arXiv subjects

Anne Amy-Klein

Publications and source records attributed to Anne Amy-Klein.

At least 19 recordsLinked to original sources

arXiv2026

International Optical Clock Comparison Using the European Optical Fiber Network

Optical clocks have achieved remarkable estimated fractional frequency uncertainties reaching the $10^{-18}$ level and below, enabling applications in fundamental physics, general relativity, and geodesy. However, the challenge of verifying the international consistency of optical clocks remains critical as efforts intensify toward redefining the SI second based on an optical transition or transitions. We report on a two-month international clock comparison campaign involving seven optical clocks in four national metrology institutes (INRIM, LNE-OP, NPL, and PTB) connected via the optical fiber network established in Europe. The campaign resulted in optical frequency ratios with uncertainties ranging from $7.7\times10^{-18}$ to $6.1\times10^{-17}$. Among the results, the $^{171}$Yb$^+$(E3) clocks at NPL and PTB demonstrated agreement within an uncertainty of $7.7\times10^{-18}$, marking the first international verification of two independently developed optical clocks below one part in $10^{17}$. The operation of the $^{199}$Hg clock at LNE-OP (formerly LNE-SYRTE) resulted in frequency ratios with improved uncertainties with $^{171}$Yb$^+$(E3), $^{171}$Yb, and $^{87}$Sr optical clocks. These results provide input for the redefinition of the second and underscore how fiber-linked clock networks can advance metrology and scientific applications.

physics.atom-ph↗

arXiv2025

Coordinated international comparisons between optical clocks connected via fiber and satellite links

Optical clocks provide ultra-precise frequency references that are vital for international metrology as well as for tests of fundamental physics. To investigate the level of agreement between different clocks, we simultaneously measured the frequency ratios between ten optical clocks in six different countries, using fiber and satellite links. This is the largest coordinated comparison to date, from which we present a subset of 38 optical frequency ratios and an evaluation of the correlations between them. Four ratios were measured directly for the first time, while others had significantly lower uncertainties than previously achieved, supporting the advance towards a redefinition of the second and the use of optical standards for international time scales.

physics.atom-ph↗

arXiv2025

Extending frequency metrology to increasingly complex molecules: SI-traceable sub-Doppler mid-IR spectroscopy of trioxane

Bringing increasingly complex polyatomic molecules within reach of precision measurement experiments offers fascinating and far-reaching prospects ranging from Earth sciences and astrophysics, to metrology and quantum sciences. Here, we demonstrate sub-Doppler spectroscopic measurements in the mid-IR fingerprint region of, to our knowledge, the largest molecule to date. To this end, we use a high-resolution ~10.3 $\mu$m spectrometer based on a sub-Hz quantum cascade laser remotely calibrated against state-of-the-art primary frequency standards via a metrology-grade fibre link. We perform saturated absorption spectroscopy in the v5 CO stretching mode of 1,3,5-trioxane, (H2CO)3, at a resolution of ~100 kHz, allowing us to measure the absolute frequency of hundreds of rovibrational transitions at unprecedented uncertainties for such a complex species, as low as ~5 kHz. Our work demonstrates the extension of frequency metrology methodologies to ever larger molecular system, confirming the potential of the technologies we develop for bringing increasingly complex species within reach of ultra-precise measurement experiments.

physics.atom-ph↗

arXiv2024

International comparison of optical frequencies with transportable optical lattice clocks

Optical clocks have improved their frequency stability and estimated accuracy by more than two orders of magnitude over the best caesium microwave clocks that realise the SI second. Accordingly, an optical redefinition of the second has been widely discussed, prompting a need for the consistency of optical clocks to be verified worldwide. While satellite frequency links are sufficient to compare microwave clocks, a suitable method for comparing high-performance optical clocks over intercontinental distances is missing. Furthermore, remote comparisons over frequency links face fractional uncertainties of a few $10^{-18}$ due to imprecise knowledge of each clock's relativistic redshift, which stems from uncertainty in the geopotential determined at each distant location. Here, we report a landmark campaign towards the era of optical clocks, where, for the first time, state-of-the-art transportable optical clocks from Japan and Europe are brought together to demonstrate international comparisons that require neither a high-performance frequency link nor information on the geopotential difference between remote sites. Conversely, the reproducibility of the clocks after being transported between countries was sufficient to determine geopotential height offsets at the level of 4 cm. Our campaign paves the way for redefining the SI second and has a significant impact on various applications, including tests of general relativity, geodetic sensing for geosciences, precise navigation, and future timing networks.

physics.atom-ph↗

arXiv2022

Limitations due to residual interference in a fiber-based optical frequency reference at 1.55 $μ$m

We present an experimental investigation of the stability limits specific to optical frequency standards using a fiber-optic architecture and semiconductor lasers. A compact setup composed of a semiconductor laser frequency-locked onto an acetylene transition detected in saturated absorption has been implemented using only fiber-optic components. Fiber optic technology allows compact and reliable solutions for various applications. However, for high sensitivity and stability applications such as metrology, residual reflections induced by optical index inhomogeneities in connectors and fiber-coupled components leading to spurious interference significantly limit performance. We have examined the origin of the interference fringes superimposed on the detected signal and the limitations they cause to the frequency stability of the reference. The effects of temperature and beam power fluctuations are also examined. Our results show that the frequency stability is limited in the 10-13 range by the effect of interference fringes due to use of fiber components.

physics.ins-det↗

arXiv2019

Combining fiber Brillouin amplification with a repeater laser station for fiber-based optical frequency dissemination over 1400 km

We investigate optical frequency dissemination over a 1400 km long fiber link in looped configuration over a pair of underground fibers between Braunschweig and Strasbourg. This fiber link is the first to combine fiber Brillouin amplifiers with a repeater laser station. Phase-coherent operation over more than five days is demonstrated. We analyze the repeatability of the performance over four campaigns and present results of 65 days in total. The weighted mean of the fractional frequency offset of the transferred optical frequency over the complete data set is $(-1.1 \pm 0.4) \times 10^{-20}$. By analyzing the stabilization signals of the two individual fibers, the correlation of the phase noise on the two fibers is shown to be >98%.

physics.ins-det↗

arXiv2019

Two-Branch Fiber Link for International Clock Networks

We present our work on realizing two-branch fiber links enabling multiple-partner clock comparisons in Europe. We report in detail on the setup connecting two long haul links, and report for the relative frequency stability and accuracy. We report on a combined uptime of 90% for our dual-branch link during almost one month. We finally discuss the combined uncertainty contribution of the ensemble of the link architecture to a clock comparison. We show that the frequency transfer uncertainty is 2 x 10 --19 .

quant-ph↗

arXiv2019

Studying fundamental limit of optical fiber links to $10^{-21}$ level

We present an hybrid fiber link combining effective optical frequency transfer and evaluation of performances with a self-synchronized two-way comparison. It enables us to detect the round-trip fiber noise and each of the forward and backward one-way fiber noises simultaneously. The various signals acquired with this setup allow us to study quantitatively several properties of optical fiber links. We check the reciprocity of the accumulated noise forth and back over a bi-directional fiber to the level of $3.1(\pm 3.9)\times 10^{-20}$ based on a 160000s continuous data. We also analyze the noise correlation between two adjacent fibers and show the first experimental evidence of interferometric noise at very low Fourier frequency. We estimate redundantly and consistently the stability and accuracy of the transferred optical frequency over 43~km at $4\times 10^{-21}$ level after 16 days of integration and demonstrate that frequency comparison with instability as low as $8\times 10^{-18}$ would be achievable with uni-directional fibers in urban area.

quant-ph↗

arXiv2017

Hybrid fiber links for accurate optical frequency comparisons

We present the first experimental demonstration over a 43-km-long urban fiber network of a local two-way optical frequency comparison, which does not require any synchronization of the measurements. It was combined with a regular active-noise compensation on another parallel fiber leading to a very reliable and robust frequency transfer. This hybrid scheme enables us to investigate the major limiting factors of the local two-way comparison. We analyze the contribution to the phase noise of the recovered signal by the interferometers at local and remote places. By using the ability of this set up to be injected by a single laser or two independent lasers, we measure the contribution to the long-term instability by the demodulated laser instabilities. We show that a fractional frequency instability level of $1\times10^{-20}$ at 10 000 s can be obtained with this simple setup after 43-km-long propagation in an urban area.

quant-ph↗

arXiv2016

Ultra-stable optical frequency dissemination on a multi-access fibre network

We report the dissemination of an ultrastable optical frequency signal to two distant users simultaneously using a branching network. The ultrastable signal is extracted along a main fibre link; it is optically tracked with a narrow-linewidth laser diode, which light is injected in a secondary link. The propagation noise of both links is actively compensated. We implement this scheme with two links of 50-km fibre spools, the extraction being setup at the mid-point of the main link. We show that the extracted signal at the end of the secondary link exhibits fractional frequency instability of 1.4x10-15 at 1-s measurement time, almost equal to the 1.3x10-15 instability of the main link output end. The long-term instabilities are also very similar, at a level of 3-5x10-20 at 3x104-s integration time. We also show that the setting up of this extraction device, or a simpler one, at the main link input, can test the proper functioning of the noise rejection on this main link. This work is a significant step towards a robust and flexible ultra-stable network for multi-users dissemination.

quant-ph↗

arXiv2015

Cascaded optical fiber link using the Internet network for remote clocks comparison

We report a cascaded optical link of 1100 km for ultra-stable frequency distribution over an Internet fiber network. The link is composed of four spans for which the propagation noise is actively compensated. The robustness and the performance of the link are ensured by five fully automated optoelectronic stations, two of them at the link ends, and three deployed on the field and connecting the spans. This device coherently regenerates the optical signal with the heterodyne optical phase locking of a low-noise laser diode. Optical detection of the beat-note signals for the laser lock and the link noise compensation are obtained with stable and low-noise fibered optical interferometer. We show 3.5 days of continuous operation of the noise-compensated 4-span cascaded link leading to fractional frequency instability of 4x10-16 at 1-s measurement time and 1x10-19 at 2000 s. This cascaded link was extended to 1480-km with the same performance. This work is a significant step towards a sustainable wide area ultra-stable optical frequency distribution and comparison network at a very high level of performance.

physics.optics↗

arXiv2015

Frequency and time transfer for metrology and beyond using telecommunication network fibres

The distribution and the comparison of an ultra-stable optical frequency and accurate time using optical fibres have been greatly improved in the last ten years. The frequency stability and accuracy of optical links surpass well-established methods using the global navigation satellite system and geostationary satellites. In this paper, we present a review of the methods and the results obtained. We show that public telecommunication network carrying Internet data can be used to compare and distribute ultra-stable metrological signals over long distances. This novel technique paves the way for the deployment of a national and continental ultra-stable metrological optical network.

physics.optics↗

arXiv2014

Tackling the Limits of Optical Fiber Links

We theoretically and experimentally investigate relevant noise processes arising in optical fiber links, which fundamentally limit their relative stability. We derive the unsuppressed delay noise for three configurations of optical links: two-way method, Sagnac interferometry, and actively compensated link, respectively designed for frequency comparison, rotation sensing, and frequency transfer. We also consider an alternative two-way setup allowing real-time frequency comparison and demonstrate its effectiveness on a proof-of-principle experiment with a 25-km fiber spool. For these three configurations, we analyze the noise arising from uncommon fiber paths in the interferometric ensemble and design optimized interferometers. We demonstrate interferometers with very low temperature sensitivity of respectively -2.2, -0.03 and 1 fs/K. We use one of these optimized interferometers on a long haul compensated fiber link of 540km. We obtain a relative frequency stability of 3E-20 after 10,000 s of integration time.

physics.optics↗

arXiv2014

Quantum cascade laser frequency stabilisation at the sub-Hz level

Quantum Cascade Lasers (QCL) are increasingly being used to probe the mid-infrared "molecular fingerprint" region. This prompted efforts towards improving their spectral performance, in order to reach ever-higher resolution and precision. Here, we report the stabilisation of a QCL onto an optical frequency comb. We demonstrate a relative stability and accuracy of 2x10-15 and 10-14, respectively. The comb is stabilised to a remote near-infrared ultra-stable laser referenced to frequency primary standards, whose signal is transferred via an optical fibre link. The stability and frequency traceability of our QCL exceed those demonstrated so far by two orders of magnitude. As a demonstration of its capability, we then use it to perform high-resolution molecular spectroscopy. We measure absorption frequencies with an 8x10-13 relative uncertainty. This confirms the potential of this setup for ultra-high precision measurements with molecules, such as our ongoing effort towards testing the parity symmetry by probing chiral species.

physics.optics↗

arXiv2014

Two-Way Optical Frequency Comparisons Over 100km Telecommunication Network Fibers

By using two-way frequency transfer, we demonstrate ultra-high resolution comparison of optical frequencies over a telecommunication fiber link of 100 km operating simultaneously digital data transfer. We first propose and experiment a bi-directional scheme using a single fiber. We show that the relative stability at 1 s integration time is 7 10^18 and scales down to 5 10^21. The same level of performance is reached when an optical link is implemented with an active compensation of the fiber noise. We also implement a real-time two-way frequency comparison over a uni-directional telecommunication network using a pair of parallel fibers. The relative frequency stability is 10^15 at 1 s integration time and reaches 2 10^17 at 40 000 s. The fractional uncertainty of the frequency comparisons was evaluated for the best case to 2 10^20. These results open the way to accurate and high resolution frequency comparison of optical clocks over intercontinental fiber networks.

physics.optics↗

arXiv2014

A widely tunable 10-$μ$m quantum cascade laser phase-locked to a state-of-the-art mid-infrared reference for precision molecular spectroscopy

We report the coherent phase-locking of a quantum cascade laser (QCL) at 10-$μ$m to the secondary frequency standard of this spectral region, a CO2 laser stabilized on a saturated absorption line of OsO4. The stability and accuracy of the standard are transferred to the QCL resulting in a line width of the order of 10 Hz, and leading to our knowledge to the narrowest QCL to date. The locked QCL is then used to perform absorption spectroscopy spanning 6 GHz of NH3 and methyltrioxorhenium, two species of interest for applications in precision measurements.

physics.optics↗

arXiv2014

In-line extraction of an ultra-stable frequency signal over an optical fiber link

We demonstrate in-line extraction of an ultra-stable frequency signal over an optical link of 92-km of installed telecommunication fibers, following the proposition of G. Grosche in 2010. We show that the residual frequency noise at the extraction end is noticeably below that at the main link output when the extraction is near the input end, as expected from a simple model of the noise compensation. We obtain relative frequency instabilities, expressed as overlapping Allan deviation, of 8x10-16 at 1 s averaging time and a few 10-19 at 1 day. These results are at the state-of-the-art for a link using urban telecommunication fibers. We also propose an improved scheme which delivers an ultra-stable signal of higher power, in order to feed a secondary link. In-line extraction opens the way to a broad distribution of an ultra-stable frequency reference, enabling a wide range of applications beyond metrology.

physics.optics↗

arXiv2013

Probing weak force induced parity violation by high resolution mid-infrared molecular spectroscopy

To date no experiment has reached the level of sensitivity required to observe weak nuclear force induced parity violation (PV) energy differences in chiral molecules. In this paper, we present the approach, adopted at Laboratoire de Physique des Lasers (LPL), to measure frequency differences in the vibrational spectrum of enantiomers. We review different spectroscopic methods developed at LPL leading to the highest resolutions, as well as 20 years of CO2 laser stabilization work enabling such precise measurements. After a first attempt to observe PV vibrational frequency shifts using sub-Doppler saturated absorption spectroscopy in a cell, we are currently aiming at an experiment based on Doppler-free two-photon Ramsey interferometry on a supersonic beam. We report on our latest progress towards observing PV with chiral organo-metallic complexes containing a heavy rhenium atom.

physics.atom-ph↗