fuel and carbon dioxide (CO$_2$), technologies which are being pursued to mitigate climate change and advance the energy transition. Once injected underground, CO$_2$ and H$_2$ will exist in multiphase fluid-water-rock systems: being partially-soluble, injected fluids can flow through the porous rack in a connected plume, become disconnected and trapped as ganglia surrounded by groundwater within the storage rock pore space, and also dissolve and migrate through the aqueous phase. Recent analyses have focused on the concentration gradients induced by differing capillary pressure between fluid ganglia which can drive diffusive transport ("Ostwald ripening"). However, studies have neglected or excessively simplified important factors; namely: the non-ideality of gases under geologic conditions, the opposing equilibrium state of dissolved CO$_2$ and H$_2$ driven by the partial molar density of dissolved solutes, and entropic and thermodiffusive effects resulting from geothermal gradients. We conduct an analysis from thermodynamic first principles and use this to provide numerical estimates at conditions relevant to underground storage reservoirs. We show that entropic contributions to the free energy are so significant as to cause a reversal in the direction of diffusive transport in systems with geothermal gradients. For CO$_2$, even geothermal gradients less than 10 C/km induce downwards diffusion at depths relevant to storage. Diffusive transport of H$_2$ is less affected, but still reverses direction under typical gradients. Contrary to previous studies, we find that in diffusion and convection will likely work in concert - both driving CO$_2$ downwards, and both driving H$_2$ upwards - for conditions representative of their respective storage reservoirs.

physics.geo-ph