arXiv subjects

Aitor Erkoreka

Publications and source records attributed to Aitor Erkoreka.

11 recordsLinked to original sources

arXiv2026

The effect of side chain length on the mesomorphic properties of ferroelectric nematogens

The discovery of ferroelectric nematic phase opened new directions in the field of soft matter chemistry and physics. In this paper, we have modified a previously reported ferroelectric nematogen based on molecular structure with dimethylamino-terminated part. We have prepared two new homologues by prolonging a side chain and investigated the effect of its length on the mesomorphic properties. While previously reported homologues exhibited a direct phase transition from the isotropic (Iso) to the ferroelectric nematic phase (NF), for prolonged alkyl chain there is a narrow nematic phase (N) in between. For new compounds, we have established their mesomorphic and material properties. We have confirmed ferroelectricity of the NF phase by the polarization, SHG signal and permittivity. Finally, we have compared these parameters with respect to the side-chain length and discussed new effects, discovered for prolonged homologues due to the presence of an additional N phase.

cond-mat.soft↗

arXiv2026

On the emergence of molecular tilt in a ferroelectric smectic liquid crystal with broken director-inversion symmetry

The origin of some mesophases of the ferroelectric nematic realm is not yet well understood. In this work we study the highly polar liquid crystal MIO, a close structural analogue of the prototypical ferroelectric nematogen DIO, which exhibits a ferroelectric smectic A to ferroelectric smectic C (SmAF-SmCF) phase transition. Calorimetric, dielectric and light-scattering experiments reveal that it is a second-order phase transition with mean-field behavior, and is driven by the softening of the tilt elastic constant accompanied by the divergence of the amplitude of the associated dielectric mode.

cond-mat.soft↗

arXiv2026

Elasticity-Driven Periodic Polarization Patterns in Confined Chiral Ferroelectric Nematic Fluid

Ferroelectric nematic phases are a new class of polar fluids in which spontaneous polarization is directly coupled to the orientational order, providing unique opportunities for creating self-organized materils with spatially modulated electric polarization and nonlinear optical response. Here we report the spontaneous emergence of polarization modulated textures in a chiral ferroelectric nematic material close to the transition to the chiral twist-bend ferroelectric nematic phase. By systematically varying cell thickness and surface anchoring conditions, we map the formation of these modulated states, revealing stripe, square and hexagonal morphologies determined via confinement conditions. These structures are directly translated into periodic modulation of the nonlinear optical response, as evidenced by second-harmonic generation imaging. Comparison with an elasticity based theoretical framework and numerical free energy minimization shows that the instability originates from the softening of the bend elastic constant in the chiral nematic phase as the system approaches the lower-temperature heliconical polar phase. The resulting elastic frustration, combined with confinement, drives the formation of spatially periodic director distortions, highlighting ferroelectric nematic fluids as a promising platform for self-assembled nonlinear optical materials.

cond-mat.soft↗

arXiv2026

Flexoelectricity-driven softening of bend elasticity leads to spontaneous chiral symmetry breaking in a polar fluid

The origin of recently observed spontaneous chiral symmetry breaking in polar fluids is an unsolved problem, and poses fundamental questions as to how heliconical structures emerge in systems composed of achiral molecules. We report on the softening of bend elasticity close to such phase transition, showing that flexoelectric coupling between the electric polarization and the bend deformation is the responsible mechanism, presumably arising from the bent shape of the constituent highly polar molecules.

cond-mat.soft↗

arXiv2024

Mean-field theory of the uniaxial ferroelectric smectic A liquid crystal phase

Following the groundbreaking discovery of the ferroelectric nematic liquid crystal phase (NF), a series of closely-related new polar phases have also been found. An especially interesting one is the ferroelectric smectic A phase (SmAF) with spontaneous polarization along the layer normal observed in a few materials of the NF realm. Here, we present a mean-field molecular model that successfully captures the rich phase diagrams experimentally observed in the literature in terms of two parameters. Additionally, we carry out second harmonic generation, X-ray diffraction and birefringence measurements in a compound exhibiting the SmAF phase to determine the appropriate order parameters and compare with the model predictions.

cond-mat.soft↗

arXiv2024

Constraining the value of the dielectric constant of the ferroelectric nematic phase

Ferroelectric nematic liquid crystals are currently being subject to a plethora of investigations since they are of great fundamental interest and could potentially foster promising applications. However, many basic aspects are still poorly understood, among which the problem of the dielectric constant stands out. Ferroelectric nematics exhibit giant dielectric constants whose value depends on the thickness of the measurement cell. Even though this must be the result of a spurious artifact, the intrinsic permittivity has not been determined yet. In this work, we tackle this problem by modeling the dielectric response of the liquid crystal filled cell through an equivalent circuit accounting for polarization reorientation and the effect of insulating interfacial layers. We arrive at the conclusion that the perpendicular component of the permittivity $\varepsilon_{\perp}$ is of the order of $10$ in the prototypical ferroelectric nematogen DIO, while the parallel component $\varepsilon_{\parallel}$ is of the order of $150$. In this way, the dielectric tensor of DIO has been fully determined.

cond-mat.soft↗

arXiv2024

A molecular perspective on the emergence of long-range polar order from an isotropic fluid

The ferroelectric nematic phase (N$_{\text{F}}$) has quickly become the most studied system in liquid crystal research. In this work, we investigate the origin of such polar structure by studying a compound for which the N$_{\text{F}}$ phase directly follows the isotropic liquid phase on cooling, making it a particularly interesting system. Our experimental results evidence the presence of polar correlations already in the high-temperature phase, in which ferroelectric order can be induced under a sufficiently strong electric field. In the N$_{\text{F}}$ phase, molecular dynamics and polar correlations are investigated through detailed dynamic dielectric measurements, while second harmonic generation experiments evidence a large value of the main coefficient of the second order dielectric susceptibility tensor. Lastly, experimentally determined parameters are employed for calculations based on a recently proposed theoretical model for the stability of the N$_{\text{F}}$ phase. The obtained results suggest that the parallel alignment of dipoles is driven by a subtle interplay between electrostatic and excluded volume interactions.

cond-mat.soft↗

arXiv2024

Development of a high-frequency dielectric spectrometer using a portable vector network analyzer

A simple and novel setup for high-frequency dielectric spectroscopy of materials has been developed using a portable vector network analyzer. The measurement principle is based on radio-frequency reflectometry, and both its capabilities and limitations are discussed. The results obtained on a typical liquid crystal prove that the device can provide reliable spectra between $10^7$ Hz and $10^9$ Hz, thus extending the capabilities of conventional impedance analyzers.

physics.ins-det↗

arXiv2024

Dielectric spectroscopy of a ferroelectric nematic liquid crystal and the effect of the sample thickness

The recently discovered ferroelectric nematic liquid crystals have been reported to exhibit very large dielectric permittivity values. Here, we report a systematic investigation of the dielectric behavior of a prototypical ferroelectric nematogen by varying the thickness of the parallel capacitor measuring cell. While in the non-polar high temperature nematic phase results show only slight differences due to slight variations of the alignment, the measured permittivity values in the ferroelectric nematic phase show a linear dependence on the cell thickness. It is also shown that the characteristic relaxation frequency decreases inversely proportionally to the thickness. The results are discussed in terms of three different available models based on different underlying mechanisms, accounting for cancellation of the probe electric fields by polarization reorientation or by ionic charges, or based on a recently proposed continuous phenomenological model.

cond-mat.soft↗

arXiv2024

Collective and non-collective molecular dynamics in a ferroelectric nematic liquid crystal studied by broadband dielectric spectroscopy

A great deal of effort has been recently devoted to the study of dielectric relaxation processes in ferroelectric nematic liquid crystals, yet their interpretation remains unclear. In this work, we present the results of broadband dielectric spectroscopy experiments of a prototypical ferroelectric nematogen in the frequency range 10 Hz-110 MHz at different electrode separations and under the application of DC bias fields. The results evidence a complex behavior in all phases due to the magnitude of polar correlations in these systems. The observed modes have been assigned to different relaxation mechanisms based on existing theoretical frameworks.

cond-mat.soft↗

arXiv2023

Orientation-Constrained System for Lamp Detection in Buildings Based on Computer Vision

Computer vision is used in this work to detect lighting elements in buildings with the goal of improving the accuracy of previous methods to provide a precise inventory of the location and state of lamps. Using the framework developed in our previous works, we introduce two new modifications to enhance the system: first, a constraint on the orientation of the detected poses in the optimization methods for both the initial and the refined estimates based on the geometric information of the building information modelling (BIM) model; second, an additional reprojection error filtering step to discard the erroneous poses introduced with the orientation restrictions, keeping the identification and localization errors low while greatly increasing the number of detections. These~enhancements are tested in five different case studies with more than 30,000 images, with results showing improvements in the number of detections, the percentage of correct model and state identifications, and the distance between detections and reference positions

cs.CV↗