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Anjali A. A. Piette

Publications and source records attributed to Anjali A. A. Piette.

At least 19 recordsLinked to original sources

No statistically significant evidence for a correlation between stellar and planetary composition

The chemical compositions of planets and their hosts stars are intrinsically linked, having formed from the same protostellar material. Characterising this relationship provides key constraints on the processes governing planetary formation and evolution. Focusing on host stars with near-solar chemical abundances limits our understanding of how planetary composition varies across a broader chemical parameter space. Expanding the sample to include stars with compositions markedly different from the Sun is therefore essential for building a complete picture of star--planet compositional connections. Here, we focus specifically on iron-poor hosts since they are more likely to be alpha-enhanced and represent some of the most chemically distinct stars relative to the Sun (i.e., thick disc stars). We present a sample of 45 stars hosting 64 planets across the super-Earth and sub-Neptune regimes, for which we homogeneously obtain new stellar parameters including abundances, re-derive planetary mass and radius, and model the bulk interior compositions of their planetary companions. No statistically significant evidence for a correlation between stellar and planetary composition was found in our sample. We suggest that this null result is primarily driven by the large uncertainties inherent to both compositional proxies, which may obscure an underlying relationship. Quantifying these uncertainties is therefore a critical step that previous studies have not fully addressed. Furthermore, even with improved precision, uncovering such a relation may require a higher-dimensional treatment that accounts for additional parameters such as planetary equilibrium temperature.

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JWST MIRI reveals a potential atmosphere on the ultra-hot rocky planet TOI-431b

An open question in exoplanet science is whether rocky exoplanets extremely close in to their host stars, `lava worlds', can retain significant atmospheres. Thermal emission observations via secondary eclipse can be used to determine whether a rocky exoplanet possesses an atmosphere. It is expected that an atmosphere could increase the planet's albedo and/or redistribute heat away from the dayside, reducing the secondary eclipse depth measured. Recent eclipse observations of lava planets, rocky planets hot enough to have liquid magma surfaces, have suggested the presence of atmospheres. Here, we present a single JWST MIRI/LRS partial secondary eclipse of the lava planet TOI-431b. We measure an eclipse depth of 81 $\pm$ 16 ppm, which corresponds to a brightness temperature of $1967^{+237}_{-253}$ K and a brightness temperature ratio R = $0.81\pm0.10$, being 1.2 $σ$ higher than the value reported by Spitzer. The observed brightness temperature ratio is 1.8$σ$ below that of a zero-albedo, zero heat redistribution bare rock (R=1). Given that magma pools are expected to have low albedos, we find that our results are best explained by the presence of an atmosphere. Future work to measure the exact composition of TOI-431b's atmosphere and improve models of lava planet atmospheres would better constrain the nature and evolution of lava planets.

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A Highly Reflective Atmosphere on the Lava World TOI-561b Revealed by JWST/NIRSpec Phase Curve

Ultra-short period (USP) rocky planets are expected to be depleted of any substantial gaseous envelope due to the intense irradiation they receive from their host star, making the recent detection of an atmosphere around TOI-561~b particularly surprising. That finding was based on the planet's bulk density and dayside emission spectrum, but full-orbit phase curve observations offer a more comprehensive way to constrain the presence and characteristics of a planet's atmosphere. In this paper, we map TOI-561~b's 3-5~$μ$m emission using JWST/NIRSpec multi-orbit spectroscopic phase curves, explicitly accounting for the curvature of the out-of-eclipse baseline and possible hotspot offsets. From a simple energy balance argument as well as comparing to general circulation models, we find the phase curve observations are best explained with high Bond albedo and moderate global heat transfer. Our 37-hour continuous observation provides a long baseline that allows us to model stellar granulation, the planetary phase curve, and dayside emission simultaneously, effectively disentangling these signals and yielding a dayside emission spectrum that is more robust against stellar variability and consistent with previous eclipse-only fits. Using general circulation model outputs, we constrain where clouds can plausibly form and test candidate compositions, finding that silicate clouds, such as SiO$_2$ and MgSiO$_3$, can form on the dayside near the terminator and explain the observed albedo. Our findings confirm that TOI-561~b appears to have a global reflective atmosphere, suggesting exchange of volatiles with the interior to maintain it.

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GEMS JWST: Hold on to your HATS(-6 b), a sub-solar metallicity giant planet with water, methane and ammonia in its atmosphere

HATS-6 b is one of several recently discovered Giant Exoplanets orbiting M-dwarf Stars (GEMS) and is part of a JWST survey that aims to compare bulk and atmospheric properties of these rare planets against their FGK star counterparts. HATS-6 b is a warm ($\mathrm{T_{eq}}\sim700$ K), Saturn-mass ($M_p\sim0.3~\mathrm{M_J}$), Jupiter-radius ($R_p\sim1~\mathrm{R_J}$) planet that transits its star every $\sim$ 3 days. In this study, we present the transmission spectrum of HATS-6 b obtained with two transits using the PRISM mode of JWST Near Infrared Spectrograph (NIRSpec), spanning a wavelength range of $0.6-5.3$ um. Analyzing these JWST observations using an iterative approach between forward modeling and free chemistry retrievals, we derive a low metallicity ($\log\mathrm{[M/H]}=-1.99^{+0.2}_{-0.2}$) sub-solar C/O ($\log\mathrm{[C/O]=-0.46^{+0.2}_{-0.2}}$) atmosphere, and find strong evidence for H$_2$O, CH$_4$, and NH$_3$ at volume mixing ratios (in $\log[X]$) of $-4.88_{-0.24}^{+0.25}$, $-5.38_{-0.19}^{+0.18}$, and $-6.03_{-0.19}^{+0.18}$, respectively. We consistently retrieve a significantly lower $\mathrm{T_{eq}}$ than predicted from the orbital configuration of HATS-6 b, which was impervious to any data reduction and retrieval choices, suggesting a non-zero bond albedo. Our planetary interior models retrieve bulk metallicities three orders of magnitude larger than our retrieved atmospheric metallicity, also suggesting that the atmosphere is not well-mixed. We find an excess feature around 3 um, and expand on possible explanations for this, such as the presence of HCN or hydrocarbons like C$_2$H$_4$. Yet, due to the degeneracies present for hydrocarbon features in this wavelength region, we do not draw any conclusions about the excess feature and instead encourage further observations and follow-up of this intriguing target.

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Phase-dependent chemistry of WASP-43 b revealed with a suite of one-, two-, and three-dimensional models

Our goal is to investigate the chemistry of the hot Jupiter WASP-43 b in detail using theoretical models, considering the constraints of the James Webb Space Telescope MIRI phase curve. With a suite of pseudo-two-dimensional and three-dimensional photochemical models, we simulate the composition of WASP-43 b in various configurations, and compare them with atmospheric retrieval models. We confirm that disequilibrium chemistry in our theoretical models reduces the methane concentration on the planet night side for wind jet speeds > 500 m/s. Varying the metallicity in the models induces large changes in the CO$_2$ and SO$_2$ concentrations, with SO$_2$ producing mid-infrared absorption features in synthetic emission spectra of the night side at atmospheric metallicities > 10x solar. Our models provide evidence for pole-to-equator circulation enhancing the CH$_4$, NH$_3$, and HCN abundances, which is nonetheless insufficient for detectable spectral features. Finally, we show that H$_2$O, CO, and CO$_2$ are robustly modeled, but species affected by photochemistry are more sensitive to model-specific assumptions and pathways. We conclude that horizontal quenching is the prime mechanism that explains the non-detection of methane in the MIRI phase-curve of WASP-43 b. This mechanism requires only moderate wind speeds and is operative at various thermal structures and atmospheric metallicities. Furthermore, coupled carbon-sulfur chemistry leads to an additional decrease in methane compared to previous models in the literature that did not contain sulfur chemistry. We do not favor a high metallicity as it would have led to observable SO$_2$ features in the MIRI spectra. Our study shows that phase-dependent photochemistry models are essential tools in the interpretation of hot-Jupiter phase curves, but benchmarking is needed to improve the accuracy of photochemical models in the future.

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Understanding eccentric temperate giants: an in-depth study of the architecture and stellar obliquity of the TOI-2134 system

We revisit the TOI-2134 planetary system with three new high-cadence TESS sectors and 98 more spectra. This new analysis confirms the two orbiting planets by simultaneously modelling a total of eight sectors of corrected TESS photometry and 280 HARPS-N and SOPHIE radial velocities: an inner mini-Neptune in a near-circular $9.229198\pm0.000003$ days orbit, and an outer temperate sub-Saturn orbiting with a $95.852840\pm0.000042$ days period and eccentricity of $0.31\pm0.01$. The masses and radii of the planets were computed to be $9.37\pm0.54$ Me and $2.735\pm0.068$ Re for planet b, and $58.3\pm1.9$ Me and $7.35\pm0.18$ Re for planet c. The new data not only improves the detection significance and precisions on the planetary orbits, but also breaks the original multimodality in the eccentricity solution for the outer planet. We also detect a long-term trend in the radial velocity data, which we attribute to a stellar magnetic cycle. We investigate the spin-orbit alignment of the system via observations of the Rossiter-McLaughlin effect for TOI-2134~b with EXPRES and TOI-2134~c with PARAS-2. No RM effect was detected for planet b, but we find a 4.7$σ$ detection of a $59\pm31^{\circ}$ obliquity for planet c. Finally, we examine the architecture of the system, assess its completeness, investigate the planetary interior, and their suitability for follow-up atmospheric analysis.

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Evidence for an Atmosphere on the Ultra-Short Period super-Earth HD 3167 b

'Lava worlds'-Earth-sized planets hot enough (Teq >~ 1100 K) to melt their dayside silicate surfaces-have emerged as promising candidates for atmospheric detection and characterization. Thermal emission observations show an apparent dichotomy: the hottest lava worlds have colder daysides than the temperature of a maximally emitting bare rock, indicating the likely presence of thick and/or reflective atmospheres while the coldest ones do not. However, where in instellation flux this potential bifurcation occurs is uncertain. We present a JWST MIRI LRS eclipse of the ultra-short period (USP) lava world HD 3167 b (Teq = 1786 K, R = 1.6 Rearth, P = 0.96 d) that helps bridge this gap. We measure the white light eclipse depth to be 38 +/- 11 ppm, more than 5 sigma lower than the expected eclipse depth of a dark, maximally hot bare rock. We use this to derive a dayside brightness temperature that is best explained by the presence of an atmosphere that cools the dayside by reflecting incoming starlight and/or efficiently redistributing heat to the planet's nightside. An atmosphere is further compatible with the planet's slight under-density compared to an Earth-like composition. The corresponding dayside emission spectrum is not precise enough to constrain atmospheric composition, motivating follow-up spectroscopic observations with JWST NIRSpec. Lastly, we use our observation and existing data to refine key planetary parameters of the HD 3167 system. HD 3167 b is currently the least irradiated USP super-Earth with evidence for an atmosphere.

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GEMS JWST: HATS-75 b -- A giant planet with a sub-solar metallicity atmosphere orbiting an M-dwarf

HATS-75 b is one of the recently discovered Giant Exoplanets orbiting M-dwarf Stars (GEMS) with a transmission spectrum shaped by both its atmosphere and the active stellar surface it transits. As part of a JWST program studying 7 GEMS, we observed three transits of HATS-75 b with the NIRSpec PRISM instrument (0.6-5.3 um). The planet's spectra exhibit a slightly larger transit depth at shorter wavelengths, indicative of hazes or stellar contamination due to stellar heterogeneities outside the transit chord, i.e., the transit light source (TLS) effect. While both a hazy atmospheric model or TLS model can replicate the transmission spectrum, independent evidence (.e.g, stellar rotation, spot-crossing events) favors a model that includes contamination from unocculted starspots and faculae. Within this stellar heterogeneity / TLS-based framework, atmospheric retrievals yield remarkably low atmospheric metallicity (log[M/H]=-1.74^{+0.92}_{-0.76}) and super-solar carbon-to-oxygen (C/O=1.04^{+0.40}_{-0.09}), which paired with a best-fit interior model with bulk metallicity of Z_p=0.20+/-0.04, implies poor vertical mixing within the planet. Retrievals also detect robust absorption signatures of CH4, CO, and CO2. We obtain only an upper limit for H2O, consistent with its atmospheric spectral features being masked by stellar contamination. These results underscore the importance of accounting for stellar heterogeneity when interpreting exoplanet transmission spectra and highlight HATS-75 b as a significant asset to our understanding of giant exoplanets around M-dwarfs with JWST.

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GEMS JWST: A sub-Solar metallicity atmosphere for giant planet TOI-5293Ab orbiting a rapidly changing M-dwarf

The growing sample of Giant Exoplanets around M-dwarf Stars (GEMS) helps probe the extremes of giant planet formation. Comparing the properties of this sample with their FGK counterparts can help us understand how planet formation and migration depend on stellar mass. We initiated a large Cycle 2 JWST transmission spectroscopy survey of seven GEMS. Here we present the atmospheric characterization using two JWST transits of TOI-5293Ab, a 0.5 $M_J$ planet orbiting an early M-dwarf with a period of $\sim$ 3 days. The two NIRSpec/PRISM transits indicate the planet is eclipsing a rapidly changing (heterogeneous) stellar photosphere. We see that Visit 1 had heterogeneity crossings across the entire transit chord, rendering inferences from it to be unreliable. The Visit 1 spectrum exhibits a downward slope ${<1}$ $μ$m suggestive of stellar contamination from faculae. In contrast, for Visit 2 we are able to model the heterogeneity crossings and obtain a transmission spectrum free from stellar contamination. We therefore limit our conclusions to a detailed analysis of Visit 2, and using Bayesian free chemistry retrievals, we find a low atmospheric metallicity ($\log [\mathrm{M/H}] = -1.03^{+0.53}_{-0.44}$ $\times$ Solar) and slightly super-solar C/O ratio ($1.23^{+2.94}_{-0.75}$). The retrievals yield Bayes factors that indicate strong evidence for \ce{CH4} as well as low significance detections of \ce{CO2}, \ce{H2O}, \ce{NH3}. Finally, using thermal evolution models we find that the radius of TOI-5293Ab is inflated above theoretical expectations ($\sim$ 1.07 $R_J$), despite it having an temperature of $\sim$ 700 K, and hence we were unable to constrain its bulk composition.

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GEMS JWST: Transmission spectroscopy of TOI-5205b reveals significant stellar contamination and a metal-poor atmosphere

Recent discoveries of transiting giant exoplanets ($R_p\gtrsim8\mathrm{~R_\oplus}$) around M dwarfs (GEMS) present an opportunity to investigate their atmospheric compositions and explore how such massive planets form around low-mass stars contrary to the prediction from formation models. We present the first transmission spectra of TOI-5205b, a short-period ($P=1.63~\mathrm{days}$) Jupiter-like planet ($M_p=1.08~\mathrm{M_J}$ and $R_p=0.94~\mathrm{R_J}$) orbiting an M4 dwarf ($M_\star=0.392~\mathrm{M_\odot}$, $R_\star=0.394~\mathrm{R_\odot}$). We obtained three transits using the PRISM mode of the JWST Near Infrared Spectrograph (NIRSpec) spanning $0.6-5.3$ um. The data reveal significant stellar contamination that is evident in the light curves as spot-crossing events and in the transmission spectra as a larger transit depth at bluer wavelengths. Atmospheric retrievals demonstrate that stellar contamination from unocculted starspots and faculae is the dominant component of the transmission spectrum at wavelengths $λ\lesssim3.0$ um, reducing the sensitivity to the presence of clouds or hazes in our models and preventing detection of $\mathrm{H_2O}$. The wavelength coverage enabled a robust detection of $\mathrm{CH_4}$ and $\mathrm{H_2S}$, which have detectable molecular features between $3.0-5.0$ um. For both clear or cloudy atmospheres, Bayesian retrievals consistently favored an atmosphere with sub-solar metallicity ($3σ$ upper limit of $\log\mathrm{[M/H]}\lesssim-1.24$) and super-solar C/O ratio ($3σ$ lower limit of $\log\mathrm{[C/O]}\gtrsim0.09$), although this may partly be driven by the non-detection of water due to stellar contamination. Planetary interior models predict a bulk metallicity of 10--20\%, which is larger than the atmospheric metallicity and suggests that the interior of TOI-5205b is decoupled from its atmosphere.

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Magma ocean interactions can explain JWST observations of the sub-Neptune TOI-270 d

Sub-Neptunes with substantial atmospheres may possess magma oceans in contact with the overlying gas, with chemical interactions between the atmosphere and magma playing an important role in shaping atmospheric composition. Early JWST observations have found high abundances of carbon- and oxygen-bearing molecules in a number of sub-Neptune atmospheres, which may result from processes including accretion of icy material at formation or magma-atmosphere interactions. Previous work examining the effects of magma-atmosphere interactions on sub-Neptunes has mostly been limited to studying conditions at the atmosphere-mantle boundary, without considering implications for the upper atmosphere which is probed by spectroscopic observations. In this work, we present a modeling architecture to determine observable signatures of magma-atmosphere interactions. We combine an equilibrium chemistry code which models reactions between the core, mantle and atmosphere with a radiative-convective model that determines the composition and structure of the observable upper atmosphere. We examine how different conditions at the atmosphere-mantle boundary and different core and mantle compositions impact the upper atmospheric composition. We compare our models to JWST NIRISS+NIRSpec observations of the sub-Neptune TOI-270~d, finding that our models can provide a good fit to the observed transmission spectrum with little fine-tuning. This suggests that magma-atmosphere interactions may be sufficient to explain high abundances of molecules such as H$_2$O, CH$_4$ and CO$_2$ in sub-Neptune atmospheres, without additional accretion of icy material from the protoplanetary disk. Although other processes could lead to similar compositions, our work highlights the need to consider magma-atmosphere interactions when interpreting the observed atmospheric composition of a sub-Neptune.

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A carbon-rich atmosphere on a windy pulsar planet

A handful of enigmatic Jupiter-mass objects have been discovered orbiting pulsars. One such object, PSR\,J2322-2650b, uniquely resembles a hot Jupiter exoplanet due to its minimum density of 1.8 g/cm^3 and its ~1900 K equilibrium temperature. We use JWST to observe PSR J2322-2650b's emission spectrum across an entire orbit. In stark contrast to every known exoplanet orbiting a main-sequence star, we find an atmosphere rich in molecular carbon (C3, C2) with strong westward winds. Our observations open up new exoplanetary chemical (ultra-high C/O and C/N ratios of >100 and >10,000, respectively) and dynamical regimes (ultra-fast rotation with external irradiation) to observational study. The extreme carbon enrichment poses a severe challenge to the current understanding of ``black widow'' companions, which were expected to consist of a wider range of elements due to their origins as stripped stellar cores.

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A Thick Volatile Atmosphere on the Ultrahot Super-Earth TOI-561 b

Ultrashort-period (USP) exoplanets -- with $R_p \leq 2~$R$_{\oplus}$ and periods $\leq$1 day -- are expected to be stripped of volatile atmospheres by intense host star irradiation, which is corroborated by their nominal bulk densities and previous eclipse observations consistent with bare rock surfaces. However, a few USP planets appear anomalously under-dense relative to an Earth-like composition, suggesting an exotic interior structure (e.g., core-less) or a volatile-rich secondary atmosphere increasing their apparent radius. Here we present the first dayside emission spectrum of the low-density (4.3$\pm$0.4 g~cm$^{-3}$) USP planet TOI-561 b, which orbits an iron-poor, alpha-rich, $\sim$10 Gyr old thick disk star. Our 3-5 $μ$m JWST/NIRSpec observations demonstrate the dayside of TOI-561 b is inconsistent with a bare-rock surface at high statistical significance, suggesting instead a thick volatile envelope that is cooling the dayside to well below the $\sim$3000 K expected in the bare-rock or thin-atmosphere case. These results reject the popular hypothesis of complete atmospheric desiccation for highly irradiated exoplanets and support predictions that planetary-scale magma oceans can retain substantial reservoirs of volatiles, opening the geophysical study of ultrahot super-Earths through the lenses of their atmospheres.

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Horizontal and vertical exoplanet thermal structure from a JWST spectroscopic eclipse map

Highly-irradiated giant exoplanets known as "ultra-hot Jupiters" are anticipated to exhibit large variations of atmospheric temperature and chemistry as a function of longitude, latitude, and altitude. Previous observations have hinted at these variations, but the existing data have been fundamentally restricted to probing hemisphere-integrated spectra, thereby providing only coarse information on atmospheric gradients. Here we present a spectroscopic eclipse map of an extrasolar planet, resolving the atmosphere in multiple dimensions simultaneously. We analyze a secondary eclipse of the ultra-hot Jupiter WASP-18b observed with the NIRISS instrument on JWST. The mapping reveals weaker longitudinal temperature gradients than were predicted by theoretical models, indicating the importance of hydrogen dissociation and/or nightside clouds in shaping global thermal emission. Additionally, we identify two thermally distinct regions of the planet's atmosphere: a "hotspot" surrounding the substellar point and a "ring" near the dayside limbs. The hotspot region shows a strongly inverted thermal structure due to the presence of optical absorbers and a water abundance marginally lower than the hemispheric average, in accordance with theoretical predictions. The ring region shows colder temperatures and poorly constrained chemical abundances. Similar future analyses will reveal three-dimensional thermal, chemical, and dynamical properties of a broad range of exoplanet atmospheres.

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SiO and a super-stellar C/O ratio in the atmosphere of the giant exoplanet WASP-121b

Refractory elements such as iron, magnesium, and silicon can be detected in the atmospheres of ultrahot giant planets. This provides an opportunity to quantify the amount of refractory material accreted during formation, along with volatile gases and ices. However, simultaneous detections of refractories and volatiles have proved challenging, as the most prominent spectral features of associated atoms and molecules span a broad wavelength range. Here, using a single JWST observation of the ultrahot giant planet WASP-121b, we report detections of H$_2$O (5.5-13.5$σ$), CO (10.8-12.8$σ$), and SiO (5.7-6.2$σ$) in the planet's dayside atmosphere, and CH$_4$ (3.1-5.1$σ$) in the nightside atmosphere. We measure super-stellar values for the atmospheric C/H, O/H, Si/H, and C/O ratios, which point to the joint importance of pebbles and planetesimals in giant planet formation. The CH$_4$-rich nightside composition is also indicative of dynamical processes, such as strong vertical mixing, having a profound influence on the chemistry of ultrahot giant planets.

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On Linking Planet Formation Models, Protoplanetary Disk Properties, and Mature Gas Giant Exoplanet Atmospheres

Measuring a single elemental ratio (e.g., carbon-to-oxygen) provides insufficient information for understanding the formation mechanisms and evolution that affect our observations of gas giant planet atmospheres. Although the fields of planet formation, protoplanetary disks, and exoplanets are well established and interconnected, our understanding of how to self-consistently and accurately link the theoretical and observational aspects of these fields together is lacking. To foster interdisciplinary conversations, the Max-Planck Institut für Astronomie (MPIA) hosted a week-long workshop called, "Challenge Accepted: Linking Planet Formation with Present-Day Atmospheres." Here, we summarize the latest theories and results in planet formation modeling, protoplanetary disk observations, and atmospheric observations of gas giant atmospheres to address one of the challenges of hosting interdisciplinary conferences: ensuring everyone is aware of the state-of-the-art results and technical language from each discipline represented. Additionally, we highlight key discussions held at the workshop. Our main conclusion is that it is unclear what the ideal observable is to make this link between formation scenarios and exoplanet atmospheres, whether it be multiple elemental abundance ratios, measuring refractory budgets, or something else. Based on discussions held throughout the workshop, we provide several key takeaways of what the workshop attendees feel need the most improvement and exploration within each discipline.

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New Constraints on DMS and DMDS in the Atmosphere of K2-18 b from JWST MIRI

The sub-Neptune frontier has opened a new window into the rich diversity of planetary environments beyond the solar system. The possibility of hycean worlds, with planet-wide oceans and H$_2$-rich atmospheres, significantly expands and accelerates the search for habitable environments elsewhere. Recent JWST transmission spectroscopy of the candidate hycean world K2-18 b in the near-infrared led to the first detections of carbon-bearing molecules CH$_4$ and CO$_2$ in its atmosphere, with a composition consistent with predictions for hycean conditions. The observations also provided a tentative hint of dimethyl sulfide (DMS), a possible biosignature gas, but the inference was of low statistical significance. We report a mid-infrared transmission spectrum of K2-18 b obtained using the JWST MIRI LRS instrument in the ~6-12 $μ$m range. The spectrum shows distinct features and is inconsistent with a featureless spectrum at 3.4-$σ$ significance compared to our canonical model. We find that the spectrum cannot be explained by most molecules predicted for K2-18 b with the exception of DMS and dimethyl disulfide (DMDS), also a potential biosignature gas. We report new independent evidence for DMS and/or DMDS in the atmosphere at 3-$σ$ significance, with high abundance ($\gtrsim$10 ppmv) of at least one of the two molecules. More observations are needed to increase the robustness of the findings and resolve the degeneracy between DMS and DMDS. The results also highlight the need for additional experimental and theoretical work to determine accurate cross sections of important biosignature gases and identify potential abiotic sources. We discuss the implications of the present findings for the possibility of biological activity on K2-18 b.

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TOI-6478 b: a cold under-dense Neptune transiting a fully convective M dwarf from the thick disc

Growing numbers of exoplanet detections continue to reveal the diverse nature of planetary systems. Planet formation around late-type M dwarfs is of particular interest. These systems provide practical laboratories to measure exoplanet occurrence rates for M dwarfs, thus testing how the outcomes of planet formation scale with host mass, and how they compare to Sun-like stars. Here, we report the discovery of TOI-6478b, a cold ($T_{\text{eq}}=204\,$K) Neptune-like planet orbiting an M5 star ($R_\star=0.234\pm0.012\,\text{R}_\odot$, $M_\star=0.230\pm0.007\,\text{M}_\odot$, $T_{\text{eff}}=3230\pm75\,$K) which is a member of the Milky Way's thick disc. We measure a planet radius of $R_b=4.6\pm0.24\,\text{R}_\oplus$ on a $P_b=34.005019\pm0.000025\,$d orbit. Using radial velocities, we calculate an upper mass limit of $M_b\leq9.9\,\text{M}_\oplus$ ($M_b\leq0.6\,\text{M}_{\text{Nep}})$, with $3\,σ$ confidence. TOI-6478b is a milestone planet in the study of cold, Neptune-like worlds. Thanks to its large atmospheric scale height, it is amenable to atmospheric characterisation with facilities such as JWST, and will provide an excellent probe of atmospheric chemistry in this cold regime. It is one of very few transiting exoplanets that orbit beyond their system's ice-line whose atmospheric chemical composition can be measured. Based on our current understanding of this planet, we estimate TOI-6478b's spectroscopic features (in transmission) can be $\sim2.5\times$ as high as the widely studied planet K2-18b.

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