arXiv subjects

Arzhang Ardavan

Publications and source records attributed to Arzhang Ardavan.

At least 55 records · Page 3Linked to original sources

arXiv2008

Solid state quantum memory using the 31P nuclear spin

The transfer of information between different physical forms is a central theme in communication and computation, for example between processing entities and memory. Nowhere is this more crucial than in quantum computation, where great effort must be taken to protect the integrity of a fragile quantum bit. Nuclear spins are known to benefit from long coherence times compared to electron spins, but are slow to manipulate and suffer from weak thermal polarisation. A powerful model for quantum computation is thus one in which electron spins are used for processing and readout while nuclear spins are used for storage. Here we demonstrate the coherent transfer of a superposition state in an electron spin 'processing' qubit to a nuclear spin 'memory' qubit, using a combination of microwave and radiofrequency pulses applied to 31P donors in an isotopically pure 28Si crystal. The electron spin state can be stored in the nuclear spin on a timescale that is long compared with the electron decoherence time and then coherently transferred back to the electron spin, thus demonstrating the 31P nuclear spin as a solid-state quantum memory. The overall store/readout fidelity is about 90%, attributed to systematic imperfections in radiofrequency pulses which can be improved through the use of composite pulses. We apply dynamic decoupling to protect the nuclear spin quantum memory element from sources of decoherence. The coherence lifetime of the quantum memory element is found to exceed one second at 5.5K.

quant-ph↗

arXiv2008

Response to "Comment on `Method of handling the divergences in the radiation theory of sources that move faster than their own waves'" [J. Math. Phys. 40, 4331 (1999)]

There is a fundamental difference between the classical expression for the retarded electromagnetic potential and the corresponding retarded solution of the wave equation that governs the electromagnetic field. While the boundary contribution to the retarded solution for the potential can always be rendered equal to zero by means of a gauge transformation that preserves the Lorenz condition, the boundary contribution to the retarded solution of the wave equation governing the field may be neglected only if it diminishes with distance faster than the contribution of the source density in the far zone. In the case of a source whose distribution pattern rotates superluminally (i.e., faster than the speed of light in vacuo), the boundary term in the retarded solution governing the field is by a factor of the order of R^(1/2) larger than the source term of this solution in the limit where the distance R of the boundary from the source tends to infinity. This result is consistent with the prediction of the retarded potential that the radiation field generated by a rotating superluminal source decays as 1/R^(1/2), instead of 1/R. It also explains why an argument based on the solution of the wave equation governing the field in which the boundary term is neglected, such as Hannay presents in his Comment, misses the nonspherical decay of the field.

math-ph↗

arXiv2008

Morphology of the nonspherically decaying radiation generated by a rotating superluminal source: reply to comment

The fact that the formula used by Hannay in his Comment is "from a standard text on electrodynamics" neither warrants that it is universally applicable, nor that it is unequivocally correct. We have explicitly shown [J. Opt. Soc. Am. A 25, 543 (2008)] that,since it does not include the boundary contribution toward the value of the field, the formula in question is not applicable when the source is extended and has a distribution pattern that rotates faster than light in vacuo. The neglected boundary term in the retarded solution to the wave equation governing the electromagnetic field forms the basis of diffraction theory. If this term were identically zero, for the reasons given by Hannay, the iffraction of electromagnetic waves through apertures on a surface enclosing a source would have been impossible. If this term were identically zero, for the reasons given by Hannay, the diffraction of electromagnetic waves through apertures on a surface enclosing a source would have been impossible.

physics.optics↗

arXiv2008

Switchable ErSc2N rotor within a C80 fullerene cage: An EPR and photoluminescence excitation study

Systems exhibiting both spin and orbital degrees of freedom, of which Er3+ is one, can offer mechanisms for manipulating and measuring spin states via optical excitations. Motivated by the possibility of observing photoluminescence and electron paramagnetic resonance from the same species located within a fullerene molecule, we initiated an EPR study of Er3+ in ErSc2N@C80. Two orientations of the ErSc2N rotor within the C80 fullerene are observed in EPR, consistent with earlier studies using photoluminescence excitation (PLE) spectroscopy. For some crystal field orientations, electron spin relaxation is driven by an Orbach process via the first excited electronic state of the 4I_15/2 multiplet. We observe a change in the relative populations of the two ErSc2N configurations upon the application of 532 nm illuminations, and are thus able to switch the majority cage symmetry. This photoisomerisation, observable by both EPR and PLE, is metastable, lasting many hours at 20 K.

cond-mat.mtrl-sci↗

arXiv2007

Spectral properties of the nonspherically decaying radiation generated by a rotating superluminal source

The focusing of the radiation generated by a polarization current with a superluminally rotating distribution pattern is of a higher order in the plane of rotation than in other directions. Consequently, our previously published asymptotic approximation to the value of this field outside the equatorial plane breaks down as the line of sight approaches a direction normal to the rotation axis, i.e., is nonuniform with respect to the polar angle. Here we employ an alternative asymptotic expansion to show that, though having a rate of decay with frequency (mu) that is by a factor of order mu^(2/3) slower, the equatorial radiation field has the same dependence on distance as the nonspherically decaying component of the generated field in other directions: it, too, diminishes as the inverse square root of the distance from its source. We also briefly discuss the relevance of these results to the giant pulses received from pulsars: the focused, nonspherically decaying pulses that arise from a superluminal polarization current in a highly magnetized plasma have a power-law spectrum (i.e., a flux density proportional to mu^alpha) whose index (alpha) is given by one of the values -2/3, -2, -8/3, or -4.

astro-ph↗

arXiv2007

The fundamental role of the retarded potential in the electrodynamics of superluminal sources

We calculate the gradient of the radiation field generated by a polarization current with a superluminally rotating distribution pattern and show that the absolute value of this gradient increases as R^(7/2) with distance R within the sharply focused subbeams constituting the overall radiation beam. This result not only supports the earlier finding that the azimuthal and polar widths of these subbeams narrow with distance (as R^(-3) and R^(-1), respectively), but also implies that the boundary contribution to the solution of the wave equation governing the radiation field does not always vanish in the limit where the boundary tends to infinity. There is a fundamental difference between the classical expressions for the retarded potential and field: while the boundary contribution for the potential can always be made zero via a gauge transformation preserving the Lorenz condition, that for the field may be neglected only if it diminishes with distance faster than the contribution of the source density in the far zone. In the case of a rotating superluminal source, however, the boundary term in the retarded solution for the field is by a factor of order R^(1/2) larger than the source term of this solution in the limit, which explains why an argument based on the solution of the wave equation governing the field that neglects the boundary term (such as that presented by J. H. Hannay) misses the nonspherical decay of the field. Given that the distribution of the radiation field of an accelerated superluminal source in the far zone is not known a priori, the only way to calculate the free-space radiation field of such sources is via the retarded solution for the potential. Finally, we apply these findings to pulsar observational data: the more distant a pulsar, the narrower and brighter its giant pulses should be.

astro-ph↗

arXiv2007

Dissipation in the superconducting state of kappa-(BEDT-TTF)2Cu(NCS)2

We have studied the interlayer resistivity of the prototypical quasi-two-dimensional organic superconductor $κ$-(BEDT-TTF)$_2$Cu(NCS)$_2$ as a function of temperature, current and magnetic field, within the superconducting state. We find a region of non-zero resistivity whose properties are strongly dependent on magnetic field and current density. There is a crossover to non-Ohmic conduction below a temperature that coincides with the 2D vortex solid -- vortex liquid transition. We interpret the behaviour in terms of a model of current- and thermally-driven phase slips caused by the diffusive motion of the pancake vortices which are weakly-coupled in adjacent layers, giving rise to a finite interlayer resistance.

cond-mat.supr-con↗

arXiv2007

Environmental effects on electron spin relaxation in N@C60

We examine environmental effects of surrounding nuclear spins on the electron spin relaxation of the N@C60 molecule (which consists of a nitrogen atom at the centre of a fullerene cage). Using dilute solutions of N@C60 in regular and deuterated toluene, we observe and model the effect of translational diffusion of nuclear spins of the solvent molecules on the N@C60 electron spin relaxation times. We also study spin relaxation in frozen solutions of N@C60 in CS2, to which small quantities of a glassing agent, S2Cl2 are added. At low temperatures, spin relaxation is caused by spectral diffusion of surrounding nuclear 35Cl and 37Cl spins in the S2Cl2, but nevertheless, at 20 K, T2 times as long as 0.23 ms are observed.

quant-ph↗

arXiv2007

Morphology of the nonspherically decaying radiation beam generated by a rotating superluminal source

We consider the nonspherically decaying radiation field that is generated by a polarization current with a superluminally rotating distribution pattern in vacuum, a field that decays with the distance $\subP{R}$ from its source as $\subP{R}^{-1/2}$, instead of $\subP{R}^{-1}$. It is shown (i) that the nonspherical decay of this emission remains in force at all distances from its source independently of the frequency of the radiation, (ii) that the part of the source that makes the main contribution toward the value of the nonspherically decaying field has a filamentary structure whose radial and azimuthal widths become narrower (as $\subP{R}^{-2}$ and $\subP{R}^{-3}$, respectively), the farther the observer is from the source, (iii) that the loci on which the waves emanating from this filament interfere constructively delineate a radiation `subbeam' that is nondiffracting in the polar direction, (iv) that the cross-sectional area of each nondiffracting subbeam increases as $\subP{R}$, instead of $\subP{R}^2$, so that the requirements of conservation of energy are met by the nonspherically decaying radiation automatically, and (v) that the overall radiation beam within which the field decays nonspherically consists, in general, of the incoherent superposition of such coherent nondiffracting subbeams. These findings are related to the recent construction and use of superluminal sources in the laboratory and numerical models of the emission from them. We also briefly discuss the relevance of these results to the giant pulses received from pulsars.

physics.optics↗

arXiv2007

Will spin-relaxation times in molecular magnets permit quantum information processing?

Using X-band pulsed electron spin resonance, we report the intrinsic spin-lattice ($T_1$) and phase coherence ($T_2$) relaxation times in molecular nanomagnets for the first time. In Cr$_7M$ heterometallic wheels, with $M$ = Ni and Mn, phase coherence relaxation is dominated by the coupling of the electron spin to protons within the molecule. In deuterated samples $T_2$ reaches 3 $μ$s at low temperatures, which is several orders of magnitude longer than the duration of spin manipulations, satisfying a prerequisite for the deployment of molecular nanomagnets in quantum information applications.

quant-ph↗

arXiv2006

Efficient Dynamic Nuclear Polarization at High Magnetic Fields

By applying a new technique for dynamic nuclear polarization involving simultaneous excitation of electronic and nuclear transitions, we have enhanced the nuclear polarization of the nitrogen nuclei in 15N@C60 by a factor of 1000 at a fixed temperature of 3 K and a magnetic field of 8.6 T, more than twice the maximum enhancement reported to date. This methodology will allow the initialization of the nuclear qubit in schemes exploiting N@C60 molecules as components of a quantum information processing device.

quant-ph↗

arXiv2006

The effects of a pyrrolidine functional group on the magnetic properties of N@C60

A new stable pyrrolidine functionalized fullerene derivative, C69H10N2O2, has been synthesized, purified by high performance liquid chromatography, and characterized by MALDI mass spectrometry, ultraviolet-visible spectroscopy, Fourier transform infrared, 1H and 13C nuclear magnetic resonance. The magnetic properties of the analogous endohedral species have been studied by both continuous wave (CW) and pulsed EPR. CW-EPR spectra indicated an anisotropic hyperfine interaction and a permanent zero-field-splitting (ZFS). Both CW and pulsed EPR showed the ZFS parameter Deff to be around 17 MHz. Pulsed EPR revealed a biexponential decay in both T1 and T2, yielding a molecular tumbling correlation time of 31.4 +/- 2.5 ps.

physics.chem-ph↗

arXiv2006

Direct optical excitation of a fullerene-incarcerated metal ion

The endohedral fullerene Er3N@C80 shows characteristic 1.5 micron photoluminescence at cryogenic temperatures associated with radiative relaxation from the crystal-field split Er3+ 4I13/2 manifold to the 4I15/2 manifold. Previous observations of this luminescence were carried out by photoexcitation of the fullerene cage states leading to relaxation via the ionic states. We present direct non-cage-mediated optical interaction with the erbium ion. We have used this interaction to complete a photoluminescence-excitation map of the Er3+ 4I13/2 manifold. This ability to interact directly with the states of an incarcerated ion suggests the possibility of coherently manipulating fullerene qubit states with light.

quant-ph↗

arXiv2006

Davies ENDOR revisited: Enhanced sensitivity and nuclear spin relaxation

Over the past 50 years, electron-nuclear double resonance (ENDOR) has become a fairly ubiquitous spectroscopic technique, allowing the study of spin transitions for nuclei which are coupled to electron spins. However, the low spin number sensitivity of the technique continues to pose serious limitations. Here we demonstrate that signal intensity in a pulsed Davies ENDOR experiment depends strongly on the nuclear relaxation time T1n, and can be severely reduced for long T1n. We suggest a development of the original Davies ENDOR sequence that overcomes this limitation, thus offering dramatically enhanced signal intensity and spectral resolution. Finally, we observe that the sensitivity of the original Davies method to T1n can be exploited to measure nuclear relaxation, as we demonstrate for phosphorous donors in silicon and for the endohedral fullerene N@C60 in CS2.

physics.chem-ph↗

arXiv2006

Bang-bang control of fullerene qubits using ultra-fast phase gates

Quantum mechanics permits an entity, such as an atom, to exist in a superposition of multiple states simultaneously. Quantum information processing (QIP) harnesses this profound phenomenon to manipulate information in radically new ways. A fundamental challenge in all QIP technologies is the corruption of superposition in a quantum bit (qubit) through interaction with its environment. Quantum bang-bang control provides a solution by repeatedly applying `kicks' to a qubit, thus disrupting an environmental interaction. However, the speed and precision required for the kick operations has presented an obstacle to experimental realization. Here we demonstrate a phase gate of unprecedented speed on a nuclear spin qubit in a fullerene molecule (N@C60), and use it to bang-bang decouple the qubit from a strong environmental interaction. We can thus trap the qubit in closed cycles on the Bloch sphere, or lock it in a given state for an arbitrary period. Our procedure uses operations on a second qubit, an electron spin, in order to generate an arbitrary phase on the nuclear qubit. We anticipate the approach will be vital for QIP technologies, especially at the molecular scale where other strategies, such as electrode switching, are unfeasible.

quant-ph↗

arXiv2006

Electron spin relaxation of N@C60 in CS2

We examine the temperature dependence of the relaxation times of the molecules N@C60 and N@C70 (which comprise atomic nitrogen trapped within a carbon cage) in liquid CS2 solution. The results are inconsistent with the fluctuating zero field splitting (ZFS) mechanism, which is commonly invoked to explain electron spin relaxation for S > 1/2 spins in liquid solution, and is the mechanism postulated in the literature for these systems. Instead, we find a clear Arrhenius temperature dependence for N@C60, indicating the spin relaxation is driven primarily by an Orbach process. For the asymmetric N@C70 molecule, which has a permanent non-zero ZFS, we resolve an additional relaxation mechanism caused by the rapid reorientation of its ZFS. We also report the longest coherence time (T2) ever observed for a molecular electron spin, being 0.25 ms at 170K.

cond-mat.mtrl-sci↗

arXiv2005

The effect of irradiation-induced disorder on the conductivity and critical temperature of the organic superconductor $κ$-(BEDT-TTF)$_2$Cu(SCN)$_2$

We have introduced defects into clean samples of the organic superconductor $κ$-(BEDT-TTF)$_2$Cu(SCN)$_2$ in order to determine their effect on the temperature dependence of the conductivity and the critical temperature $T_{\rm c}$. We find a violation of Matthiessen's rule that can be explained by a model of the conductivity involving a defect-assisted interlayer channel which acts in parallel with the band-like conductivity. We observe an unusual dependence of $T_{\rm c}$ on residual resistivity which is not consistent with the generalised Abrikosov-Gor'kov theory for an order parameter with a single component, providing an important constraint on models of the superconductivity in this material.

cond-mat.supr-con↗

arXiv2005

Towards a fullerene-based quantum computer

Molecular structures appear to be natural candidates for a quantum technology: individual atoms can support quantum superpositions for long periods, and such atoms can in principle be embedded in a permanent molecular scaffolding to form an array. This would be true nanotechnology, with dimensions of order of a nanometre. However, the challenges of realising such a vision are immense. One must identify a suitable elementary unit and demonstrate its merits for qubit storage and manipulation, including input / output. These units must then be formed into large arrays corresponding to an functional quantum architecture, including a mechanism for gate operations. Here we report our efforts, both experimental and theoretical, to create such a technology based on endohedral fullerenes or 'buckyballs'. We describe our successes with respect to these criteria, along with the obstacles we are currently facing and the questions that remain to be addressed.

quant-ph↗