Alexandr Talyzin | Searcharxiv

arXiv2026

Graphene-based technologies for energy applications, challenges and perspectives

Here we report on technology developments implemented into the Graphene Flagship European project for the integration of graphene and graphene-related materials (GRMs) into energy application devices. Many of the technologies investigated so far aim at producing composite materials associating graphene or GRMs with either metal or semiconducting nanocrystals or other carbon nanostructures (e.g., CNT, graphite). These composites can be used favourably as hydrogen storage materials or solar cell absorbers. They can also provide better performing electrodes for fuel cells, batteries, or supercapacitors. For photovoltaic (PV) electrodes, where thin layers and interface engineering are required, surface technologies are preferred. We are using conventional vacuum processes to integrate graphene as well as radically new approaches based on laser irradiation strategies. For each application, the potential of implemented technologies is then presented on the basis of selected experimental and modelling results. It is shown in particular how some of these technologies can maximize the benefit taken from GRM integration. The technical challenges still to be addressed are highlighted and perspectives derived from the running works emphasized.

cond-mat.mtrl-sci↗

arXiv2018

Graphene oxide membranes: on the absence of "graphene capillaries", "ultrafast flow" rate and "ultraprecise sieving"

The data by Q.Yang et al suggest absence of "ultrafast flow" of solvent across graphene oxide (GO) membranes. The "ultrafast flow" is result of using unrealistic geometrical model with close packed hole-free micrometer sized GO flakes providing only 0.1 % of area in each layer available for permeation. The data by Q.Yang et all demonstrate that at least 3-5 % of total layer area are available for permeation in real GO membranes due to holes between irregularly shaped flakes. At least 2-3 percent of area also needs to be added to the permeation cross section due to holes and cracks in GO flakes, especially abundant due to prolonged sonication of dispersions. Permeation of solutions mostly through pinholes penetrating tens of GO layers suggests that "graphene capillaries" are not required to explain water flow across the membrane. Taking into account realistic packing of GO flakes with holes between the flakes and across the flakes, 2-3 orders of magnitude shorter permeation path should be formed. Considering shorter zigzag permeation path between GO sheets and 5-10 % of area in each layer available for permeation due to holes across and between GO flakes, permeation rates across GO membranes can be explained by trivial diffusion. In absence of "graphene capillaries", the "ultra-precise sieving" related to "cutoff" value of 4.5 Å (hydration diameter) provided by "graphene capillaries" has little meaning. As it is well known from earlier studies and now demonstrated by Q.Yang et al using their own samples the swelling of GO membranes is different for different solutions, depends on concentration of solutes and results in delamination in many solutions. Q.Yang et al provide controversial data for stability of their GO membranes in water citing use of surfactant to prevent dissolving. Oxidation state of GO membranes remains to be unknown due to incorrect analysis of XPS spectra.

physics.app-ph↗