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Alexander G. G. M. Tielens

Publications and source records attributed to Alexander G. G. M. Tielens.

At least 19 recordsLinked to original sources

PDRs4All XXII. Near-Infrared continuum in the Orion Bar

Conspicuous excess emission is present in the near-infrared (NIR) region in various objects, including reflection nebulae, planetary nebulae, and nearby galaxies. However, the spatial distribution and spectral shape of the excess emission remain poorly understood. We studied the NIR continuum emission spectroscopically and obtained its spatial distribution relative to the aromatic infrared band (AIB) at 3.3um in the Orion Bar prototypical photodissociation region (PDR). We aim to characterize its spectral shape and discuss its origin. We employed 3D spectroscopic data of the Orion Bar taken with the integrated field unit of NIRSpec on JWST from the Early Release Science program "PDRs4All." Contribution from the foreground ionized gas was estimated using the Cloudy code and subtracted. The observed regions were divided into nine physically distinct regions and an average spectrum was derived for each region. The nine regions, including the ionized gas, atomic PDR, and molecular PDR, clearly show remaining continuum in the region 1--4.5um. The continuum at wavelengths longer than 2.7um shows good correlations with the 3.3um AIB, while the correlation of the continuum at 1.2um is not significant. We further find that the NIR continuum in the Orion Bar can be approximated by a summation of two blackbodies. The low-temperature component correlates with the AIB well, while the high-temperature component does not. The average spectra also show absorption features at 3.0 and 4.27um, which are attributed to the presence in the spectra of water ice and CO2 ice. We discuss possible origins of the NIR continuum, among which recurrent fluorescence from carbon clusters better explains the observed low-temperature component. The presence of ice species suggests a contribution from a deeper layer of the PDR along the line of sight producing characteristic ice absorption features.

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Low-Frequency Recombination Lines from Galaxies and AGN over Cosmic Time

Radio recombination lines (RRLs) at low frequencies (<10 GHz) can provide a multi-phase view of interstellar gas in nearby galaxies, absorption-line-systems, and AGN. Hydrogen RRLs arise in fully ionized gas and carbon RRLs trace elusive cold-HI and CO-dark molecular gas. Low frequency RRLs are typically stimulated by the radio continuum and thus may be observable within or against radio bright sources out to cosmological distances (z ~ 6). Although long sought after, RRLs were only recently detected outside of the local universe (z ~ 1; Emig et al., 2020, 2023). Such detections have been made possible by the advancement of wide-bandwidth spectral-line surveys on next-generation low-frequency telescopes. Precursors and pathfinders to the SKA have opened up this field of research and will make significant advancements over the next years by enabling surveys over large source samples. The SKA will provide access to the crucial frequency ranges where RRL line intensity is brightest. Furthermore, multi-band SKA measurements will fully characterize gas physical conditions. Key extragalactic science of low frequency RRLs will focus on (i) the conversion of baryonic material into stars across cosmic time, (ii) the evolution of the ISM and its physical conditions in galaxies, and (iii) how gas drives and inhibits AGN activity.

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JWST Observations of Starbursts: Dust Processing in the M82 Superwind

We present JWST MIRI and NIRCam imaging of the inner ~5 kpc of the M82 superwind at 0.05-0.375'' (~0.9-6.5 pc) resolution. Targeted filters probe emission from polycyclic aromatic hydrocarbons (PAHs; F335M, F360M, F770W, F1130W) and continuum (F250M, F360M). The images reveal a network of cool wind filaments traced by PAHs. PAH surface brightness declines with the inverse square of distance to the midplane, suggesting that the incident radiation field from the starburst drives the observed PAH intensity out to 2.5 kpc. The 3.3/11.3 and 3.3/7.7 band ratios show uniformity with distance from the starburst, though comparisons with mid-IR dust emission models indicate a modest shift toward larger PAHs. Outside the disk, 11.3/7.7 increases moderately, reflecting that PAHs become more neutral with distance from the starburst as they are exposed to a declining radiation field and ionization parameter. Overall, PAHs in the wind are consistent with standard-to-large sizes and standard-to-high ionization states. Including Spitzer and Herschel data, PAH abundance (qPAH) is set at ~1% in the starburst and remains unchanging out to 5 kpc off the disk. This flat qPAH profile suggests that PAHs are shielded from the hot wind, perhaps residing in the surface layers of cool clouds, with possible replenishment from cloud interiors and enrichment of the halo from previous bursts. In this picture, clouds are not dense enough to promote PAH growth, and they likely undergo radiative cooling and mixing with the hot phase to survive the gauntlet for at least ~20 Myr.

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The Computed Microwave Spectrum of the Protonated Fullerene C60H+

The largest known molecule in space, C60 , has been detected in its neutral and cationic form through its vibrational, UV-driven fluorescence emission spectrum and its electronic absorption spectrum, respectively. The detection of several polycyclic aromatic hydrocarbon molecules through their pure rotation spectrum in cold, dense, molecular cloud cores suggests that C60 might be present in these environments as well. The low flux of UV pumping photons in molecular cloud cores and the absence of suitably bright background stars, make detection of C60 and its cation through the commonly used methods impractical. As C60 has no permanent dipole moment, its pure rotational transitions are forbidden and its presence must be inferred from the rotational transitions of C60 derivatives with permanent dipole moments. Here, we present a study of the predicted rotational spectrum of protonated C60 that has a sizeable permanent dipole moment. Protonation of C60 reduces the icosahedral symmetry to Cs and results in a dipole moment of about 3.8 Debye. The resulting C60H+ is a closed shell system

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Variations in the 6.2 $μ$m polycyclic aromatic hydrocarbon band in Active Galactic Nuclei- and Starburst-dominated galaxies

Polycyclic aromatic hydrocarbons (PAHs) are fundamental to understanding the interstellar medium (ISM) of several astrophysical objects. Normally present in Starburst (SB) galaxies, they have also been more frequently detected in active galaxy nuclei (AGNs), suggesting an inner dusty torus that can shield the radiation from the central black role. In this work, we analyze the 6.2 $μ$m PAH band of SB-, AGN- and mixed-dominated spectra from 175 IDEOS database galaxies. After fitting of the band, the sources were distributed into the Peeters' A, B and C classes according to their profile peak positions. Class A objects are predominant in 80% of the entire sample, which could indicate the presence of PAHs with nitrogen incorporation. The water ice absorption at 6.0 $μ$m was also studied in eleven objects, and it affected the PAH band poorly. A prominent second spectral feature after 6.3 $μ$m is present in ten galaxies. Fitting both PAH profiles at 6.2 $μ$m changes all the fit results: the first profile is consistently blue-shifted and classified as class A due to the presence of the second component. Further studies are needed to better comprehend these PAH trends in galactic environments.

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PDRs4All: XVIII. The evolution of the PAH ionisation and PAH size distribution across the Orion Bar

We investigate the evolution of the PAH population's charge state and size across key physical zones in the Orion Bar, which include the HII region, the atomic PDR (APDR), and three HI/H2 dissociation fronts (DF1, DF2, and DF3). Utilising the NASA Ames PAH Infrared Spectroscopic Database (PAHdb) and the pyPAHdb spectral modelling tool, we analysed the MIRI-MRS observations of the Orion Bar from the "PDRs4All" ERS Program. pyPAHdb modelling reveals the fractional contribution of the different PAH charge states and sizes to the total PAH emission across the Orion Bar. Cationic PAH emission peaks in the APDR region, where neutral PAHs have minimal contribution. Emission from neutral PAHs peaks in the HII region that consists of emission from a face-on PDR associated to the background OMC-1 molecular cloud, and in the molecular cloud regions past DF2. PAH anions are observed deep within the DF2 and DF3 zones. The average PAH size ranges between ~$60-74$ Nc. The modelling reveals regions of top-down PAH formation at the ionisation front, and bottom-up PAH formation within the molecular cloud region. The PAH ionisation parameter $γ$ ranges between ~$2-9 x 10^4$. Intensity ratios tracing PAH ionisation scale well with $γ$ in regions encompassing edge-on or face-on PDR emission, but their correlation weakens within the molecular cloud zone. Modelling of the $5-15$ $μ$m PAH spectrum with pyPAHdb achieves comprehensive characterization of the net contribution of neutral and cationic PAHs across different environments, whereas empirical PAH proxy intensity ratio tracers can be highly variable and unreliable outside regions dominated by PDR emission. The derived average PAH size in the different physical zones is consistent with a view of PAHs being more extensively subjected to ultraviolet processing closer to the ionisation front, and less affected within the molecular cloud.

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PAH Spectral Diversity in NGC 7027 and the Evolution of Aromatic Carriers

Polycyclic Aromatic Hydrocarbons (PAHs) constitute a significant fraction of the Universe's carbon budget, playing a key role in the cosmic carbon cycle and dominating the mid-infrared spectra of astrophysical environments in which they reside. Although PAHs are known to form in the circumstellar envelopes of post-AGB stars, their formation and evolution are still not well-understood. We aim to understand how pristine complex hydrocarbons and PAHs in circumstellar environments transition to the PAHs observed in the ISM. The mid-infrared PAH spectra (5-18 micron) of the planetary nebula, NGC 7027, are investigated using spectral cubes from JWST MIRI-MRS. We report the first detection of spatially-resolved variations of the PAH spectral profiles across class A, AB, and B in all major PAH bands (6.2, 7.7, 8.6, and 11.2 micron) within a single source, NGC 7027. These variations are linked to morphological structures within NGC 7027. Clear correlations are revealed between the 6.2, 7.7, and 8.6 micron features, where the red components (6.26, 7.8, 8.65 micron) exhibit a strong correlation and the same is found for the blue components of the 6.2 and 7.7 (6.205 and 7.6 micron). The blue component of the 8.6 (8.56 micron) appears to be independent of the other components. We link this behaviour to differences in molecular structure of their PAH subpopulations. Decomposition of the 11.2 micron band confirms two previously identified components, with the broader 11.25 micron component attributed to emission from very small grains of PAH clusters rather than PAH emission. We show that PAH profile classes generally vary with proximity to the central star's UV radiation field, suggesting class B PAHs represent more processed species while class A PAHs remain relatively pristine, challenging current notions on the spectral evolution of PAHs.

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SOFIA FEEDBACK Survey: The Eagle Nebula in [C II] and Molecular Lines

We characterize the physical conditions and energy budget of the M16 H II region using SOFIA FEEDBACK observations of the [C II] 158 $μ$m line. The O stars in the $\sim 10^{4}~{\rm M}_{\odot}$ NGC 6611 cluster powering this H II region have blown at least 2 cavities into the giant molecular cloud: the large M16 cavity and the small N19 bubble. We detect the spectroscopic signature of an expanding photodissociation region shell towards N19, and traces of a thin, fragmented expanding shell towards M16. Our [C II] observations are resolved to 0.5 km s$^{-1}$ and 15.5$^{\prime\prime}$ and analyzed alongside similarly resolved CO J=3$-$2 observations as well as archival data ranging from the radio to X-ray tracing a variety of gas phases spanning dense $\sim$10 K molecular gas, $10^{4}$ K photoionized gas, and million-K collisionally ionized plasma. With this dataset, we evaluate the coupling of energetic feedback from NGC 6611 and the O9 V star within N19 to the surrounding gas. Winds from NGC 6611 have blown a 20 pc radius cavity constrained in size along the major axis of the natal giant molecular filament, and much of the mechanical wind energy ($>$90%) has escaped through breaches in the $\lesssim 10^{4}~{\rm M}_{\odot}$ shell. Reservoirs of dense gas remain within a few parsecs of the cluster. N19, younger than M16 by $\gtrsim 10^6$ yr, is driven by a combination of mechanical wind energy and thermal pressure from photoionized gas and has swept up $\sim 10^{3}~{\rm M}_{\odot}$ into neutral atomic and molecular shells.

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Cool dark gas in Cygnus X: The first large-scale mapping of low-frequency carbon recombination lines

Understanding the transition from atomic gas to molecular gas is critical to explain the formation and evolution of molecular clouds. However, the gas phases involved, cold HI and CO-dark molecular gas, are challenging to directly observe and physically characterize. We observed the Cygnus X star-forming complex in carbon radio recombination lines (CRRLs) at 274--399 MHz with the Green Bank Telescope at 48' (21 pc) resolution. Of the 30 deg$^2$ surveyed, we detect line-synthesized C273$α$ emission from 24 deg$^2$ and produce the first large-area maps of low-frequency CRRLs, which likely originate in CO-dark molecular gas. The morphology of the C273$α$ emission reveals arcs, ridges, and extended possibly sheet-like gas which are often on the outskirts of CO emission. We find a correlation between velocity-integrated C273$α$ and the 8 $μ$m intensity with a power-law slope of $1.3 \pm 0.2$. We interpret the relation as the dependence of cool dark gas emission on the FUV radiation field, $G_0 \approx 40 - 160$. We determine the typical angular separation between C273$α$ and $^{13}$CO emission to be 12 pc. Velocity differences between C273$α$ and $^{13}$CO are apparent throughout the region and have a typical value of 2.9 km s$^{-1}$. We estimate gas densities of $n \approx 20 - 900$ cm$^{-3}$ with a nominal $n \approx 400$ cm$^{-3}$ in the C$^{+}$/H$_2$ layer. The evolution of the C273$α$ gas seems to be dominated by turbulent pressure, with a characteristic timescale to form H$_2$ of about 2.6 Myr. These observations underline the richness of low-frequency CRRLs to provide revelatory insights into the characteristics of (CO-)dark gas and the evolution of molecular gas.

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PDRs4All XIX. The 6 to 9 $μ$m region as a probe of PAH charge and size in the Orion Bar

Infrared emission from polycyclic aromatic hydrocarbons (PAHs) play a major role in determining the charge balance of their host environments that include photo-dissociation regions (PDRs) in galaxies, planetary nebulae, and rims of molecular clouds. We aim to investigate the distribution and sizes of charged PAHs across the key zones of the Orion Bar PDR. We employ JWST MIRI-MRS observations of the Orion Bar from the Early Release Science program ''PDRs4All'' and synthetic images in the JWST MIRI filters. We investigate the spatial morphology of the AIBs at 6.2, 7.7, 8.6, and 11.0 $μ$m that commonly trace PAH cations, and the neutral PAH-tracing 11.2 $μ$m AIB, their (relative) correlations, and the relationship with existing empirical prescriptions for AIBs. The 6.2. 7.7, 8.6, 11.0, and 11.2 $μ$m AIBs are similar in spatial morphology, on larger scales. Analyzing three-feature intensity correlations, two distinct groups emerge: the 8.6 and 11.0 $μ$m vs. the 6.2 and 7.7 $μ$m AIBs. We attribute these correlations to PAH size. The 6.2 and 7.7 $μ$m AIBs trace cationic, medium-sized PAHs. Quantum chemical calculations reveal that the 8.6 $μ$m AIB is carried by large, compact, cationic PAHs, and the 11.0 $μ$m AIB's correlation to it implies, so is this band. The 6.2/8.6 and 7.7/8.6 PAH band ratios thus probe PAH size. We conclude that the 6.2/11.2 AIB ratio is the most reliable proxy for charged PAHs, within the cohort. We outline JWST MIRI imaging prescriptions that serve as effective tracers of the PAH ionization fraction as traced. This study showcases the efficacy of the 6-9 $μ$m AIBs to probe the charge state and size distribution of the emitting PAHs, offering insights into the physical conditions of their host environments. JWST MIRI photometry offers a viable alternative to IFU spectroscopy for characterizing this emission in extended objects.

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PDRs4All XVI. Tracing aromatic infrared band characteristics in photodissociation region spectra with PAHFIT in the JWST era

Photodissociation regions (PDRs) exhibit emission between 3-20 um known as the Aromatic Infrared Bands (AIBs), originating from small carbonaceous species such as polycyclic aromatic hydrocarbons (PAHs). The AIB spectra observed in Galactic PDRs, such as the Orion Bar observations by the PDRs4All JWST program, are considered a local analog for those seen in extragalactic star-forming regions. We present the Python version of PAHFIT, a spectral decomposition tool that separates the contributions by AIB subcomponents, thermal dust emission, gas lines, stellar light, and dust extinction. By fitting segments of the Orion Bar spectra, we provide a configuration to decompose JWST spectra of PDRs in detail. The resulting central wavelengths and FWHM of the AIB subcomponents are compiled into a "PDR pack" for PAHFIT. We applied PAHFIT with this PDR pack and the default continuum model to spectra of the central star forming ring of the galaxy NGC7469. We introduce an alternate dust continuum model to fit the Orion Bar spectra, as the default PAHFIT continuum model mismatches the intensity at 15-26 um. Using the PDR pack and the alternate continuum model, PAHFIT reproduces the Orion Bar spectra with residuals of a few percent, and similar performance is achieved for the NGC7469 spectra. We provide PAHFIT-based diagnostics that trace the profile variations of the 3.3, 3.4, 5.7, 6.2, and 7.7 um AIBs, and thus the photochemical evolution of the AIB carriers. The 5.7 um AIB emission originates from at least two subpopulations, one more prominent in highly irradiated environments and one preferring more shielded environments. Smaller PAHs as well as very small grains or PAH clusters both thrive in the more shielded environments of the molecular zone in the Orion Bar. Based on these new diagnostics, we quantify the similarities between the AIB profiles observed in the Orion Bar and NGC7469.

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The Discovery of 25 um Interstellar Methanol

We present the first astrophysical detection of methanol (CH3OH) in the torsional band near 25 um. Using high resolution mid-infrared (MIR) spectroscopy, we identified over seventy gas-phase CH3OH absorption lines between 20 and 28 um towards the massive protostar NGC 7538 IRS 1 with SOFIA/EXES. We derive a temperature of 180 K and a total column density of 2 x 10^17 cm-2, comparable to sub-mm measurements. Complementary analysis of acetylene (C2H2) absorption lines is also included. Both CH3OH and C2H2 reveal an unresolved second velocity component. These MIR absorption lines likely probe the molecular material in two edge-on disks, supporting the scenario that NGC 7538 IRS 1 consists of multiple protostars. We provide an updated line list for the torsional band of CH3OH, which was generated from lab work and model calculations. This discovery and the updated line list will enable the search for CH3OH in JWST/MIRI spectra.

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Investigating silicate, carbon, and water in the diffuse interstellar medium: the first shots from WISCI

The dusty interstellar medium (ISM) of the Milky Way is distributed in a complex, cloudy structure. It is fundamental to the radiation balance within the Milky Way, provides a reaction surface to form complex molecules, and is the feedstock for future generations of stars and planets. The life cycle of interstellar dust is not completely understood, and neither are its structure nor composition. The abundance, composition, and structure of dust in the diffuse ISM can be determined by combining infrared, optical and ultraviolet spectroscopy. JWST enables measurement of the faint absorption of ISM dust grains against bright stars at kiloparsec distances across the infrared spectrum. Here we present an overview of the project `Webb Investigation of Silicates, Carbons, and Ices' (WISCI) along with interpretation of two targets, GSC 08152-02121 and CPD-59 5831. Observations of 12 WISCI target stars were taken by JWST, the Hubble Space Telescope, Himalayan Chandra Telescope, and the Very Large Telescope. We use these to characterize the targets' spectral types and calculate their line-of-sight extinction parameters, $A_{\rm V}$ and $R_{\rm V}$. We find absorption in the JWST spectra of GSC 08152-02121, and CPD-59 5831 associated with carbonaceous dust around 3.4 and 6.2 micron and amorphous silicates at 9.7 micron. In GSC 08152-02121 we also find indications of absorption by trapped water around 3 micron. This first look from WISCI demonstrates the line-of-sight variability within the sample, and the program's potential to identify and correlate features across ultraviolet to mid-infrared wavelengths.

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Solar C/O ratio in planet-forming gas at 1 au in a highly irradiated disk

The chemical composition of exoplanets is thought to be influenced by the composition of the disks in which they form. JWST observations have unveiled a variety of species in numerous nearby disks, showing significant variations in the C/O abundance ratio. However, little is known about the composition and C/O ratio of disks around young stars in clusters exposed to strong ultraviolet (UV) radiation from nearby massive stars, which are representative of the environments where most planetary systems form, including ours. We present JWST spectroscopy of d203-504, a young 0.7 $\rm M_{\odot}$ star in the Orion Nebula with a 30 au disk irradiated by nearby massive stars. These observations reveal spectroscopic signatures of CO, H$_2$O, CH$_3^+$, and PAHs. Water and CO are detected in absorption in the inner disk ($r\lesssim 1$ au), where the estimated gas-phase C/O ratio is 0.48, consistent with the Solar value and that of the Orion Nebula. In contrast, \ch{CH3+} and PAHs are found in the extended surface layers of the disk. These results suggest that gas in the inner disk is chemically shielded from UV radiation while the surface layers of the disk experience UV-induced chemistry, potentially depleting their carbon content.

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[C II]-deficit caused by self-absorption in an ionized carbon-filled bubble in RCW79

Recent spectroscopic observations of the [C II] 158$\,\mathrm{μm}$ fine-structure line of ionized carbon (C$^+$), using the Stratospheric Observatory for Infrared Astronomy (SOFIA), have revealed expanding [C II] shells in Galactic H II regions. We report the discovery of a bubble-shaped source (S144 in RCW79), associated with a compact H II region, excited by a single O7.5--9.5V/III star, which is consistent with a scenario that the bubble is still mostly ``filled'' with C$^+$. This indicates most likely a very early evolutionary state, in which the stellar wind has not yet blown material away, as it is the case for more evolved H II regions. Using the SimLine non-LTE radiative transfer code, the [C II] emission can be modeled to originate from three regions. First, a central H II region with little C$^+$ in the fully ionized phase, followed by two layers with gas density around $2500\,\mathrm{cm^{-3}}$ of partially photo-dissociated gas. The second layer is a slowly expanding [C II] shell with an expansion velocity of $\sim\,$$2.6\,\mathrm{km\,s^{-1}}$. The outermost layer exhibits a temperature and velocity gradient that produces the observed self-absorption features in the optically thick [C II] line ($τ\sim 4$) leading to an apparent deficit in [C II] emission and a low ratio of [C II] to total far-infrared (FIR) emission. We developed a procedure to approximate the missing [C II] flux and find a linear correlation between [C II] and FIR without a [C II]-deficit. This demonstrates that at least some of the [C II]-deficit found in Galactic H II bubbles can be attributed to self-absorption.

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PDRs4All XI. Detection of infrared CH$^+$ and CH$_3^+$ rovibrational emission in the Orion Bar and disk d203-506: evidence of chemical pumping

The methylidyne cation (CH$^+$) and the methyl cation (CH$_3^+$) are building blocks of organic molecules, yet their coupled formation and excitation mechanisms remain mainly unprobed. The James Webb Space Telescope (JWST), with its high spatial resolution and good spectral resolution, provides unique access to the detection of these molecules. Our goal is to use the first detection of CH$^+$ and CH$_3^+$ rovibrational emission in the Orion Bar and in the protoplanetary disk d203-506, irradiated by the Trapezium cluster, to probe their formation and excitation mechanisms and constrain the physico-chemical conditions. We use spectro-imaging acquired using both the NIRSpec and MIRI-MRS instruments to study the CH$^+$ and CH$_3^+$ spatial distribution at very small scales, and compare it to excited H$_2$ emission. CH$^+$ and CH$_3^+$ emissions originate from the same region as highly excited H$_2$. Our comparison between the Bar and d203-506 reveals that both CH$^+$ and CH$_3^+$ excitation and/or formation are highly dependent on gas density. The excitation temperature of the observed CH$^+$ and CH$_3^+$ rovibrational lines is around $T$ ~ 1500 K in the Bar and $T$ ~ 800 K in d203-506. Moreover, the column densities derived from the rovibrational emission are less than 0.1 % of the total known (CH$^+$) and expected (CH$_3^+$) column densities. These results show that CH$^+$ and CH$_3^+$ level populations strongly deviate from ETL. CH$^+$ rovibrational emission can be explained by chemical formation pumping with excited H$_2$ via C$^+$ + H$_2^*$ = CH$^+$ + H. These results support a gas phase formation pathway of CH$^+$ and CH$_3^+$ via successive hydrogen abstraction reactions. However, we do not find any evidence of CH$_2^+$ emission in the JWST spectrum. Finally, observed CH$^+$ intensities coupled with chemical formation pumping model provide a diagnostic tool to trace the local density.

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On the Interpretation of Mid-Infrared Absorption Lines of Gas-Phase H$_2$O as Observed by JWST/MIRI

Ro-vibrational absorption lines of H$_2$O in the 5-8 $μ$m wavelength range selectively probe gas against the mid-infrared continuum emitting background of the inner regions of YSOs and AGN and deliver important information about these warm, dust-obscured environments. JWST/MIRI detects these lines in many lines of sight at a moderate spectral resolving power of $R\sim3500$ (FWHM of 85 km/s). Based on our analysis of high-resolution SOFIA/EXES observations, we find that the interpretation of JWST/MIRI absorption spectra can be severely hampered by the blending of individual transitions and the lost information on the intrinsic line width or the partial coverage of the background continuum source. In this paper, we point out problems such as degeneracy that arise in deriving physical properties from an insufficiently resolved spectrum. This can lead to differences in the column density by two orders of magnitude. We emphasize the importance of weighting optically thin and weak lines in spectral analyses and provide recipes for breaking down the coupled parameters. We also provide an online tool to generate the H$_2$O absorption line spectra that can be compared to observations.

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PDRs4All VIII: Mid-IR emission line inventory of the Orion Bar

Mid-infrared emission features probe the properties of ionized gas, and hot or warm molecular gas. The Orion Bar is a frequently studied photodissociation region (PDR) containing large amounts of gas under these conditions, and was observed with the MIRI IFU aboard JWST as part of the "PDRs4All" program. The resulting IR spectroscopic images of high angular resolution (0.2") reveal a rich observational inventory of mid-IR emission lines, and spatially resolve the substructure of the PDR, with a mosaic cutting perpendicularly across the ionization front and three dissociation fronts. We extracted five spectra that represent the ionized, atomic, and molecular gas layers, and measured the most prominent gas emission lines. An initial analysis summarizes the physical conditions of the gas and the potential of these data. We identified around 100 lines, report an additional 18 lines that remain unidentified, and measured the line intensities and central wavelengths. The H I recombination lines originating from the ionized gas layer bordering the PDR, have intensity ratios that are well matched by emissivity coefficients from H recombination theory, but deviate up to 10% due contamination by He I lines. We report the observed emission lines of various ionization stages of Ne, P, S, Cl, Ar, Fe, and Ni, and show how certain line ratios vary between the five regions. We observe the pure-rotational H$_2$ lines in the vibrational ground state from 0-0 S(1) to 0-0 S(8), and in the first vibrationally excited state from 1-1 S(5) to 1-1 S(9). We derive H$_2$ excitation diagrams, and approximate the excitation with one thermal (~700 K) component representative of an average gas temperature, and one non-thermal component (~2700 K) probing the effect of UV pumping. We compare these results to an existing model for the Orion Bar PDR and highlight the differences with the observations.

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