arXiv subjects

Anat Shahar

Publications and source records attributed to Anat Shahar.

7 recordsLinked to original sources

arXiv2026

Magnesium silicate condensation in sub-Neptune envelopes: the fundamental link between chemistry, structure, and observables

Chemical interactions between the hydrogen-dominated envelopes and silicate-rich interiors of sub-Neptunes likely play a key role in shaping their atmospheric structure, mass-radius relations, and upper atmosphere composition. While atmospheric abundances and structure deeply influence each other, many existing models have either considered the effects of chemical interactions without the structural implications or have modeled the envelope structure using oversimplified chemical networks. In this work, we introduce Rocky Raccoon, a coupled chemical equilibrium-atmospheric structure model. This model incorporates Mg, Si, O, C, and H species and produces self-consistent atmospheric chemical and thermal profiles for sub-Neptune envelopes, treating multi-species condensation for the first time. We find that the condensation sequence of magnesium silicates above a magma ocean is determined by the basal magma composition. We show that these condensation sequences drive the upper atmospheric composition to two endmembers: high oxygen abundances in the underlying melt produce compositions rich in oxygen-bearing volatiles (sub-solar C/O) and higher mean molecular weight atmospheres with $\mu \sim 4$ amu, while oxygen-poor melts produce lower mean molecular weight atmospheres dominated by methane and silane (super-solar C/O). The transition between the two regimes is abrupt and depends on melt properties like Mg/Si ratios and oxygen abundances. The different condensation sequences also lead to different thermal profiles, as deep convection is inhibited over different regions due to varying molecular weight gradients. Further experiments and simulations are key to resolving critical uncertainties in the condensation sequences and the corresponding significant impacts on sub-Neptune composition and thermal structure.

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arXiv2026

The Effects of Non-ideal Mixing in Planetary Magma Oceans and Atmospheres

Sub-Neptunes with hydrogen-rich envelopes are expected to sustain long-lived magma oceans that continuously exchange volatiles with their overlying atmospheres. Capturing these interactions is key to understanding the chemical evolution and present-day diversity of sub-Neptunes, super-Earths, and terrestrial planets, particularly in light of new JWST observations and upcoming missions. Recent advances in both geochemistry and astrophysics now allow the integration of experimental constraints and thermodynamic models across melt, metal, and gas phases. Here we extend a global chemical equilibrium model to include non-ideal behavior in all three phases. Our framework combines fugacity corrections for gas species with activity coefficients for silicate and metal species, enabling a fully coupled description of volatile partitioning. We show that for planetary embryos (0.5 M$_\oplus$ at 2350 K), non-ideality introduces only modest corrections to atmosphere-magma ocean interface (AMOI) pressures, volatile inventories, and interior compositions. In contrast, for sub-Neptunes with higher temperatures ($\approx$ 3000 K) and pressures, non-ideal effects are more pronounced, though still modest in absolute terms$-$typically within 20% and at most a factor of two. Including activity and fugacity coefficients simultaneously increases the AMOI pressure, enhances water retention in the mantle and the envelope. Our results demonstrate that non-ideality must be treated globally: applying corrections to only one phase leads to incomplete or even misleading trends. These findings highlight the importance of self-consistent global thermodynamic treatments for interpreting atmospheric spectra and interior structures of sub-Neptunes and super-Earths.

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arXiv2025

Experiments reveal extreme water generation during planet formation

The most abundant type of planet discovered in the Galaxy has no analogue in our Solar System and is believed to consist of a rocky interior with an overlying thick H2 dominated envelope. Models have predicted that the reaction between the atmospheric hydrogen and the underlying magma ocean can lead to the production of significant amounts of water. The models suffer however from the current lack of experimental data on the reaction between hydrogen and silicate melt at high pressures and temperatures. Here we present novel experimental results designed to investigate this interaction. Laser heating diamond anvil cell experiments were conducted between 16 and 60 GPa at temperatures above 4000 K. We find that copious amounts of hydrogen dissolve into the silicate melt with a large dependence on temperature rather than pressure. We also find that the reduction of iron oxide leads to the production of significant amounts of water along with the formation of iron-enriched blebs. Altogether, the results predict that the typical processes attending planet formation will result in significant water production with repercussions for the chemistry and structure of the planetary interior as well as the atmosphere.

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arXiv2025

Water solubility in silicate melts: The effects of melt composition under reducing conditions and implications for nebular ingassing on rocky planets

Rocky planet atmospheres form and evolve through interactions between the planet's surface and interior. If a growing rocky planet acquires enough mass prior to the dissipation of the nebular gas disk, it can gravitationally capture a `primary' atmosphere dominated by H2. At the same time, these young, rocky bodies are likely to have partial or global magma oceans as a result of the heat from accretion, core formation and radioactive decay of short-lived major element isotopes. During this magma ocean stage, the dissolution of volatile, life-essential elements, such as hydrogen in the form of water or H2, into the magma is critical in determining the extent to which a rocky planet can maintain these elements over time. However, our ability to quantify the amount of hydrogen dissolved in the magma oceans of rocky planets is limited by the lack of experimental constraints on H-bearing species' solubilities at relevant pressure and temperature conditions, including those expected for the early Earth. Here we experimentally determine the solubility of water in silicate melts of various compositions in the Ca-Mg-Al-Si-Fe-O system at a total pressure of 1 bar and temperatures from 1673-1823 K, synthesized in a H2-CO2 gas-mixing furnace. We use Bayesian parameter estimation to derive a robust water solubility law that includes the effects of melt composition and temperature. Using this solubility law, we estimate that ~100 ppm of hydrogen can dissolve into a 1 MEarth planet with a surface pressure of ~300 bars set by accretion of solar-like nebular gas. For rocky planets in general, ingassing of a primary atmosphere may be an important source and initial storage mechanism for hydrogen-bearing species in a planet's interior, provided it grew to a sufficient mass within the lifetime of the solar nebula.

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arXiv2023

Rocky planet or water world? Observability of low-density lava world atmospheres

Super-Earths span a wide range of bulk densities, indicating a diversity in interior conditions beyond that seen in the solar system. In particular, an emerging population of low-density super-Earths may be explained by volatile-rich interiors. Among these, low-density lava worlds have dayside temperatures high enough to evaporate their surfaces, providing a unique opportunity to probe their interior compositions and test for the presence of volatiles. In this work, we investigate the atmospheric observability of low-density lava worlds. We use a radiative-convective model to explore the atmospheric structures and emission spectra of these planets, focusing on three case studies with high observability metrics and sub-stellar temperatures spanning $\sim$1900-2800 K: HD 86226c, HD 3167b and 55 Cnce. Given the possibility of mixed volatile and silicate interior compositions for these planets, we consider a range of mixed volatile and rock vapor atmospheric compositions. This includes a range of volatile fractions and three volatile compositions: water-rich (100% H$_2$O), water with CO$_2$ (80% H$_2$O+20% CO$_2$), and a desiccated O-rich scenario (67% O$_2$+33%CO$_2$). We find that spectral features due to H$_2$O, CO$_2$, SiO and SiO$_2$ are present in the infrared emission spectra as either emission or absorption features, depending on dayside temperature, volatile fraction and volatile composition. We further simulate JWST secondary eclipse observations for each of the three case studies, finding that H$_2$O and/or CO$_2$ could be detected with as few as $\sim$5 eclipses. Detecting volatiles in these atmospheres would provide crucial independent evidence that volatile-rich interiors exist among the super-Earth population.

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arXiv2023

Earth shaped by primordial H$_2$ atmospheres

Earth's water, intrinsic oxidation state, and metal core density are fundamental chemical features of our planet. Studies of exoplanets provide a useful context for elucidating the source of these chemical traits. Planet formation and evolution models demonstrate that rocky exoplanets commonly formed with hydrogen-rich envelopes that were lost over time. These findings suggest that Earth may also have formed from bodies with H$_2$-rich primary atmospheres. Here we use a self-consistent thermodynamic model to show that Earth's water, core density, and overall oxidation state can all be sourced to equilibrium between H$_2$-rich primary atmospheres and underlying magma oceans in its progenitor planetary embryos. Water is produced from dry starting materials resembling enstatite chondrites as oxygen from magma oceans reacts with hydrogen. Hydrogen derived from the atmosphere enters the magma ocean and eventually the metal core at equilibrium, causing metal density deficits matching that of Earth. Oxidation of the silicate rocks from solar-like to Earth-like oxygen fugacities also ensues as Si, along with H and O, alloys with Fe in the cores. Reaction with hydrogen atmospheres and metal-silicate equilibrium thus provides a simple explanation for fundamental features of Earth's geochemistry that is consistent with rocky planet formation across the galaxy.

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arXiv2018

Geoscience and the Search for Life Beyond the Solar System

How can scientists conclude with high confidence that an exoplanet hosts life? As telescopes come on line over the next 20 years that can directly observe photons from terrestrial exoplanets, this question will dictate the activities of many scientists across many fields. The expected data will be sparse and with low signal-to-noise, which will make disentangling biosignatures from abiotic features challenging. Our Earth is not just unique in that it hosts life, it is also the only terrestrial planet with direct observations of its interior through seismic waves, and compositional evolution through field and laboratory measurements. This extensive research reveals a planet born from collisions between worlds, followed by a complicated biogeochemical evolution. Exoplanet interiors, on the other hand, can only be constrained by the following observations: 1) photometric and spectroscopic analysis of the planet's atmosphere, 2) spectroscopic and photometric analysis of the host star, and 3) companion planet properties. From these (future) data, astrobiologists must generate plausible compositional and evolutionary models that constrain a potentially habitable exoplanet's internal properties and history, provide environmental context, and rule out geochemical explanations for any putative biosignatures. The goal of this white paper is to frame the role of geophysical and geochemical processes relevant to the search for life beyond the Solar System and to identify critical, but understudied, areas of future research.

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