arXiv subjects

Arthur D. Bosman

Publications and source records attributed to Arthur D. Bosman.

At least 19 recordsLinked to original sources

arXiv2022

UV-driven Chemistry as a Signpost for Late-stage Planet Formation

The chemical reservoir within protoplanetary disks has a direct impact on planetary compositions and the potential for life. A long-lived carbon-and nitrogen-rich chemistry at cold temperatures (<=50K) is observed within cold and evolved planet-forming disks. This is evidenced by bright emission from small organic radicals in 1-10 Myr aged systems that would otherwise have frozen out onto grains within 1 Myr. We explain how the chemistry of a planet-forming disk evolves from a cosmic-ray/X-ray-dominated regime to an ultraviolet-dominated chemical equilibrium. This, in turn, will bring about a temporal transition in the chemical reservoir from which planets will accrete. This photochemical dominated gas phase chemistry develops as dust evolves via growth, settling and drift, and the small grain population is depleted from the disk atmosphere. A higher gas-to-dust mass ratio allows for deeper penetration of ultraviolet photons is coupled with a carbon-rich gas (C/O > 1) to form carbon-bearing radicals and ions. This further results in gas phase formation of organic molecules, which then would be accreted by any actively forming planets present in the evolved disk.

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arXiv2022

The kinematics and excitation of infrared water vapor emission from planet-forming disks: results from spectrally-resolved surveys and guidelines for JWST spectra

This work presents ground-based spectrally-resolved water emission at R = 30000-100000 over infrared wavelengths covered by JWST (2.9-12.8 $μ$m). Two new surveys with iSHELL and VISIR are combined with previous spectra from CRIRES and TEXES to cover parts of multiple ro-vibrational and rotational bands observable within telluric transmission bands, for a total of $\approx160$ spectra and 85 disks (30 of which are JWST targets in Cycle 1). The general expectation of a range of regions and excitation conditions traced by infrared water spectra is for the first time supported by the combined kinematics and excitation as spectrally resolved at multiple wavelengths. The main findings from this analysis are: 1) water lines are progressively narrower from the ro-vibrational bands at 2-9 $μ$m to the rotational lines at 12 $μ$m, and partly match a broad (BC) and narrow (NC) emission components, respectively, as extracted from ro-vibrational CO spectra; 2) rotation diagrams of resolved water lines from upper level energies of 4000-9500 K show vertical spread and curvatures indicative of optically thick emission ($\approx 10^{18}$ cm$^{-2}$) from a range of excitation temperatures ($\approx 800$-1100 K); 3) the new 5 $μ$m spectra demonstrate that slab model fits to the rotational lines at $> 10$ $μ$m strongly over-predict the ro-vibrational emission bands at $< 9$ $μ$m, implying non-LTE vibrational excitation. We discuss these findings in the context of emission from a disk surface and a molecular inner disk wind, and provide a list of guidelines to support the analysis of spectrally-unresolved JWST spectra.

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arXiv2022

Water shielding in the terrestrial planet-forming zone: Implication for inner disk organics

The chemical composition of the inner region of protoplanetary disks can trace the composition of planetary building material. The exact elemental composition of the inner disk has not yet been measured and tensions between models and observations still exist. Recent advancements have shown UV-shielding to be able to increase emission of organics. Here, we expand on these models and investigate how UV-shielding may impact chemical composition in the inner 5 au. In this work, we use the model from arxiv:2204.07108 and expand it with a larger chemical network. We focus on the chemical abundances in the upper disk atmosphere where the effects of water UV-shielding are most prominent and molecular lines originate. We find rich carbon and nitrogen chemistry with enhanced abundances of C2H2, CH4, HCN, CH3CN, and NH3 by > 3 orders of magnitude. This is caused by the self-shielding of H2O, which locks oxygen in water. This subsequently results in a suppression of oxygen-containing species like CO and CO2. The increase in C2H2 seen in the model with the inclusion of water UV-shielding allows us to explain the observed C2H2 abundance without resorting to elevated C/O ratios as water UV-shielding induced an effectively oxygen-poor environment in oxygen-rich gas. Thus, water UV-shielding is important for reproducing the observed abundances of hydrocarbons and nitriles. From our model result, species like CH4, NH3, and NO are expected to be observable with the James Webb Space Telescope (JWST).

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arXiv2022

Water UV-Shielding in the Terrestrial Planet-Forming Zone: Implications for Oxygen-18 Isotope Anomalies in H2-18O Infrared Emission and Meteorites

An understanding of the abundance and distribution of water vapor in the innermost region of protoplanetary disks is key to understanding the origin of habitable worlds and planetary systems. Past observations have shown H2O to be abundant and a major carrier of elemental oxygen in disk surface layers that lie within the inner few au of the disk. The combination of high abundance and strong radiative transitions leads to emission lines that are optically thick across the infrared spectral range. Its rarer isotopologue H2-18O traces deeper into this layer and will trace the full content of the planet forming zone. In this work, we explore the relative distribution of H2-16O and H2-18O within a model that includes water self-shielding from the destructive effects of ultraviolet radiation. In this Letter we show that there is an enhancement in the relative H2-18O abundance high up in the warm molecular layer within 0.1-10 au due to self-shielding of CO, C18O, and H2O. Most transitions of H2-18O that can be observed with JWST will partially emit from this layer, making it essential to take into account how H2O self-shielding may effect the H2O to H2-18O ratio. Additionally, this reservoir of H2-18O-enriched gas in combination with the vertical "cold finger" effect might provide a natural mechanism to account for oxygen isotopic anomalies found in meteoritic material in the solar system

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arXiv2022

Water UV-shielding in the terrestrial planet-forming zone: Implications for carbon dioxide emission

Carbon Dioxide is an important tracer of the chemistry and physics in the terrestrial planet forming zone. Using a thermo-chemical model that has been tested against the mid-infrared water emission we re-interpret the CO2 emission as observed with Spitzer. We find that both water UV-shielding and extra chemical heating significantly reduce the total CO2 column in the emitting layer. Water UV-shielding is the more efficient effect, reducing the CO2 column by $\sim$ 2 orders of magnitude. These lower CO2 abundances lead to CO2-to-H2O flux ratios that are closer to the observed values, but CO2 emission is still too bright, especially in relative terms. Invoking the depletion of elemental oxygen outside of the water mid-plane iceline more strongly impacts the CO2 emission than it does the H2O emission, bringing the CO2-to-H2O emission in line with the observed values. We conclude that the CO2 emission observed with Spitzer-IRS is coming from a thin layer in the photo-sphere of the disk, similar to the strong water lines. Below this layer, we expect CO2 not to be present except when replenished by a physical process. This would be visible in the $^{13}$CO2 spectrum as well as certain $^{12}$CO2 features that can be observed by JWST-MIRI.

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arXiv2022

Molecules with ALMA at Planet-forming Scales (MAPS) III: Characteristics of Radial Chemical Substructures

The Molecules with ALMA at Planet-forming Scales (MAPS) Large Program provides a detailed, high resolution (${\sim}$10-20 au) view of molecular line emission in five protoplanetary disks at spatial scales relevant for planet formation. Here, we present a systematic analysis of chemical substructures in 18 molecular lines toward the MAPS sources: IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. We identify more than 200 chemical substructures, which are found at nearly all radii where line emission is detected. A wide diversity of radial morphologies - including rings, gaps, and plateaus - is observed both within each disk and across the MAPS sample. This diversity in line emission profiles is also present in the innermost 50 au. Overall, this suggests that planets form in varied chemical environments both across disks and at different radii within the same disk. Interior to 150 au, the majority of chemical substructures across the MAPS disks are spatially coincident with substructures in the millimeter continuum, indicative of physical and chemical links between the disk midplane and warm, elevated molecular emission layers. Some chemical substructures in the inner disk and most chemical substructures exterior to 150 au cannot be directly linked to dust substructure, however, which indicates that there are also other causes of chemical substructures, such as snowlines, gradients in UV photon fluxes, ionization, and radially-varying elemental ratios. This implies that chemical substructures could be developed into powerful probes of different disk characteristics, in addition to influencing the environments within which planets assemble. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2022

Water UV-shielding in the terrestrial planet-forming zone: Implications from water emission

Mid-infrared spectroscopy is one of the few ways to observe the composition of the terrestial planet forming zone, the inner few au, of proto-planetary disks. The species currently detected in the disk atmosphere, for example CO, CO2, H2O and C2H2, are theoretically enough to constrain the C/O ratio in the disk surface. However, thermo-chemical models have difficulties in reproducing the full array of detected species in the mid-infrared simultaneously. In an effort to get closer to the observed spectra, we have included water UV-shielding as well as more efficient chemical heating into thermo-chemical code Dust And Lines. We find that both are required to match the observed emission spectrum. Efficient chemical heating, in addition to traditional heating from UV photons, is necessary to elevate the temperature of the water emitting layer to match the observed excitation temperature of water. We find that water UV-shielding stops UV photons from reaching deep into the disk, cooling down the lower layers with higher column. These two effects create a hot emitting layer of water with a column of 1-10$\times 10^{18}$ cm$^{-2}$. This is only 1-10% of the water column above the dust $τ=1$ surface at mid-infrared wavelengths in the models and represents <1% of the total water column.

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arXiv2022

Scanning disk rings and winds in CO at 0.01-10 au: a high-resolution $M$-band spectroscopy survey with IRTF-iSHELL

We present an overview and first results from a $M$-band spectroscopic survey of planet-forming disks performed with iSHELL on IRTF, using two slits that provide resolving power R $\approx$ 60,000-92,000 (5-3.3 km/s). iSHELL provides a nearly complete coverage at 4.52-5.24 $μ$m in one shot, covering $>50$ lines from the R and P branches of $^{12}$CO and $^{13}$CO for each of multiple vibrational levels, and providing unprecedented information on the excitation of multiple emission and absorption components. Some of the most notable new findings of this survey are: 1) the detection of two CO Keplerian rings at $<2$ au (in HD 259431), 2) the detection of H${_2}$O ro-vibrational lines at 5 $μ$m (in AS 205 N), and 3) the common kinematic variability of CO lines over timescales of 1-14 years. By homogeneously analyzing this survey together with a previous VLT-CRIRES survey of cooler stars, we discuss a unified view of CO spectra where emission and absorption components scan the disk surface across radii from a dust-free region within dust sublimation out to $\approx10$ au. We classify two fundamental types of CO line shapes interpreted as emission from Keplerian rings (double-peak lines) and a disk surface plus a low-velocity part of a wind (triangular lines), where CO excitation reflects different emitting regions (and their gas-to-dust ratio) rather than just the irradiation spectrum. A disk+wind interpretation for the triangular lines naturally explains several properties observed in CO spectra, including the line blue-shifts, line shapes that turn into narrow absorption at high inclinations, and the frequency of disk winds as a function of stellar type.

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arXiv2022

Chemical Feedbacks of Pebble Growth: Impacts on CO depletion and C/O ratios

Observations of protoplanetary disks have revealed them to be complex and dynamic, with vertical and radial transport of gas and dust occurring simultaneously with chemistry and planet formation. Previous models of protoplanetary disks focused primarily on chemical evolution of gas and dust in a static disk, or dynamical evolution of solids in a chemically passive disk. In this paper, we present a new 1D method for modelling pebble growth and chemistry simultaneously. Gas and small dust particles are allowed to diffuse vertically, connecting chemistry at all elevations of the disk. Pebbles are assumed to form from the dust present around the midplane, inheriting the composition of ices at this location. We present the results of this model after 1 Myr of disk evolution around a 1$M_\odot$ star at various locations both inside and outside of the CO snowline. We find that for a turbulent disk ($α= 10^{-3}$), CO is depleted from the surface layers of the disk by roughly 1-2 orders of magnitude, consistent with observations of protoplanetary disks. This is achieved by a combination of ice sequestration and decreasing UV opacity, both driven by pebble growth. Further, we find the selective removal of ice species via pebble growth and sequestration can increase gas phase C/O ratios to values of approximately unity. However, our model is unable to produce C/O values of $\sim$1.5-2.0 inferred from protoplanetary disk observations, implying selective sequestration of ice is not sufficient to explain C/O ratios $>1$.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS). X. Studying deuteration at high angular resolution toward protoplanetary disks

Deuterium fractionation is dependent on various physical and chemical parameters. Thus, the formation location and thermal history of material in the solar system is often studied by measuring its D/H ratio. This requires knowledge about the deuteration processes operating during the planet formation era. We aim to study these processes by radially resolving the DCN/HCN (at 0.3" resolution) and N$_2$D$^+$/N$_2$H$^+$ (0.3 to 0.9") column density ratios toward the five protoplanetary disks observed by the Molecules with ALMA at Planet-forming scales (MAPS) Large Program. DCN is detected in all five sources, with one newly reported detection. N$_2$D$^+$ is detected in four sources, two of which are newly reported detections. We derive column density profiles that allow us to study the spatial variation of the DCN/HCN and N$_2$D$^+$/N$_2$H$^+$ ratios at high resolution. DCN/HCN varies considerably for different parts of the disks, ranging from $10^{-3}$ to $10^{-1}$. In particular, the inner disk regions generally show significantly lower HCN deuteration compared with the outer disk. In addition, our analysis confirms that two deuterium fractionation channels are active, which can alter the D/H ratio within the pool of organic molecules. N$_2$D$^+$ is found in the cold outer regions beyond $\sim$50 au, with N$_2$D$^+$/N$_2$H$^+$ ranging between $10^{-2}$ and 1 across the disk sample. This is consistent with the theoretical expectation that N$_2$H$^+$ deuteration proceeds via the low-temperature channel only. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS) II: CLEAN Strategies for Synthesizing Images of Molecular Line Emission in Protoplanetary Disks

The Molecules with ALMA at Planet-forming Scales large program (MAPS LP) surveyed the chemical structures of five protoplanetary disks across more than 40 different spectral lines at high angular resolution (0.15" and 0.30" beams for Bands 6 and 3, respectively) and sensitivity (spanning 0.3 - 1.3 mJy/beam and 0.4 - 1.9 mJy/beam for Bands 6 and 3, respectively). In this article, we describe our multi-stage workflow -- built around the CASA tclean image deconvolution procedure -- that we used to generate the core data product of the MAPS LP: the position-position-velocity image cubes for each spectral line. Owing to the expansive nature of the survey, we encountered a range of imaging challenges; some are familiar to the sub-mm protoplanetary disk community, like the benefits of using an accurate CLEAN mask, and others less well-known, like the incorrect default flux scaling of the CLEAN residual map first described in Jorsater & van Moorsel 1995 (the "JvM effect"). We distill lessons learned into recommended workflows for synthesizing image cubes of molecular emission. In particular, we describe how to produce image cubes with accurate fluxes via the "JvM correction," a procedure that is generally applicable to any image synthesized via CLEAN deconvolution but is especially critical for low S/N emission. We further explain how we used visibility tapering to promote a common, fiducial beam size and contextualize the interpretation of signal to noise ratio when detecting molecular emission from protoplanetary disks. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS) XVII: Determining the 2D Thermal Structure of the HD 163296 Disk

Understanding the temperature structure of protoplanetary disks is key to interpreting observations, predicting the physical and chemical evolution of the disk, and modeling planet formation processes. In this study, we constrain the two-dimensional thermal structure of the disk around Herbig Ae star HD 163296. Using the thermo-chemical code RAC2D, we derive a thermal structure that reproduces spatially resolved ALMA observations (~0.12 arcsec (13 au) - 0.25 arcsec (26 au)) of CO J = 2-1, 13CO J = 1-0, 2-1, C18O J = 1-0, 2-1, and C17O J = 1-0, the HD J = 1-0 flux upper limit, the spectral energy distribution (SED), and continuum morphology. The final model incorporates both a radial depletion of CO motivated by a time scale shorter than typical CO gas-phase chemistry (0.01 Myr) and an enhanced temperature near the surface layer of the the inner disk (z/r <= 0.21). This model agrees with the majority of the empirically derived temperatures and observed emitting surfaces derived from the J = 2-1 CO observations. We find an upper limit for the disk mass of 0.35 Msun, using the upper limit of the HD J = 1-0 and J = 2-1 flux. With our final thermal structure, we explore the impact that gaps have on the temperature structure constrained by observations of the resolved gaps. Adding a large gap in the gas and small dust additionally increases gas temperature in the gap by only 5-10%. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS) V: CO gas distributions

Here we present high resolution (15-24 au) observations of CO isotopologue lines from the Molecules with ALMA on Planet-forming Scales (MAPS) ALMA Large Program. Our analysis employs $^{13}$CO and C$^{18}$O ($J$=2-1), (1-0), and C$^{17}$O (1-0) line observations of five protoplanetary disks. We retrieve CO gas density distributions, using three independent methods: (1) a thermo-chemical modeling framework based on the CO data, the broadband spectral energy distribution, and the mm-continuum emission; (2) an empirical temperature distribution based on optically thick CO lines; and (3) a direct fit to the C$^{17}$O hyperfine lines. Results from these methods generally show excellent agreement. The CO gas column density profiles of the five disks show significant variations in the absolute value and the radial shape. Assuming a gas-to-dust mass ratio of 100, all five disks have a global CO-to-H$_2$ abundance of 10-100 times lower than the ISM ratio. The CO gas distributions between 150-400 au match well with models of viscous disks, supporting the long-standing theory. CO gas gaps appear to be correlated with continuum gap locations, but some deep continuum gaps do not have corresponding CO gaps. The relative depths of CO and dust gaps are generally consistent with predictions of planet-disk interactions, but some CO gaps are 5-10 times shallower than predictions based on dust gaps. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS) XIV: Revealing disk substructures in multi-wavelength continuum emission

Constraining dust properties of planet-forming disks via high angular resolution observations is fundamental to understanding how solids are trapped in substructures and how dust growth may be favored or accelerated therein. We use ALMA dust continuum observations of the Molecules with ALMA at Planet-forming Scales (MAPS) disks and explore a large parameter space to constrain the radial distribution of solid mass and maximum grain size in each disk, including or excluding dust scattering. In the nonscattering model, the dust surface density and maximum grain size profiles decrease from the inner disks to the outer disks, with local maxima at the bright ring locations, as expected from dust trapping models. The inferred maximum grain sizes from the inner to outer disks decrease from ~1 cm to 1 mm. For IM Lup, HD 163296, and MWC 480 in the scattering model, two solutions are compatible with their observed inner disk emission: one solution corresponding to a maximum grain size of a few millimeters (similar to the nonscattering model), and the other corresponding to a few hundred micrometer sizes. Based on the estimated Toomre parameter, only IM Lup -- which shows a prominent spiral morphology in millimeter dust -- is found to be gravitationally unstable. The estimated maximum Stokes number in all the disks lies between 0.01 and 0.3, and the estimated turbulence parameters in the rings of AS 209 and HD 163296 are close to the threshold where dust growth is limited by turbulent fragmentation. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS XVIII): Kinematic Substructures in the Disks of HD 163296 and MWC 480

We explore the dynamical structure of the protoplanetary disks surrounding HD 163296 and MWC 480 as part of the Molecules with ALMA at Planet Forming Scales (MAPS) large program. Using the $J = 2-1$ transitions of $^{12}$CO, $^{13}$CO and C$^{18}$O imaged at spatial resolutions of $\sim 0.^{\prime \prime}15$ and with a channel spacing of $200$ ${\rm m\,s^{-1}}$, we find perturbations from Keplerian rotation in the projected velocity fields of both disks ($\lesssim\!5\%$ of the local Keplerian velocity), suggestive of large-scale (10s of au in size), coherent flows. By accounting for the azimuthal dependence on the projection of the velocity field, the velocity fields were decomposed into azimuthally averaged orthogonal components, $v_ϕ$, $v_r$ and $v_z$. Using the optically thick $^{12}$CO emission as a probe of the gas temperature, local variations of $\approx\! 3$ K ($\approx\! 5 \%$ relative changes) were observed and found to be associated with the kinematic substructures. The MWC 480 disk hosts a suite of tightly wound spiral arms. The spirals arms, in conjunction with the highly localized perturbations in the gas velocity structure (kinematic planetary signatures), indicate a giant planet, $\sim\! 1$ $M_{\rm Jup}$, at a radius of $\approx 245$ au. In the disk of HD 163296, the kinematic substructures were consistent with previous studies of Pinte et al. (2018a) and Teague et al. (2018a) advocating for multiple $\sim\! 1$ $M_{\rm Jup}$ planets embedded in the disk. These results demonstrate that molecular line observations that characterize the dynamical structure of disks can be used to search for the signatures of embedded planets. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS) IV: Emission Surfaces and Vertical Distribution of Molecules

The Molecules with ALMA at Planet-forming Scales (MAPS) Large Program provides a unique opportunity to study the vertical distribution of gas, chemistry, and temperature in the protoplanetary disks around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. By using the asymmetry of molecular line emission relative to the disk major axis, we infer the emission height ($z$) above the midplane as a function of radius ($r$). Using this method, we measure emitting surfaces for a suite of CO isotopologues, HCN, and C$_2$H. We find that $^{12}$CO emission traces the most elevated regions with $z/r > 0.3$, while emission from the less abundant $^{13}$CO and C$^{18}$O probes deeper into the disk at altitudes of $z/r \lesssim 0.2$. C$_2$H and HCN have lower opacities and SNRs, making surface fitting more difficult, and could only be reliably constrained in AS 209, HD 163296, and MWC 480, with $z/r \lesssim 0.1$, i.e., relatively close to the planet-forming midplanes. We determine peak brightness temperatures of the optically thick CO isotopologues and use these to trace 2D disk temperature structures. Several CO temperature profiles and emission surfaces show dips in temperature or vertical height, some of which are associated with gaps and rings in line and/or continuum emission. These substructures may be due to local changes in CO column density, gas surface density, or gas temperatures, and detailed thermo-chemical models are necessary to better constrain their origins and relate the chemical compositions of elevated disk layers with those of planet-forming material in disk midplanes. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS) XIII: HCO$^+$ and disk ionization structure

We observed HCO$^+$ $J=1-0$ and H$^{13}$CO$^+$ $J=1-0$ emission towards the five protoplanetary disks around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480 as part of the MAPS project. HCO$^+$ is detected and mapped at 0.3\arcsec\,resolution in all five disks, while H$^{13}$CO$^+$ is detected (SNR$>6 σ$) towards GM Aur and HD 163296 and tentatively detected (SNR$>3 σ$) towards the other disks by a matched filter analysis. Inside a radius of $R\sim 100$ au, the HCO$^+$ column density is flat or shows a central dip. At outer radii ($\gtrsim 100$ au), the HCO$^+$ column density decreases outwards, while the column density ratio of HCO$^+$/CO is mostly in the range of $\sim 10^{-5}-10^{-4}$. We derived the HCO$^+$ abundance in the warm CO-rich layer, where HCO$^+$ is expected to be the dominant molecular ion. At $R\gtrsim 100$ au, the HCO$^+$ abundance is $\sim 3 \times 10^{-11} - 3\times 10^{-10}$, which is consistent with a template disk model with X-ray ionization. At the smaller radii, the abundance decreases inwards, which indicates that the ionization degree is lower in denser gas, especially inside the CO snow line, where the CO-rich layer is in the midplane. Comparison of template disk models with the column densities of HCO$^+$, N$_2$H$^+$, and N$_2$D$^+$ indicates that the midplane ionization rate is $\gtrsim 10^{-18}$ s$^{-1}$ for the disks around IM Lup, AS 209, and HD 163296. We also find hints of an increased HCO$^+$ abundance around the location of dust continuum gaps in AS 209, HD 163296, and MWC 480. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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arXiv2021

Molecules with ALMA at Planet-forming Scales (MAPS) XII: Inferring the C/O and S/H ratios in Protoplanetary Disks with Sulfur Molecules

Sulfur-bearing molecules play an important role in prebiotic chemistry and planet habitability. They are also proposed probes of chemical ages, elemental C/O ratio, and grain chemistry processing. Commonly detected in diverse astrophysical objects, including the Solar System, their distribution and chemistry remain, however, largely unknown in planet-forming disks. We present CS ($2-1$) observations at $\sim0."3$ resolution performed within the ALMA-MAPS Large Program toward the five disks around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. CS is detected in all five disks, displaying a variety of radial intensity profiles and spatial distributions across the sample, including intriguing apparent azimuthal asymmetries. Transitions of C$_2$S and SO were also serendipitously covered but only upper limits are found. For MWC 480, we present complementary ALMA observations at $\sim0."5$, of CS, $^{13}$CS, C$^{34}$S, H$_2$CS, OCS, and SO$_2$. We find a column density ratio N(H$_{2}$CS)/N(CS)$\sim2/3$, suggesting that a substantial part of the sulfur reservoir in disks is in organic form (i.e., C$_x$H$_y$S$_z$). Using astrochemical disk modeling tuned to MWC 480, we demonstrate that $N$(CS)/$N$(SO) is a promising probe for the elemental C/O ratio. The comparison with the observations provides a super-solar C/O. We also find a depleted gas-phase S/H ratio, suggesting either that part of the sulfur reservoir is locked in solid phase or that it remains in an unidentified gas-phase reservoir. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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