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Arthur D. Bosman

Publications and source records attributed to Arthur D. Bosman.

At least 37 records · Page 2Linked to original sources

Molecules with ALMA at Planet-forming Scales (MAPS) I: Program Overview and Highlights

Planets form and obtain their compositions in dust and gas-rich disks around young stars, and the outcome of this process is intimately linked to the disk chemical properties. The distributions of molecules across disks regulate the elemental compositions of planets, including C/N/O/S ratios and metallicity (O/H and C/H), as well as access to water and prebiotically relevant organics. Emission from molecules also encodes information on disk ionization levels, temperature structures, kinematics, and gas surface densities, which are all key ingredients of disk evolution and planet formation models. The Molecules with ALMA at Planet-forming Scales (MAPS) ALMA Large Program was designed to expand our understanding of the chemistry of planet formation by exploring disk chemical structures down to 10 au scales. The MAPS program focuses on five disks - around IM Lup, GM Aur, AS 209, HD 163296, and MWC 480 - in which dust substructures are detected and planet formation appears to be ongoing. We observed these disks in 4 spectral setups, which together cover ~50 lines from over 20 different species. This paper introduces the ApJS MAPS Special Issue by presenting an overview of the program motivation, disk sample, observational details, and calibration strategy. We also highlight key results, including discoveries of links between dust, gas, and chemical sub-structures, large reservoirs of nitriles and other organics in the inner disk regions, and elevated C/O ratios across most disks. We discuss how this collection of results is reshaping our view of the chemistry of planet formation.

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Molecules with ALMA at Planet-forming Scales (MAPS). XV. Tracing protoplanetary disk structure within 20 au

Constraining the distribution of gas and dust in the inner 20 au of protoplanetary disks is difficult. At the same time, this region is thought to be responsible for most planet formation, especially around the water ice line at 3-10 au. Under the assumption that the gas is in a Keplerian disk, we use the exquisite sensitivity of the Molecules with ALMA at Planet-forming Scales (MAPS) ALMA large program to construct radial surface brightness profiles with a ~3 au effective resolution for the CO isotopologue J=2-1 lines using the line velocity profile. IM Lup reveals a central depression in 13CO and C18O that is ascribed to a pileup of ~500 $M_\oplus$ of dust in the inner 20 au, leading to a gas-to-dust ratio of around <10. This pileup is consistent with efficient drift of grains ($\gtrsim$ 100 $M_\oplus$ Myr$^{-1}$) and a local gas-to-dust ratio that suggests that the streaming instability could be active. The CO isotopologue emission in the GM Aur disk is consistent with a small (~15 au), strongly depleted gas cavity within the ~40 au dust cavity. The radial surface brightness profiles for both the AS 209 and HD 163296 disks show a local minimum and maximum in the C18O emission at the location of a known dust ring (~14 au) and gap (~10 au), respectively. This indicates that the dust ring has a low gas-to-dust ratio ($>$ 10) and that the dust gap is gas-rich enough to have optically thick C18O.

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Molecules with ALMA at Planet-forming Scales (MAPS). VII. Sub-stellar O/H and C/H and super-stellar C/O in planet feeding gas

The elemental composition of the gas and dust in a protoplanetary disk influences the compositions of the planets that form in it. We use the Molecules with ALMA at Planet-forming Scales (MAPS) data to constrain the elemental composition of the gas at the locations of potentially forming planets. The elemental abundances are inferred by comparing source-specific gas-grain thermochemical models, with variable C/O ratios and small-grain abundances, from the DALI code with CO and C2H column densities derived from the high-resolution observations of the disks of AS 209, HD 163296, and MWC 480. Elevated C/O ratios (~2.0), even within the CO ice line, are necessary to match the inferred C2H column densities, over most of the pebble disk. Combined with constraints on the CO abundances in these systems, this implies that both the O/H and C/H ratios in the gas are substellar by a factor of 4-10, with the O/H depleted by a factor of 20-50, resulting in the high C/O ratios. This necessitates that even within the CO ice line, most of the volatile carbon and oxygen is still trapped on grains in the midplane. Planets accreting gas in the gaps of the AS 209, HD 163296, and MWC 480 disks will thus acquire very little carbon and oxygen after reaching the pebble isolation mass. In the absence of atmosphere-enriching events, these planets would thus have a strongly substellar O/H and C/H and superstellar C/O atmospheric composition.

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Molecules with ALMA at Planet-forming Scales (MAPS) XI: CN and HCN as Tracers of Photochemistry in Disks

UV photochemistry in the surface layers of protoplanetary disks dramatically alters their composition relative to previous stages of star formation. The abundance ratio CN/HCN has long been proposed to trace the UV field in various astrophysical objects, however to date the relationship between CN, HCN, and the UV field in disks remains ambiguous. As part of the ALMA Large Program MAPS (Molecules with ALMA at Planet-forming Scales), we present observations of CN N=1-0 transitions at 0.3'' resolution towards five disk systems. All disks show bright CN emission within $\sim$50-150 au, along with a diffuse emission shelf extending up to 600 au. In all sources we find that the CN/HCN column density ratio increases with disk radius from about unity to 100, likely tracing increased UV penetration that enhances selective HCN photodissociation in the outer disk. Additionally, multiple millimeter dust gaps and rings coincide with peaks and troughs, respectively, in the CN/HCN ratio, implying that some millimeter substructures are accompanied by changes to the UV penetration in more elevated disk layers. That the CN/HCN ratio is generally high (>1) points to a robust photochemistry shaping disk chemical compositions, and also means that CN is the dominant carrier of the prebiotically interesting nitrile group at most disk radii. We also find that the local column densities of CN and HCN are positively correlated despite emitting from vertically stratified disk regions, indicating that different disk layers are chemically linked. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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Molecules with ALMA at Planet-forming Scales (MAPS) XIX. Spiral Arms, a Tail, and Diffuse Structures Traced by CO around the GM Aur Disk

The concentric gaps and rings commonly observed in protoplanetary disks in millimeter continuum emission have lent the impression that planet formation generally proceeds within orderly, isolated systems. While deep observations of spatially resolved molecular emission have been comparatively limited, they are increasingly suggesting that some disks interact with their surroundings while planet formation is underway. We present an analysis of complex features identified around GM Aur in $^{12}$CO $J=2-1$ images at a spatial resolution of $\sim40$ au. In addition to a Keplerian disk extending to a radius of $\sim550$ au, the CO emission traces flocculent spiral arms out to radii of $\sim$1200 au, a tail extending $\sim1800$ au southwest of GM Aur, and diffuse structures extending from the north side of the disk up to radii of $\sim1900$ au. The diffuse structures coincide with a "dust ribbon" previously identified in scattered light. The large-scale asymmetric gas features present a striking contrast with the mostly axisymmetric, multi-ringed millimeter continuum tracing the pebble disk. We hypothesize that GM Aur's complex gas structures result from late infall of remnant envelope or cloud material onto the disk. The morphological similarities to the SU Aur and AB Aur systems, which are also located in the L1517 cloud, provide additional support to a scenario in which interactions with the environment are playing a role in regulating the distribution and transport of material in all three of these Class II disk systems. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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Molecules with ALMA at Planet-forming Scales (MAPS). IX. Distribution and Properties of the Large Organic Molecules HC$_3$N, CH$_3$CN, and $c$-C$_3$H$_2$

The precursors to larger, biologically-relevant molecules are detected throughout interstellar space, but determining the presence and properties of these molecules during planet formation requires observations of protoplanetary disks at high angular resolution and sensitivity. Here we present 0.3" observations of HC$_3$N, CH$_3$CN, and $c$-C$_3$H$_2$ in five protoplanetary disks observed as part of the Molecules with ALMA at Planet-forming Scales (MAPS) Large Program. We robustly detect all molecules in four of the disks (GM Aur, AS 209, HD 163296 and MWC 480) with tentative detections of $c$-C$_3$H$_2$ and CH$_3$CN in IM Lup. We observe a range of morphologies -- central peaks, single or double rings -- with no clear correlation in morphology between molecule nor disk. Emission is generally compact and on scales comparable with the millimetre dust continuum. We perform both disk-integrated and radially-resolved rotational diagram analysis to derive column densities and rotational temperatures. The latter reveals 5-10 times more column density in the inner 50-100 au of the disks when compared with the disk-integrated analysis. We demonstrate that CH$_3$CN originates from lower relative heights in the disks when compared with HC$_3$N, in some cases directly tracing the disk midplane. Finally, we find good agreement between the ratio of small to large nitriles in the outer disks and comets. Our results indicate that the protoplanetary disks studied here are host to significant reservoirs of large organic molecules, and that this planet- and comet-building material can be chemically similar to that in our own Solar System. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement Series.

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Molecules with ALMA at Planet-forming Scales (MAPS) XVI: Characterizing the impact of the molecular wind on the evolution of the HD 163296 system

During the main phase of evolution of a protoplanetary disk, accretion regulates the inner-disk properties, such as the temperature and mass distribution, and in turn, the physical conditions associated with planet formation. The driving mechanism behind accretion remains uncertain; however, one promising mechanism is the removal of a fraction of angular momentum via a magnetohydrodynamic (MHD) disk wind launched from the inner tens of astronomical units of the disk. This paper utilizes CO isotopologue emission to study the unique molecular outflow originating from the HD 163296 protoplanetary disk obtained with the Atacama Large Millimeter/submillimeter Array. HD~163296 is one of the most well-studied Class II disks and is proposed to host multiple gas-giant planets. We robustly detect the large-scale rotating outflow in the 12CO J=2-1 and the 13CO J=2-1 and J=1-0 transitions. We constrain the kinematics, the excitation temperature of the molecular gas, and the mass-loss rate. The high ratio of the rates of ejection to accretion (5 - 50), together with the rotation signatures of the flow, provides solid evidence for an MHD disk wind. We find that the angular momentum removal by the wind is sufficient to drive accretion through the inner region of the disk; therefore, accretion driven by turbulent viscosity is not required to explain HD~163296's accretion. The low temperature of the molecular wind and its overall kinematics suggest that the MHD disk wind could be perturbed and shocked by the previously observed high-velocity atomic jet. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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Molecules with ALMA at Planet-forming Scales (MAPS) VI: Distribution of the small organics HCN, C2H, and H2CO

Small organic molecules, such as C2H, HCN, and H2CO, are tracers of the C, N, and O budget in protoplanetary disks. We present high angular resolution (10-50 au) observations of C2H, HCN, and H2CO lines in five protoplanetary disks from the Molecules with ALMA at Planet-forming Scales (MAPS) ALMA Large Program. We derive column density and excitation temperature profiles for HCN and C2H, and find that the HCN emission arises in a temperate (20-30 K) layer in the disk, while C2H is present in relatively warmer (20-60 K) layers. In the case of HD 163296, we find a decrease in column density for HCN and C2H inside one of the dust gaps near 83 au, where a planet has been proposed to be located. We derive H2CO column density profiles assuming temperatures between 20 and 50 K, and find slightly higher column densities in the colder disks around T Tauri stars than around Herbig Ae stars. The H2CO column densities rise near the location of the CO snowline and/or millimeter dust edge, suggesting an efficient release of H2CO ices in the outer disk. Finally, we find that the inner 50 au of these disks are rich in organic species, with abundances relative to water that are similar to cometary values. Comets could therefore deliver water and key organics to future planets in these disks, similar to what might have happened here on Earth. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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Molecules with ALMA at Planet-forming Scales. XX. The Massive Disk Around GM Aurigae

Gas mass remains one of the most difficult protoplanetary disk properties to constrain. With much of the protoplanetary disk too cold for the main gas constituent, H2, to emit, alternative tracers such as dust, CO, or the H2 isotopolog HD are used. However, relying on disk mass measurements from any single tracer requires assumptions about the tracer's abundance relative to \hh\ and the disk temperature structure. Using new Atacama Large Millimeter/submillimeter Array (ALMA) observations from the Molecules with ALMA at Planet-forming Scales (MAPS) ALMA Large Program as well as archival ALMA observations, we construct a disk physical/chemical model of the protoplanetary disk GM Aur. Our model is in good agreement with the spatially resolved CO isotopolog emission from eleven rotational transitions with spatial resolution ranging from 0.15'' to 0.46'' (24-73 au at 159 pc) and the spatially unresolved HD J=1-0 detection from Herschel. Our best-fit model favors a cold protoplanetary disk with a total gas mass of approximately 0.2 solar masses, a factor of 10 reduction in CO gas inside roughly 100 au and a factor of 100 reduction outside of 100 au. Despite its large mass, the disk appears to be on the whole gravitationally stable based on the derived Toomre Q parameter. However, the region between 70 and 100 au, corresponding to one of the millimeter dust rings, is close to being unstable based on the calculated Toomre Q of <1.7. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

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Reimagining the water snowline

Water is a molecule that is tightly related to many facets of star and planet formation. Water's abundance and distribution, especially the location of it's snowline has thus been the subject of much study. While water is seen to be abundant in the inner region of proto-planetary disks in infrared spectroscopy, detections of water in the disk in the sub-millimeter are rare, with only one detection towards AS 205. Here we put the multitude of non-detections and the single detection into context of recent physico-chemical models. We find that the 321.2257 GHz (10(2,9) - 9(3,6)) line detection towards AS 205 is inconsistent with a normal inner disk temperature structure and that the observed line must be masing. Furthermore, the emitting area derived from the line width, together with published analyses on water in disks around T-Tauri stars implies that the water snowline in the disk surface is at the same location as the snowline in the mid-plane. We propose that this is caused by vertical mixing continuously sequestering water from the warm surface layers into the cold disk midplane.

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X-ray induced chemistry of water and related molecules in low-mass protostellar envelopes

Recent water line observations toward several low-mass protostars suggest low water gas fractional abundances in the inner warm envelopes. Water destruction by X-rays has been proposed to influence the water abundances in these regions, but the detailed chemistry, including the nature of alternative oxygen carriers, is not yet understood. In this study, we aim to understand the impact of X-rays on the composition of low-mass protostellar envelopes, focusing specifically on water and related oxygen bearing species. We compute the chemical composition of two low-mass protostellar envelopes using a 1D gas-grain chemical reaction network, under various X-ray field strengths. According to our calculations, outside the water snowline, the water gas abundance increases with $L_{\mathrm{X}}$. Inside the water snowline, water maintains a high abundance of $\sim 10^{-4}$ for small $L_{\mathrm{X}}$, with water and CO being the dominant oxygen carriers. For large $L_{\mathrm{X}}$, the water gas abundances significantly decrease just inside the water snowline (down to $\sim10^{-8}-10^{-7}$) and in the innermost regions ($\sim10^{-6}$). For these cases, the O$_{2}$ and O gas abundances reach $\sim 10^{-4}$ within the water snowline, and they become the dominant oxygen carriers. The HCO$^{+}$ and CH$_{3}$OH abundances, which have been used as tracers of the water snowline, significantly increase/decrease within the water snowline, respectively, as the X-ray fluxes become larger. The abundances of some other dominant molecules, such as CO$_{2}$, OH, CH$_{4}$, HCN, and NH$_{3}$, are also affected by strong X-ray fields, especially within their own snowlines. These X-ray effects are larger in lower density envelope models. Future observations of water and related molecules (using e.g., ALMA and ngVLA) will access the regions around protostars where such X-ray induced chemistry is effective.

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CO isotopolog line fluxes of viscously evolving disks: cold CO conversion insufficient to explain observed low fluxes

Protoplanetary disks are thought to evolve viscously, where the disk mass - the reservoir available for planet formation - decreases over time as material is accreted onto the central star. Observations show a correlation between dust mass and the stellar accretion rate, as expected from viscous theory. However, the gas mass inferred from 13CO and C18O line fluxes, which should be a more direct measure, shows no such correlation. Using thermochemical DALI models, we investigate how 13CO and C18O J=3-2 line fluxes change over time in a viscously evolving disk. We also investigate if the chemical conversion of CO through grain-surface chemistry combined with viscous evolution can explain the observations of disks in Lupus. The 13CO and C18O 3-2 line fluxes increase over time due to their optically thick emitting regions growing in size as the disk expands viscously. The C18O 3-2 emission is optically thin throughout the disk for only a subset of our models (Mdisk (t = 1 Myr) < 1e-3 Msun). For these disks the integrated C18O flux decreases with time, similar to the disk mass. The C18O 3-2 fluxes for the bulk of the disks in Lupus (with Mdust < 5e-5 Msun) can be reproduced to within a factor of ~2 with viscously evolving disks in which CO is converted into other species through grain-surface chemistry driven by a cosmic-ray ionization rate zeta_cr ~ 5e-17 - 1e-16 s^-1. However, explaining the stacked C18O upper limits requires a lower average abundance than our models can produce and they cannot explain the observed 13CO fluxes, which, for most disks, are more than an order of magnitude fainter than what our models predict. Reconciling the 13CO fluxes of viscously evolving disks with the observations requires either a combination of efficient vertical mixing and a high zeta_cr or low mass disks (Mdust < 3e-5 Msun) being much thinner and/or smaller than their more massive counterparts.

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Exploring HNC and HCN line emission as probes of the protoplanetary disk temperature

The distributions and abundances of molecules in protoplanetary disks are powerful tracers of the physical and chemical disk structures. The abundance ratios of HCN and its isomer HNC are known to be sensitive to gas temperature. Their line ratios might therefore offer a unique opportunity to probe the properties of the emitting gas. Using the 2D thermochemical code DALI, we ran a set of disk models accounting for different stellar and disk properties, with an updated chemical network for the nitrogen chemistry. These modeling results were then compared with observations, including new ALMA observations of HNC $J=3-2$ for the TW Hya disk and HNC $J=1-0$ for 29 disks in Lupus. Similar to CN, HCN and HNC have brighter line emission in models with larger disk flaring angles and higher UV fluxes. HNC and HCN are predicted to be abundant in the warm surface layer and outer midplane region, which results in ring-shaped emission patterns. However, the precise emitting regions and emission morphology depend on the probed transition, as well as on other parameters such as C and O abundances. The modeled HNC-to-HCN line intensity ratio increases from $<0.1$ in the inner disk to up to 0.8 in the outer disk regions, which can be explained by efficient HNC destruction at high temperatures. Disk-integrated HNC line fluxes from current scarce observations and its radial distribution in the TW Hya disk are broadly consistent with our model predictions. The HNC-to-HCN flux ratio robustly increases with radius (decreasing temperature), but its use as a chemical thermometer in disks is affected by other factors, including UV flux and C and O abundances. High-spatial resolution ALMA disk observations of HNC and HCN that can locate the emitting layers would have the great potential to constrain both the disk thermal and UV radiation structures, and also to verify our understanding of the nitrogen chemistry.

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Destruction of refractory carbon grains drives the final stage of proto-planetary disk chemistry

Here we aim to explore the origin of the strong C2H lines to reimagine the chemistry of protoplanetary disks. There are a few key aspects that drive our analysis. First, C2H is detected in young and old systems, hinting at a long-lived chemistry. Second, as a radical, C2H is rapidly destroyed, within <1000 yr. These two statements hint that the chemistry responsible for C2H emission must be predominantly in the gas-phase and must be in equilibrium. Combining new and published chemical models we find that elevating the total volatile (gas and ice) C/O ratio is the only natural way to create a long lived, high C2H abundance. Most of the \ce{C2H} resides in gas with a Fuv/n-gas ~ 10^-7 G0 cm^3. To elevate the volatile C/O ratio, additional carbon has to be released into the gas to enable an equilibrium chemistry under oxygen-poor conditions. Photo-ablation of carbon-rich grains seems the most straightforward way to elevate the C/O ratio above 1.5, powering a long-lived equilibrium cycle. The regions at which the conditions are optimal for the presence of high C/O ratio and elevated C2H abundances in the gas disk set by the Fuv/n-gas ~ 10^-7 G0 cm^3 condition lie just outside the pebble disk as well as possibly in disk gaps. This process can thus also explain the (hints of) structure seen in C2H observations.

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Hints for icy pebble migration feeding an oxygen-rich chemistry in the inner planet-forming region of disks

We present a synergic study of protoplanetary disks to investigate links between inner disk gas molecules and the large-scale migration of solid pebbles. The sample includes 63 disks where two types of measurements are available: i) spatially-resolved disk images revealing the radial distribution of disk pebbles (mm-cm dust grains), from millimeter observations with ALMA or the SMA, and ii) infrared molecular emission spectra as observed with Spitzer. The line flux ratios of H2O with HCN, C2H2, and CO2 all anti-correlate with the dust disk radius R$_{dust}$, expanding previous results found by Najita et al. (2013) for HCN/H2O and the dust disk mass. By normalization with the dependence on accretion luminosity common to all molecules, only the H2O luminosity maintains a detectable anti-correlation with disk radius, suggesting that the strongest underlying relation is between H2O and R$_{dust}$. If R$_{dust}$ is set by large-scale pebble drift, and if molecular luminosities trace the elemental budgets of inner disk warm gas, these results can be naturally explained with scenarios where the inner disk chemistry is fed by sublimation of oxygen-rich icy pebbles migrating inward from the outer disk. Anti-correlations are also detected between all molecular luminosities and the infrared index n$_{13-30}$, which is sensitive to the presence and size of an inner disk dust cavity. Overall, these relations suggest a physical interconnection between dust and gas evolution both locally and across disk scales. We discuss fundamental predictions to test this interpretation and study the interplay between pebble drift, inner disk depletion, and the chemistry of planet-forming material.

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Temperature structures of embedded disks: young disks in Taurus are warm

The chemical composition of gas and ice in disks around young stars set the bulk composition of planets. In contrast to protoplanetary disks (Class II), young disks that are still embedded in their natal envelope (Class 0 and I) are predicted to be too warm for CO to freeze out, as has been confirmed observationally for L1527 IRS. To establish whether young disks are generally warmer than their more evolved counterparts, we observed five young (Class 0/I and Class I) disks in Taurus with the Atacama Large Millimeter/submillimeter Array (ALMA), targeting C$^{17}$O $2-1$, H$_2$CO $3_{1,2}-2_{1,1}$, HDO $3_{1,2}-2_{2,1}$ and CH$_3$OH $5_K-4_K$ transitions at $0.48^{\prime\prime} \times 0.31^{\prime\prime}$ resolution. The different freeze-out temperatures of these species allow us to derive a global temperature structure. C$^{17}$O and H$_2$CO are detected in all disks, with no signs of CO freeze-out in the inner $\sim$100 au, and a CO abundance close to $\sim$10$^{-4}$. H$_2$CO emission originates in the surface layers of the two edge-on disks, as witnessed by the especially beautiful V-shaped emission pattern in IRAS~04302+2247. HDO and CH$_3$OH are not detected, with column density upper limits more than 100 times lower than for hot cores. Young disks are thus found to be warmer than more evolved protoplanetary disks around solar analogues, with no CO freeze-out (or only in the outermost part of $\gtrsim$100 au disks) or CO processing. However, they are not as warm as hot cores or disks around outbursting sources, and therefore do not have a large gas-phase reservoir of complex molecules.

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CO Depletion in Protoplanetary Disks: A Unified Picture Combining Physical Sequestration and Chemical Processing

The gas-phase CO abundance (relative to hydrogen) in protoplanetary disks decreases by up to 2 orders of magnitude from its ISM value ${\sim}10^{-4}$, even after accounting for freeze-out and photo-dissociation. Previous studies have shown that while local chemical processing of CO and the sequestration of CO ice on solids in the midplane can both contribute, neither of these processes appears capable of consistently reaching the observed depletion factors on the relevant timescale of $1{-}3\mathrm{~Myr}$. In this study, we model these processes simultaneously by including a compact chemical network (centered on carbon and oxygen) to 2D ($r+z$) simulations of the outer ($r>20\mathrm{~au}$) disk regions that include turbulent diffusion, pebble formation, and pebble dynamics. In general, we find that the CO/H$_2$ abundance is a complex function of time and location. Focusing on CO in the warm molecular layer, we find that only the most complete model (with chemistry and pebble evolution included) can reach depletion factors consistent with observations. In the absence of pressure traps, highly-efficient planetesimal formation, or high cosmic ray ionization rates, this model also predicts a resurgence of CO vapor interior to the CO snowline. We show the impact of physical and chemical processes on the elemental (C/O) and (C/H) ratios (in the gas and ice phases), discuss the use of CO as a disk mass tracer, and, finally, connect our predicted pebble ice compositions to those of pristine planetesimals as found in the Cold Classical Kuiper Belt and debris disks.

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Excess C/H in Protoplanetary Disk Gas from Icy Pebble Drift across the CO Snowline

The atmospheric composition of giant planets carries the information of their formation history. Superstellar C/H ratios are seen in atmospheres of Jupiter, Saturn, and various giant exoplanets. Also, giant exoplanets show a wide range of C/O ratio. To explain these ratios, one hypothesis is that protoplanets accrete carbon-enriched gas when a large number of icy pebbles drift across the CO snowline. Here we report the first direct evidence of an elevated C/H ratio in disk gas. We use two thermo-chemical codes to model the $^{13}$C$^{18}$O, C$^{17}$O, and C$^{18}$O (2-1) line spectra of the HD 163296 disk. We show that the gas inside the CO snowline ($\sim$70 au) has a C/H ratio of 1-2 times higher than the stellar value. This ratio exceeds the expected value substantially, as only 25-60% of the carbon should be in gas at these radii. Although we cannot rule out the case of a normal C/H ratio inside 70 au, the most probable solution is an elevated C/H ratio of 2-8 times higher than the expectation. Our model also shows that the gas outside 70 au has a C/H ratio of 0.1$\times$ the stellar value. This picture of enriched C/H gas at the inner region and depleted gas at the outer region is consistent with numerical simulations of icy pebble growth and drift in protoplanetary disks. Our results demonstrate that the large-scale drift of icy pebble can occur in disks and may significantly change the disk gas composition for planet formation.

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