Searcharxiv⌕ Search

arXiv subjects

Anjali A. A. Piette

Publications and source records attributed to Anjali A. A. Piette.

At least 37 records · Page 2Linked to original sources
arXiv2025

The radiative effects of photochemical hazes on the atmospheric circulation and phase curves of sub-Neptunes

Measuring the atmospheric composition of hazy sub-Neptunes like GJ~1214b through transmission spectroscopy is difficult because of the degeneracy between mean molecular weight and haziness. It has been proposed that phase curve observations can break this degeneracy because of the relationship between mean molecular weight (MMW) and phase curve amplitude. However, photochemical hazes can strongly affect phase curve amplitudes as well. We present a large set of GCM simulations of the sub-Neptune GJ~1214b that include photochemical hazes with varying atmospheric composition, haze opacity and haze optical properties. In our simulations, photochemical hazes cause temperature changes of up to 200~K, producing thermal inversions and cooling deeper regions. This results in increased phase curve amplitudes and adds a considerable scatter to the phase curve amplitude--metallicity relationship. However, we find that if the haze production rate is high enough to significantly alter the phase curve, the secondary eclipse spectrum will exhibit either emission features or strongly muted absorption features. Thus, the combination of a white-light phase curve and a secondary eclipse spectrum can successfully distinguish between a hazy, lower MMW and a clear, high MMW scenario.

astro-ph.EP↗
arXiv2025

Clouds and Hazes in GJ 1214b's Metal-Rich Atmosphere

The sub-Neptune GJ 1214b has an infamously flat transmission spectrum, likely due to thick aerosols in its atmosphere. A recent JWST MIRI spectroscopic phase curve of GJ 1214 b added to this picture, suggesting a highly reflective and metal-rich atmosphere. Using a 3D General Circulation Model with both photochemical hazes and condensate clouds, we characterize how different aerosol types affect the atmospheric structure of GJ 1214 b and manifest in its spectroscopic phase curve. Additionally, we reanalyze the original GJ 1214 b JWST phase curve. The reanalysis shows a hotter nightside, similar dayside temperature, and a lower, but still elevated, Bond albedo (0.42 +/- 0.11) than the original results. We find that a scenario with both clouds and hazes is most consistent with the JWST phase curve. Reflective clouds or hazes are needed to explain the large Bond albedo, and hazes or a super-solar metallicity help account for the several hundred Kelvin day-night temperature difference measured by the phase curve.

astro-ph.EP↗
arXiv2024

New insights into the internal structure of GJ 1214 b informed by JWST

Recent JWST observations of the sub-Neptune GJ 1214 b suggest that it hosts a high-metallicity (>100x solar), hazy atmosphere. Emission spectra of the planet show molecular absorption features, most likely due to atmospheric H2O. In light of this new information, we conduct a thorough reevaluation of the planet's internal structure. We consider interior models with mixed H/He/H2O envelopes of varying composition, informed by atmospheric constraints from the JWST phase curve, in order to determine possible bulk compositions and internal structures. Self-consistent atmospheric models consistent with the JWST observations are used to set boundary conditions for the interior. We find that a total envelope mass fraction of at least 8.1% is required to explain the planet's mass and radius. Regardless of H2O content, the maximum H/He mass fraction of the planet is 5.8%. We find that a 1:1 ice-to-rock ratio along with 3.4-4.8% H/He is also a permissible solution. In addition, we consider a pure H2O (steam) envelope and find that such a scenario is possible, albeit with a high ice-to-rock ratio of at least 3.76:1, which may be unrealistic from a planet formation standpoint. We discuss possible formation pathways for the different internal structures that are consistent with observations. Since our results depend strongly on the atmospheric composition and haze properties, more precise observations of the planet's atmosphere would allow for further constraints on its internal structure. This type of analysis can be applied to any sub-Neptune with atmospheric constraints to better understand its interior.

astro-ph.EP↗
arXiv2024

Sulphur dioxide in the mid-infrared transmission spectrum of WASP-39b

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $μ$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $μ$m in the 5-12 $μ$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$σ$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $μ$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range.

astro-ph.EP↗
arXiv2024

Simultaneous retrieval of orbital phase resolved JWST/MIRI emission spectra of the hot Jupiter WASP-43b: evidence of water, ammonia and carbon monoxide

Spectroscopic phase curves of hot Jupiters measure their emission spectra at multiple orbital phases, thus enabling detailed characterisation of their atmospheres. Precise constraints on the atmospheric composition of these exoplanets offer insights into their formation and evolution. We analyse four phase-resolved emission spectra of the hot Jupiter WASP-43b, generated from a phase curve observed with the MIRI/LRS onboard the JWST, to retrieve its atmospheric properties. Using a parametric 2D temperature model and assuming a chemically homogeneous atmosphere within the observed pressure region, we simultaneously fit the four spectra to constrain the abundances of atmospheric constituents, thereby yielding more precise constraints than previous work that analysed each spectrum independently. Our analysis reveals statistically significant evidence of NH3 (4$σ$) in a hot Jupiter's emission spectra for the first time, along with evidence of H2O (6.5$σ$), CO (3.1$σ$), and a non-detection of CH4. With our abundance constraints, we tentatively estimate the metallicity of WASP-43b at 0.6-6.5$\times$solar and its C/O ratio at 0.6-0.9. Our findings offer vital insights into the atmospheric conditions and formation history of WASP-43b by simultaneously constraining the abundances of carbon, oxygen, and nitrogen-bearing species.

astro-ph.EP↗
arXiv2024

Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $μ$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$σ$ upper limit of 1-6 parts per million, depending on model assumptions).

astro-ph.EP↗
arXiv2023

Carbon-bearing Molecules in a Possible Hycean Atmosphere

The search for habitable environments and biomarkers in exoplanetary atmospheres is the holy grail of exoplanet science. The detection of atmospheric signatures of habitable Earth-like exoplanets is challenging due to their small planet-star size contrast and thin atmospheres with high mean molecular weight. Recently, a new class of habitable exoplanets, called Hycean worlds, has been proposed, defined as temperate ocean-covered worlds with H2-rich atmospheres. Their large sizes and extended atmospheres, compared to rocky planets of the same mass, make Hycean worlds significantly more accessible to atmospheric spectroscopy with the JWST. Here we report a transmission spectrum of the candidate Hycean world, K2-18 b, observed with the JWST NIRISS and NIRSpec instruments in the 0.9-5.2 $μ$m range. The spectrum reveals strong detections of methane (CH4) and carbon dioxide (CO2) at 5$σ$ and 3$σ$ confidence, respectively, with high volume mixing ratios of ~1% each in a H2-rich atmosphere. The abundant CH4 and CO2 along with the non-detection of ammonia (NH3) are consistent with chemical predictions for an ocean under a temperate H2-rich atmosphere on K2-18 b. The spectrum also suggests potential signs of dimethyl sulfide (DMS), which has been predicted to be an observable biomarker in Hycean worlds, motivating considerations of possible biological activity on the planet. The detection of CH4 resolves the long-standing missing methane problem for temperate exoplanets and the degeneracy in the atmospheric composition of K2-18 b from previous observations. We discuss possible implications of the findings, open questions, and future observations to explore this new regime in the search for life elsewhere.

astro-ph.EP↗
arXiv2023

Rocky planet or water world? Observability of low-density lava world atmospheres

Super-Earths span a wide range of bulk densities, indicating a diversity in interior conditions beyond that seen in the solar system. In particular, an emerging population of low-density super-Earths may be explained by volatile-rich interiors. Among these, low-density lava worlds have dayside temperatures high enough to evaporate their surfaces, providing a unique opportunity to probe their interior compositions and test for the presence of volatiles. In this work, we investigate the atmospheric observability of low-density lava worlds. We use a radiative-convective model to explore the atmospheric structures and emission spectra of these planets, focusing on three case studies with high observability metrics and sub-stellar temperatures spanning $\sim$1900-2800 K: HD 86226c, HD 3167b and 55 Cnce. Given the possibility of mixed volatile and silicate interior compositions for these planets, we consider a range of mixed volatile and rock vapor atmospheric compositions. This includes a range of volatile fractions and three volatile compositions: water-rich (100% H$_2$O), water with CO$_2$ (80% H$_2$O+20% CO$_2$), and a desiccated O-rich scenario (67% O$_2$+33%CO$_2$). We find that spectral features due to H$_2$O, CO$_2$, SiO and SiO$_2$ are present in the infrared emission spectra as either emission or absorption features, depending on dayside temperature, volatile fraction and volatile composition. We further simulate JWST secondary eclipse observations for each of the three case studies, finding that H$_2$O and/or CO$_2$ could be detected with as few as $\sim$5 eclipses. Detecting volatiles in these atmospheres would provide crucial independent evidence that volatile-rich interiors exist among the super-Earth population.

astro-ph.EP↗
arXiv2023

A reflective, metal-rich atmosphere for GJ 1214b from its JWST phase curve

There are no planets intermediate in size between Earth and Neptune in our Solar System, yet these objects are found around a substantial fraction of other stars. Population statistics show that close-in planets in this size range bifurcate into two classes based on their radii. It is hypothesized that the group with larger radii (referred to as "sub-Neptunes") is distinguished by having hydrogen-dominated atmospheres that are a few percent of the total mass of the planets. GJ 1214b is an archetype sub-Neptune that has been observed extensively using transmission spectroscopy to test this hypothesis. However, the measured spectra are featureless, and thus inconclusive, due to the presence of high-altitude aerosols in the planet's atmosphere. Here we report a spectroscopic thermal phase curve of GJ 1214b obtained with JWST in the mid-infrared. The dayside and nightside spectra (average brightness temperatures of 553 $\pm$ 9 and 437 $\pm$ 19 K, respectively) each show >3$σ$ evidence of absorption features, with H$_2$O as the most likely cause in both. The measured global thermal emission implies that GJ 1214b's Bond albedo is 0.51 $\pm$ 0.06. Comparison between the spectroscopic phase curve data and three-dimensional models of GJ 1214b reveal a planet with a high metallicity atmosphere blanketed by a thick and highly reflective layer of clouds or haze.

astro-ph.EP↗
arXiv2023

The Hazy and Metal-Rich Atmosphere of GJ 1214 b Constrained by Near and Mid-Infrared Transmission Spectroscopy

The near-infrared transmission spectrum of the warm sub-Neptune exoplanet GJ 1214 b has been observed to be flat and featureless, implying a high metallicity atmosphere with abundant aerosols. Recent JWST MIRI LRS observations of a phase curve of GJ 1214 b showed that its transmission spectrum is flat out into the mid-infrared. In this paper, we use the combined near- and mid-infrared transmission spectrum of GJ 1214 b to constrain its atmospheric composition and aerosol properties. We generate a grid of photochemical haze models using an aerosol microphysics code for a number of background atmospheres spanning metallicities from 100 to 1000 $\times$ solar, as well as a steam atmosphere scenario. The flatness of the combined data set largely rules out atmospheric metallicities $\leq$300 $\times$ solar due to their large corresponding molecular feature amplitudes, preferring values $\geq$1000 $\times$ solar and column haze production rates $\geq$10$^{-10}$ g cm$^{-2}$ s$^{-1}$. The steam atmosphere scenario with similarly high haze production rates also exhibit sufficiently small molecular features to be consistent with the transmission spectrum. These compositions imply that atmospheric mean molecular weights $\geq$15 g mol$^{-1}$ are needed to fit the data. Our results suggest that haze production is highly efficient on GJ 1214 b and could involve non-hydrocarbon, non-nitrogen haze precursors. Further characterization of GJ 1214 b's atmosphere would likely require multiple transits and eclipses using JWST across the near and mid-infrared, potentially complemented by groundbased high resolution transmission spectroscopy.

astro-ph.EP↗
arXiv2023

TOI-5205 b: A Short-period Jovian Planet Transiting a Mid-M Dwarf

We present the discovery of TOI-5205~b, a transiting Jovian planet orbiting a solar metallicity M4V star, which was discovered using Transiting Exoplanet Survey Satellite photometry and then confirmed using a combination of precise radial velocities, ground-based photometry, spectra, and speckle imaging. TOI-5205~b has one of the highest mass ratios for M dwarf planets with a mass ratio of almost 0.3$\%$, as it orbits a host star that is just $0.392 \pm 0.015$ \solmass{}. Its planetary radius is $1.03 \pm 0.03~R_J$, while the mass is $1.08 \pm 0.06~M_J$. Additionally, the large size of the planet orbiting a small star results in a transit depth of $\sim 7\%$, making it one of the deepest transits of a confirmed exoplanet orbiting a main-sequence star. The large transit depth makes TOI-5205~b a compelling target to probe its atmospheric properties, as a means of tracing the potential formation pathways. While there have been radial-velocity-only discoveries of giant planets around mid-M dwarfs, this is the first transiting Jupiter with a mass measurement discovered around such a low-mass host star. The high mass of TOI-5205~b stretches conventional theories of planet formation and disk scaling relations that cannot easily recreate the conditions required to form such planets.

astro-ph.EP↗
arXiv2023

A broadband thermal emission spectrum of the ultra-hot Jupiter WASP-18b

Close-in giant exoplanets with temperatures greater than 2,000 K (''ultra-hot Jupiters'') have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble and Spitzer Space Telescopes. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS instrument on JWST. The data span 0.85 to 2.85 $μ$m in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at $>$6$σ$ confidence) and evidence for optical opacity, possibly due to H$^-$, TiO, and VO (combined significance of 3.8$σ$). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy element abundance (''metallicity'', M/H = 1.03$_{-0.51}^{+1.11}$ $\times$ solar), and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the sub-stellar point that decreases steeply and symmetrically with longitude toward the terminators.

astro-ph.EP↗
arXiv2022

Constraints on TESS albedos for five hot Jupiters

Photometric observations of occultations of transiting exoplanets can place important constraints on the thermal emission and albedos of their atmospheres. We analyse photometric measurements and derive geometric albedo ($A_\mathrm{g}$) constraints for five hot Jupiters observed with TESS in the optical: WASP-18 b, WASP-36 b, WASP-43 b, WASP-50 b and WASP-51 b. For WASP-43 b, our results are complemented by a VLT/HAWK-I observation in the near-infrared at $2.09~μ$m. We derive the first geometric albedo constraints for WASP-50 b and WASP-51 b: $A_\mathrm{g}<0.445$ and $A_\mathrm{g}<0.368$, respectively. We find that WASP-43 b and WASP-18 b are both consistent with low geometric albedos ($A_\mathrm{g}<0.16$) even though they lie at opposite ends of the hot Jupiter temperature range with equilibrium temperatures of $\sim1400$ K and $\sim2500$ K, respectively. We report self-consistent atmospheric models which explain broadband observations for both planets from TESS, \HST, \Spitzer and VLT/HAWK-I. We find that the data of both hot Jupiters can be explained by thermal emission alone and inefficient day-night energy redistribution. The data do not require optical scattering from clouds/hazes, consistent with the low geometric albedos observed.

astro-ph.EP↗
arXiv2021

HyDRo: Atmospheric Retrieval of Rocky Exoplanets in Thermal Emission

Emission spectroscopy is a promising technique to observe atmospheres of rocky exoplanets, probing both their chemistry and thermal profiles. We present HyDRo, an atmospheric retrieval framework for thermal emission spectra of rocky exoplanets. HyDRo does not make prior assumptions about the background atmospheric composition, and can therefore be used to interpret spectra of secondary atmospheres with unknown compositions. We use HyDRo to assess the chemical constraints which can be placed on rocky exoplanet atmospheres using JWST. Firstly, we identify the best currently-known rocky exoplanet candidates for spectroscopic observations in thermal emission with JWST, finding >30 known rocky exoplanets whose thermal emission will be detectable by JWST/MIRI in fewer than 10 eclipses at R~10. We then consider the observations required to characterise the atmospheres of three promising rocky exoplanets across the ~400-800 K equilibrium temperature range: Trappist-1 b, GJ 1132 b, and LHS 3844 b. Considering a range of CO_2- to H_2O-rich atmospheric compositions, we find that as few as 8 eclipses of LHS 3844 b or GJ 1132 b with MIRI will be able to place important constraints on the chemical compositions of their atmospheres. This includes confident detections of CO_2 and H_2O in the case of a cloud-free CO_2-rich composition, besides ruling out a bare rock scenario. Similarly, 30 eclipses of Trappist-1 b with MIRI/LRS can allow detections of a cloud-free CO_2-rich or CO_2-H_2O atmosphere. HyDRo will allow important atmospheric constraints for rocky exoplanets using JWST observations, providing clues about their geochemical environments.

astro-ph.EP↗
arXiv2021

Habitability and Biosignatures of Hycean Worlds

We investigate a new class of habitable planets composed of water-rich interiors with massive oceans underlying H2-rich atmospheres, referred to here as Hycean worlds. With densities between those of rocky super-Earths and more extended mini-Neptunes, Hycean planets can be optimal candidates in the search for exoplanetary habitability and may be abundant in the exoplanet population. We investigate the bulk properties (masses, radii, and temperatures), potential for habitability, and observable biosignatures of Hycean planets. We show that Hycean planets can be significantly larger compared to previous considerations for habitable planets, with radii as large as 2.6 Earth radii (2.3 Earth radii) for a mass of 10 Earth masses (5 Earth masses). We construct the Hycean habitable zone (HZ), considering stellar hosts from late M to sun-like stars, and find it to be significantly wider than the terrestrial-like HZ. While the inner boundary of the Hycean HZ corresponds to equilibrium temperatures as high as ~500 K for late M dwarfs, the outer boundary is unrestricted to arbitrarily large orbital separations. Our investigations include tidally locked `Dark Hycean' worlds that permit habitable conditions only on their permanent nightsides and `Cold Hycean' worlds that see negligible irradiation. Finally, we investigate the observability of possible biosignatures in Hycean atmospheres. We find that a number of trace terrestrial biomarkers which may be expected to be present in Hycean atmospheres would be readily detectable using modest observing time with the James Webb Space Telescope (JWST). We identify a sizable sample of nearby potential Hycean planets that can be ideal targets for such observations in search of exoplanetary biosignatures.

astro-ph.EP↗
arXiv2020

On the Temperature Profiles and Emission Spectra of Mini-Neptune Atmospheres

Atmospheric observations of mini-Neptunes orbiting M-dwarfs are beginning to provide constraints on their chemical and thermal properties, while also providing clues about their interiors and potential surfaces. With their relatively large scale heights and large planet-star contrasts, mini-Neptunes are currently ideal targets towards the goal of characterising temperate low-mass exoplanets. Understanding the thermal structures and spectral appearances of mini-Neptunes is important to understand various aspects of their atmospheres, including radiative/convective energy transport, boundary conditions for the interior, and their potential habitability. In the present study, we explore these aspects of mini-Neptunes using self-consistent models of their atmospheres. We begin by exploring the effects of irradiation, internal flux, metallicity, clouds and hazes on the atmospheric temperature profiles and thermal emission spectra of temperate mini-Neptunes. In particular, we investigate the impact of these properties on the radiative-convective boundary and the thermodynamic conditions in the lower atmosphere, which serves as the interface with the interior and/or a potential surface. Building on recent suggestions of habitability of the mini-Neptune K2-18 b, we find a range of physically-motivated atmospheric conditions that allow for liquid water under the H_2-rich atmospheres of such planets. We find that observations of thermal emission with JWST/MIRI spectrophotometry can place useful constraints on the habitability of temperate mini-Neptunes such as K2-18 b, and provide more detailed constraints on the chemical and thermal properties of warmer planets such as GJ 3470 b. Our results underpin the potential of temperate mini-Neptunes such as K2-18 b as promising candidates in the search for habitable exoplanets.

astro-ph.EP↗
arXiv2020

Considerations for Atmospheric Retrieval of High-Precision Brown Dwarf Spectra

Isolated brown dwarfs provide remarkable laboratories for understanding atmospheric physics in the low-irradiation regime, and can be observed more precisely than exoplanets. As such, they provide a glimpse into the future of high-SNR observations of exoplanets. In this work, we investigate several new considerations that are important for atmospheric retrievals of high-quality thermal emission spectra of sub-stellar objects. We pursue this using an adaptation of the HyDRA atmospheric retrieval code. We propose a parametric pressure-temperature (P-T) profile for brown dwarfs consisting of multiple atmospheric layers, parameterised by the temperature change across each layer. This model allows the steep temperature gradient of brown dwarf atmospheres to be accurately retrieved while avoiding commonly-encountered numerical artefacts. The P-T model is especially flexible in the photosphere, which can reach a few tens of bar for T-dwarfs. We demonstrate an approach to include model uncertainties in the retrieval, focusing on uncertainties introduced by finite spectral and vertical resolution in the atmospheric model used for retrieval (~8\% in the present case). We validate our retrieval framework by applying it to a simulated data set and then apply it to the HST/WFC3 spectrum of the T-dwarf 2MASS J2339+1352. We retrieve sub-solar abundances of H2O and CH4 in the object at ~0.1 dex precision. Additionally, we constrain the temperature structure to within ~100 K in the photosphere. Our results demonstrate the promise of high-SNR spectra to provide high-precision abundance estimates of sub-stellar objects.

astro-ph.EP↗
arXiv2020

Assessing Spectra and Thermal Inversions due to TiO in Hot Jupiter Atmospheres

Recent detections of thermal inversions in the dayside atmospheres of some hot Jupiters are motivating new avenues to understand the interplay between their temperature structures and other atmospheric conditions. In particular, TiO has long been proposed to cause thermal inversions in hot Jupiters, depending on other factors such as stellar irradiation, C/O, and vertical mixing. TiO also has spectral features in the optical and near-infrared that have been detected. However, interpretations of TiO signatures rely on the accuracy of TiO opacity used in the models. The recently reported Toto TiO line list provides a new opportunity to investigate these dependencies, which is the goal of the present work. First, we investigate how the Toto line list affects observable transmission and emission spectra of hot Jupiters at low and high resolution. The improvement in the Toto line list compared to a previous line list results in observable differences in the model spectra, particularly in the optical at high resolution. Secondly, we explore the interplay between temperature structure, irradiation and composition with TiO as the primary source of optical opacity, using 1D self-consistent atmospheric models. Among other trends, we find that the propensity for thermal inversions due to TiO peaks at C/O$\sim$0.9, consistent with recent studies. Using these models, we further assess metrics to quantify thermal inversions due to TiO, compared to frequently-used Spitzer photometry, over a range in C/O, irradiation, metallicity, gravity and stellar type.

astro-ph.EP↗