arXiv subjects

Anne Amy-Klein

Publications and source records attributed to Anne Amy-Klein.

At least 37 records · Page 2Linked to original sources

arXiv2013

Mid-infrared laser phase-locking to a remote near-infrared frequency reference for high precision molecular spectroscopy

We present a new method for accurate mid-infrared frequency measurements and stabilization to a near-infrared ultra-stable frequency reference, transmitted with a long-distance fibre link and continuously monitored against state-of-the-art atomic fountain clocks. As a first application, we measure the frequency of an OsO4 rovibrational molecular line around 10 $μ$m with a state-of-the-art uncertainty of 8x10-13. We also demonstrate the frequency stabilization of a mid-infrared laser with fractional stability better than 4x10-14 at 1 s averaging time and a line-width below 17 Hz. This new stabilization scheme gives us the ability to transfer frequency stability in the range of 10-15 or even better, currently accessible in the near-infrared or in the visible, to mid-infrared lasers in a wide frequency range.

physics.optics↗

arXiv2012

Mid-IR frequency measurement using an optical frequency comb and a long-distance remote frequency reference

We have built a frequency chain which enables to measure the absolute frequency of a laser emitting in the 28-31 THz frequency range and stabilized onto a molecular absorption line. The set-up uses an optical frequency comb and an ultrastable 1.55 $μ$m frequency reference signal, transferred from LNE-SYRTE to LPL through an optical link. We are now progressing towards the stabilization of the mid-IR laser via the frequency comb and the extension of this technique to quantum cascade lasers. Such a development is very challenging for ultrahigh resolution molecular spectroscopy and fundamental tests of physics with molecules.

physics.atom-ph↗

arXiv2012

Simultaneous remote transfer of accurate timing and optical frequency over a public fiber network

In this work we demonstrate for the first time that it is possible to transfer simultaneously an ultra-stable optical frequency and a precise and accurate timing over 540 km using a public telecommunication optical fiber networks with Internet data. The optical phase is used to carry both the frequency information and the timestamps by modulating a very narrow optical carrier at 1.55 $μ$m with spread spectrum signals using two-way satellite time transfer modems. The results in term of absolute time accuracy (250 ps) and long-term timing stability (20 ps) well outperform the conventional Global Navigation Satellite System or geostationary transfer methods.

physics.optics↗

arXiv2012

Ultra-stable long distance optical frequency distribution using the Internet fiber network

We report an optical link of 540 km for ultrastable frequency distribution over the Internet fiber network. The stable frequency optical signal is processed enabling uninterrupted propagation on both directions. The robustness and the performance of the link are enhanced by a cost effective fully automated optoelectronic station. This device is able to coherently regenerate the return optical signal with a heterodyne optical phase locking of a low noise laser diode. Moreover the incoming signal polarization variation are tracked and processed in order to maintain beat note amplitudes within the operation range. Stable fibered optical interferometer enables optical detection of the link round trip phase signal. The phase-noise compensated link shows a fractional frequency instability in 10 Hz bandwidth of 5x10-15 at one second measurement time and 2x10-19 at 30 000 s. This work is a significant step towards a sustainable wide area ultrastable optical frequency distribution and comparison network.

quant-ph↗

arXiv2010

High resolution spectroscopy of methyltrioxorhenium: towards the observation of parity violation in chiral molecules

Originating from the weak interaction, parity violation in chiral molecules has been considered as a possible origin of the biohomochirality. It was predicted in 1974 but has never been observed so far. Parity violation should lead to a very tiny frequency difference in the rovibrational spectra of the enantiomers of a chiral molecule. We have proposed to observe this predicted frequency difference using the two photon Ramsey fringes technique on a supersonic beam. Promising candidates for this experiment are chiral oxorhenium complexes, which present a large effect, can be synthesized in large quantity and enantiopure form, and can be seeded in a molecular beam. As a first step towards our objective, a detailed spectroscopic study of methyltrioxorhenium (MTO) has been undertaken. It is an ideal test molecule as the achiral parent molecule of chiral candidates for the parity violation experiment. For the 187Re MTO isotopologue, a combined analysis of Fourier transform microwave and infrared spectra as well as ultra-high resolution CO2 laser absorption spectra enabled the assignment of 28 rotational lines and 71 rovibrational lines, some of them with a resolved hyperfine structure. A set of spectroscopic parameters in the ground and first excited state, including hyperfine structure constants, was obtained for the antisymmetric Re=O stretching mode of this molecule. This result validates the experimental approach to be followed once a chiral derivative of MTO will be synthesized, and shows the benefit of the combination of several spectroscopic techniques in different spectral regions, with different set-ups and resolutions. First high resolution spectra of jet-cooled MTO, obtained on the set-up being developed for the observation of molecular parity violation, are shown, which constitutes a major step towards the targeted objective.

physics.atom-ph↗

arXiv2010

Cascaded multiplexed optical link on a telecommunication network for frequency dissemination

We demonstrate a cascaded optical link for ultrastable frequency dissemination comprised of two compensated links of 150 km and a repeater station. Each link includes 114 km of Internet fiber simultaneously carrying data traffic through a dense wavelength division multiplexing technology, and passes through two routing centers of the telecommunication network. The optical reference signal is inserted in and extracted from the communication network using bidirectional optical add-drop multiplexers. The repeater station operates autonomously ensuring noise compensation on the two links and the ultra-stable signal optical regeneration. The compensated link shows a fractional frequency instability of 3 \times 10-15 at one second measurement time and 5 \times 10-20 at 20 hours. This work paves the way to a wide dissemination of ultra-stable optical clock signals between distant laboratories via the Internet network.

quant-ph↗

arXiv2010

Progress toward a first observation of parity violation in chiral molecules by high-resolution laser spectroscopy

Parity violation (PV) effects in chiral molecules have so far never been experimentally observed. To take this challenge up, a consortium of physicists, chemists, theoreticians and spectroscopists has been established and aims at measuring PV energy differences between two enantiomers by using high-resolution laser spectroscopy. In this article, we present our common strategy to reach this goal, the progress accomplished in the diverse areas, and point out directions for future PV observations. The work of André Collet on bromochlorofluoromethane enantiomers, their synthesis and their chiral recognition by cryptophanes made feasible the first generation of experiments presented in this paper.

physics.atom-ph↗

arXiv2009

Determination of the Boltzmann constant by laser spectroscopy as a basis for future measurements of the thermodynamic temperature

In this paper, we present the latest results on the measurement of the Boltzmann constant kB, by laser spectroscopy of ammonia at 10 ?m. The Doppler absorption profile of a ro-vibrational line of an NH3 gas sample at thermal and pressure equilibrium is measured as accurately as possible. The absorption cell is placed inside a large 1m3 thermostat filled with an ice-water mixture, which sets the temperature very close to 273.15 K. Analysing this profile, which is related to the Maxwell-Boltzmann molecular speed distribution, leads to a determination of the Boltzmann constant via a measurement of the Doppler width (proportional tosqrt(kBT)). A spectroscopic determination of the Boltzmann constant with an uncertainty as low as 37 ppm is obtained. Recent improvements with a new passive thermostat lead to a temperature accuracy, stability and homogeneity of the absorption cell better than 1 ppm over a day.

physics.atom-ph↗

arXiv2009

Measurement of the Boltzmann constant by the Doppler broadening technique at a 3,8x10-5 accuracy level

In this paper, we describe an experiment performed at the Laboratoire de Physique des Lasers and dedicated to an optical measurement of the Boltzmann constant. With the proposed innovative technique, determining comes down to an ordinary frequency measurement. The method consists in measuring as accurately as possible the Doppler absorption profile of a rovibrational line of ammonia in thermal equilibrium. This profile is related to the Maxwell-Boltzmann molecular velocity distribution along the laser beam. A fit of the absorption line shape leads to a determination of the Doppler width proportional to sqrt(kT) and thus to a determination of the Boltzmann constant. The laser source is an ultra-stable CO2 laser with a wavelength . The absorption cell is placed in a thermostat keeping the temperature at 273.15 K within 1.4 mK. We were able to measure with a relative uncertainty as small as 3.8x10-5, which represents an improvement of an order of magnitude for an integration time comparable to our previous measurement published in 2007 [1]

physics.atom-ph↗

arXiv2009

High-resolution optical frequency dissemination on a telecommunication network with data traffic

We transferred the frequency of an ultra-stable laser over a 108 km urban fiber link comprising 22 km of optical communications network fiber simultaneously carrying Internet data traffic. The metrological signal and the digital data signal are transferred on two different frequency channels in a dense wavelength division multiplexing scheme. The metrological signal is inserted into and extracted from the communications network by using bidirectional off-the-shelf optical add-drop multiplexers. The link-induced phase noise is measured and cancelled with round-trip technique using an all-fiber-based interferometer. The compensated link shows an Allan deviation of a few 10-16 at one second and below 10-19 at 10,000 seconds. This opens the way to a wide dissemination of ultra stable optical clock signals between distant laboratories via the Internet network.

quant-ph↗

arXiv2008

Long-distance frequency transfer over an urban fiber link using optical phase stabilization

We transferred the frequency of an ultra-stable laser over 86 km of urban fiber. The link is composed of two cascaded 43-km fibers connecting two laboratories, LNE-SYRTE and LPL in Paris area. In an effort to realistically demonstrate a link of 172 km without using spooled fiber extensions, we implemented a recirculation loop to double the length of the urban fiber link. The link is fed with a 1542-nm cavity stabilized fiber laser having a sub-Hz linewidth. The fiber-induced phase noise is measured and cancelled with an all fiber-based interferometer using commercial off the shelf pigtailed telecommunication components. The compensated link shows an Allan deviation of a few 10-16 at one second and a few 10-19 at 10,000 seconds.

physics.ins-det↗

arXiv2008

86-km optical link with a resolution of 2.10-18 for RF frequency transfer

RF frequency transfer over an urban 86 km fibre has been demonstrated with a resolution of 2.10-18 at one day measuring time using an optical compensator. This result is obtained with a reference carrier frequency of 1 GHz, and a rapid scrambling of the polarisation state of the input light in order to reduce the sensitivity to the polarisation mode dispersion in the fibre. The limitation due to the fibre chromatic dispersion associated with the laser frequency fluctuations is highlighted and analyzed. A preliminary test of an extended compensated link over 186 km using optical amplifiers gives a resolution below 10-17 at 1 day.

quant-ph↗

arXiv2008

Stability of the proton-to-electron mass ratio

We report a limit on the fractional temporal variation of the proton-to-electron mass ratio as, obtained by comparing the frequency of a rovibrational transition in SF6 with the fundamental hyperfine transition in Cs. The SF6 transition was accessed using a CO2 laser to interrogate spatial 2-photon Ramsey fringes. The atomic transition was accessed using a primary standard controlled with a Cs fountain. This result is direct and model-free.

physics.atom-ph↗

arXiv2007

HCOOH high resolution spectroscopy in the 9.18$μ$m region

We report on higly accurate absolute frequency measurement against a femtosecond frequency comb of 6 saturated absorption lines of formic acid (HCOOH) with an accuracy of 1 kHz. We also report the frequency measurement of 17 other lines with an accuracy of 2 kHz. Those lines are in quasi coincidence with the 9R(36) to 9R(42) CO$_2$ laser emission lines and are probed either by a CO$_2$ or a widely tunable quantum cascade laser phase locked to a master CO$_2$ laser. The relative stability of two HCOOH stabilized lasers is characterized by a relative Allan deviation of 4.5 10$^{-12}$ $τ^{-1/2}$. They give suitable frequency references for H$_2^+$ Doppler free two-photon spectroscopy.

physics.atom-ph↗

arXiv2007

First direct determination of the Boltzmann constant by an optical method

We have recorded the Doppler profile of a well-isolated rovibrational line in the \nu2 band of 14NH3. Ammonia gas was placed in an absorption cell thermalized by a water-ice bath. By extrapolating to zero pressure, we have deduced the Doppler width which gives a first measurement of the Boltzmann constant, kB, by laser spectroscopy. A relative uncertainty of 2x10-4 has been obtained. The present determination should be significantly improved in the near future and contribute to a new definition of the kelvin.

quant-ph↗

arXiv2006

High Resolution Frequency Standard Dissemination via Optical Fibre Metropolitan Network

We present in this paper results on a new dissemination system of ultra-stable reference signal at 100 MHz on a standard fibre network. The 100 MHz signal is simply transferred by amplitude modulation of an optical carrier. Two different approaches for compensating the noise introduced by the link have been implemented. The limits of the two systems are analyzed and several solution suggested in order to improve the frequency stability and to further extend the distribution distance. Nevertheless, our system is a good tool for the best cold atom fountains comparison between laboratories, up to 100 km, with a relative frequency resolution of 10-14 at one second integration time and 10-17 for one day of measurement. The distribution system may be upgraded to fulfill the stringent distribution requirements for the future optical clocks.

physics.optics↗

arXiv2005

Absolute frequency measurement of an SF6 two-photon line using a femtosecond optical comb and sum-frequency generation

We demonstrate a new simple technique to measure IR frequencies near 30 THz using a femtosecond (fs) laser optical comb and sum-frequency generation. The optical frequency is directly compared to the distance between two modes of the fs laser, and the resulting beat note is used to control this distance which depends only on the repetition rate fr of the fs laser. The absolute frequency of a CO2 laser stabilized onto an SF6 two-photon line has been measured for the first time. This line is an attractive alternative to the usual saturated absorption OsO4 resonances used for the stabilization of CO2 lasers. First results demonstrate a fractional Allan deviation of 3.10-14 at 1 s.

quant-ph↗

arXiv2005

Long-distance frequency dissemination with a resolution of 10-17

We use a new technique to disseminate microwave reference signals along ordinary optical fiber. The fractional frequency resolution of a link of 86 km in length is 10-17 for a one day integration time, a resolution higher than the stability of the best microwave or optical clocks. We use the link to compare the microwave reference and a CO2/OsO4 frequency standard that stabilizes a femtosecond laser frequency comb. This demonstrates a resolution of 3.10-14 at 1 s. An upper value of the instability introduced by the femtosecond laser-based synthesizer is estimated as 1.10-14 at 1 s.

quant-ph↗