arXiv subjects

B. Büchner

Publications and source records attributed to B. Büchner.

At least 217 records · Page 12Linked to original sources

arXiv2011

One-sign order parameter in iron based superconductor

The onset of superconductivity at the transition temperature is marked by the onset of order, which is characterized by an energy gap. Most models of the iron-based superconductors find a sign-changing (s\pm) order parameter [1-6], with the physical implication that pairing is driven by spin fluctuations. Recent work, however, has indicated that LiFeAs has a simple isotropic order parameter [7-9] and spin fluctuations are not necessary [7,10], contrary to the models [1-6]. The strength of the spin fluctuations has been controversial [11,12], meaning that the mechanism of superconductivity cannot as yet be determined. Here we report the momentum dependence of the superconducting energy gap, where we find an anisotropy that rules out coupling through spin fluctuations and the sign change. The results instead suggest that orbital fluctuations assisted by phonons [13,14] are the best explanation for superconductivity.

cond-mat.supr-con↗

arXiv2011

Magnetic properties and revisited exchange integrals of the frustrated chain cuprate PbCuSO$_4$(OH)$_2$ - linarite

We present a detailed study in the paramagnetic regime of the frustrated $s$ = 1/2 spin-compound linarite, PbCuSO$_4$(OH)$_2$, with competing ferromagnetic nearest-neighbor and antiferromagnetic next-nearest-neighbor exchange interactions. Our data reveal highly anisotropic values for the saturation field along the crystallographic main directions, with $\sim$ 7.6, $\sim$ 10.5 and $\sim$ 8.5\,T for the $a$, $b$, and $c$ axes, respectively. In the paramagnetic regime, this behavior is explained mainly by the anisotropy of the \textit{g}-factor but leaving room for an easy-axis exchange anisotropy. Within the isotropic $J_1$-$J_2$ spin model our experimental data are described by various theoretical approaches yielding values for the exchange interactions $J_1$ $\sim$ -100\,K and $J_2$ $\sim$ 36\,K. These main intrachain exchange integrals are significantly larger as compared to the values derived in two previous studies in the literature and shift the frustration ratio $α= J_2/|J_1|$ $\approx$ 0.36 of linarite closer to the 1D critical point at 0.25. Electron spin resonance (ESR) and nuclear magnetic resonance (NMR) measurements further prove that the static susceptibility is dominated by the intrinsic spin susceptibility. The Knight shift as well as the broadening of the linewidth in ESR and NMR at elevated temperatures indicate a highly frustrated system with the onset of magnetic correlations far above the magnetic ordering temperature $T_\mathrm{N}$ = 2.75(5)\,K, in agreement with the calculated exchange constants.

cond-mat.str-el↗

arXiv2011

Magnetic properties of the low-dimensional spin-1/2 magnet α-Cu_2As_2O_7

In this work we study the interplay between the crystal structure and magnetism of the pyroarsenate α-Cu_2As_2O_7 by means of magnetization, heat capacity, electron spin resonance and nuclear magnetic resonance measurements as well as density functional theory (DFT) calculations and quantum Monte Carlo (QMC) simulations. The data reveal that the magnetic Cu-O chains in the crystal structure represent a realization of a quasi-one dimensional (1D) coupled alternating spin-1/2 Heisenberg chain model with relevant pathways through non-magnetic AsO_4 tetrahedra. Owing to residual 3D interactions antiferromagnetic long range ordering at T_N\simeq10K takes place. Application of external magnetic field B along the magnetically easy axis induces the transition to a spin-flop phase at B_{SF}~1.7T (2K). The experimental data suggest that substantial quantum spin fluctuations take place at low magnetic fields in the ordered state. DFT calculations confirm the quasi-one-dimensional nature of the spin lattice, with the leading coupling J_1 within the structural dimers. QMC fits to the magnetic susceptibility evaluate J_1=164K, the weaker intrachain coupling J'_1/J_1 = 0.55, and the effective interchain coupling J_{ic1}/J_1 = 0.20.

cond-mat.str-el↗

arXiv2011

Pseudogap-like phase in Ca(Fe$_{1-x}$Co$_x$)$_2$As$_2$ revealed by $^{75}$As NQR

We report $^{75}$As NQR measurements on single crystalline Ca(Fe$_{1-x}$Co$_x$)$_2$As$_2$ ($0\leq x \leq 0.09$). The nuclear spin-lattice relaxation rate $T_1^{-1}$ as a function of temperature $T$ and Co dopant concentration $x$ reveals a normal-state pseudogap-like phase below a crossover temperature $T^*$ in the under- and optimally-doped region. The resulting $x$-$T$ phase diagram shows that, after suppression of the spin-density-wave order, $T^*$ intersects $T_c$ falling to zero rapidly near the optimal doping regime. Possible origins of the pseudogap behavior are discussed.

cond-mat.supr-con↗

arXiv2011

Comment on "A de Haas-van Alphen study of the Fermi surfaces of superconducting LiFeP and LiFeAs"

In a recent preprint Putzke et al. argued that their dHvA data on LiFeAs are in good agreement with DFT calculations and contradict our ARPES results. Here we show that the situation is just the opposite.

cond-mat.supr-con↗

arXiv2011

Multi-gap superconductivity in single crystals of Ba$_{0.65}$Na$_{0.35}$Fe$_2$As$_2$: A calorimetric investigation

We investigate the electronic properties and the superconducting gap characteristics of a single crystal of hole-doped 122 Fe-pnictide Ba$_{0.65}$Na$_{0.35}$Fe$_2$As$_2$ by means of specific heat measurements. The specific heat exhibits a pronounced anomaly around the superconducting transition temperature $T_c$ = 29.4 K, and a small residual part at low temperature. In a magnetic field of 90 kOe, the transition is broadened and $T_c$ is lowered insignificantly by an amount $\sim$ 1.5 K. We estimate a high electronic coefficient in the normal state with a value 57.5 mJ mol$^{-1}$ K$^2$, being consistent with hole-doped 122 compounds. The temperature-dependent superconducting electronic specific heat cannot be described with single-gap BCS theory under weak coupling approach. Instead, our analysis implies a presence of two s-wave like gaps with magnitudes $Δ_1(0)/k_BT_c$ = 1.06 and $Δ_2(0)/k_BT_c$ = 2.08 with their respective weights of 48% and 52%. While our results have qualitative similarities with other hole-doped 122 materials, the gap's magnitude and their ratio are quite different.

cond-mat.supr-con↗

arXiv2011

Fusion of bogoliubons in Ba$_{1-x}$K$_{x}$Fe$_2$As$_2$ and similarity of energy scales in high temperature superconductors

Usually the superconducting pairing is considered to modify electronic states only in a narrow momentum range close to the Fermi surface. Here we present a direct experimental observation of fusion of Bogoliubov dispersion branches originating from the antipodal Fermi crossings by means of angle-resolved photoemission spectroscopy (ARPES). Uncommon discernibility and brightness of bogoliubons' fusion stems from comparability of the superconducting gap magnitude and the distance from the Fermi level to the band's top, and strong electron scattering on a mode with similar energy. Such similarity of the electronic and pairing energy scales seems to be a persistent associate of high-temperature superconductivity (HTSC) rather than just a mere coincidence.

cond-mat.supr-con↗

arXiv2011

Evidence for conventional superconductivity in SrPd2Ge2

Electronic structure of SrPd2Ge2 single crystals is studied by angle-resolved photoemission spectroscopy (ARPES), scanning tunneling spectroscopy (STS) and band-structure calculations within the local-density approximation (LDA). The STS measurements show single s-wave superconducting energy gap Δ(0) = 0.5 meV. Photon-energy dependence of the observed Fermi surface reveals a strongly three-dimensional character of the corresponding electronic bands. By comparing the experimentally measured and calculated Fermi velocities a renormalization factor of 0.95 is obtained, which is much smaller than typical values reported in Fe-based superconductors. We ascribe such an unusually low band renormalization to the different orbital character of the conduction electrons and using ARPES and STS data argue that SrPd2Ge2 is likely to be a conventional superconductor, which makes it clearly distinct from isostructural iron pnictide superconductors of the "122" family.

cond-mat.supr-con↗

arXiv2011

Observation of Electronic Ferroelectric Polarization in Multiferroic YMn$_2$O$_5$

We report the observation of a magnetic polarization of the O\,$2p$-states in YMn$_2$O$_5$ through the use of soft X-ray resonant scattering at the oxygen $K$-edge. Remarkably, we find that the temperature dependence of the integrated intensity of this signal closely follows the macroscopic electric polarization, and hence is proportional to the ferroelectric order parameter. This is in contrast to the temperature dependence observed at the Mn\,$L_3$-edge, which reflects the Mn magnetic order parameter. First principle calculations provide a microscopic understanding of these results and show that a spin-dependent hybridization of O\,$2p$- and Mn\, 3d-states results in a purely electronic contribution to the ferroelectric polarization, which can exist in the absence of lattice distortions.

cond-mat.str-el↗

arXiv2011

High-field electron spin resonance spectroscopy study of GdO$_{1-x}$F$_{x}$FeAs superconductors

We report a detailed investigation of GdO$_{1-x}$F$_{x}$FeAs (x = 0, 0.07 and 0.14) samples by means of high-field/high-frequency electron spin resonance (HF-ESR) together with measurements of thermodynamic and transport properties. The parent GdOFeAs compound exhibits Fe long-range magnetic order below 128 K, whereas both doped samples do not show such order and are superconducting with T$_c$ = 20 K (x = 0.07) and T$_c$ = 45 K (x = 0.14). The Gd$^{3+}$ HF-ESR reveals an appreciable exchange coupling between Gd and Fe moments, through which the static magnetic order is clearly seen in the parent compound. Owing to this coupling, HF-ESR can probe sensitively the evolution of the magnetism in the FeAs planes upon F doping. It is found that in both superconducting samples, where the Fe long-range order is absent, there are short-range, static on the ESR time scale magnetic correlations between Fe spins. Their occurrence on a large doping scale may be indicative of the ground states' coexistence.

cond-mat.str-el↗

arXiv2011

Signatures of electronic polarons in La$_{1-x}$Sr$_{1+x}$MnO$_4$ observed by electron energy-loss spectroscopy

The dielectric properties of La$_{1-x}$Sr$_{1+x}$MnO$_4$ single crystals with x = 0, 0.125, 0.25, and 0.5 were studied by means of electron energy-loss spectroscopy as a function of temperature and momentum transfer. A clear signature of the doped holes is observed around 1.65 eV energy loss, where spectral weight emerges with increasing x. For all $x \neq 0$, this doping-induced excitation can propagate within the ab-plane, as revealed by a clear upward dispersion of the corresponding loss peak with increasing momentum transfer. The hole-induced excitation also shifts to higher energies with the onset of magnetic correlations for x = 0.5, implying a strong coupling of charge and spin dynamics. We conclude that (i) the loss feature at 1.65 eV is a signature of electronic polarons, which are created around doped holes, and that (ii) this low-energy excitation involves the charge transfer between manganese and oxygen. The finite dispersion of these excitations further indicates significant polaron-polaron interactions.

cond-mat.str-el↗

arXiv2011

Monopolelike probes for quantitative magnetic force microscopy: calibration and application

A local magnetization measurement was performed with a Magnetic Force Microscope (MFM) to determine magnetization in domains of an exchange coupled [Co/Pt]/Co/Ru multilayer with predominant perpendicular anisotropy. The quantitative MFM measurements were conducted with an iron filled carbon nanotube tip, which is shown to behave like a monopole. As a result we determined an additional in-plane magnetization component of the multilayer, which is explained by estimating the effective permeability of the sample within the μ*-method.

cond-mat.mtrl-sci↗

arXiv2010

The superconducting gaps in LiFeAs: Joint study of specific heat and ARPES

We present specific heat, c_P, and ARPES data on single crystals of the stoichiometric superconductor LiFeAs. A pronounced anomaly is found in c_P at the superconducting transition. The electronic contribution can be described by two s-type energy gaps with magnitudes of approximately Delta1 = 1.2 meV and Delta2 = 2.6 meV and a normal-state gamma coefficient of 10 mJ/mol K^2. All these values are in remarkable agreement with ARPES results.

cond-mat.supr-con↗

arXiv2010

Phase diagram of iron-arsenide superconductors Ca(Fe1-xCox)2As2 (0 <= x <= 0.2)

Platelet-like single crystals of the Ca(Fe1-xCox)2As2 series having lateral dimensions up to 15 mm and thickness up to 0.5 mm were obtained from the high temperature solution growth technique using Sn flux. Upon Co doping, the c-axis of the tetragonal unit cell decreases, while the a-axis shows a less significant variation. Pristine CaFe2As2 shows a combined spin-density-wave and structural transition near T = 166 K which gradually shifts to lower temperatures and splits with increasing Co-doping. Both transitions terminate abruptly at a critical Co-concentration of xc = 0.075. For x \geq 0.05, superconductivity appears at low temperatures with a maximum transition temperature TC of around 20 K. The superconducting volume fraction increases with Co concentration up to x = 0.09 followed by a gradual decrease with further increase of the doping level. The electronic phase diagram of Ca(Fe1-xCox)2As2 (0 \leq x \leq 0.2) series is constructed from the magnetization and electric resistivity data. We show that the low-temperature superconducting properties of Co-doped CaFe2As2 differ considerably from those of BaFe2As2 reported previously. These differences seem to be related to the extreme pressure sensitivity of CaFe2As2 relative to its Ba counterpart.

cond-mat.supr-con↗

arXiv2010

Quantitative magnetic force microscopy on permalloy dots using an iron filled carbon nanotube probe

We have characterized a new Magnetic Force Microscopy (MFM) probe based on an iron filled carbon nanotube (FeCNT) using MFM imaging on permalloy (Py) disks saturated in a high magnetic field perpendicular to the disk plane. The experimental data are accurately modeled by describing the FeCNT probe as having a single magnetic monopole at its tip whose effective magnetic charge is determined by the diameter of the iron wire enclosed in the carbon nanotube and its saturation magnetization 4 πM_s ~ 2.2 x 10^4 G. A magnetic monopole probe enables quantitative measurements of the magnetic field gradient close to the sample surface. The lateral resolution is defined by the diameter of the iron wire ~15 nm and the probe-sample separation. As a demonstration, the magnetic field gradients close to the surface of a Py dot in domain and vortex states were imaged.

cond-mat.mes-hall↗

arXiv2010

Fishtail effect and vortex dynamics in LiFeAs single crystals

We investigate the fishtail effect, critical current density ($J_c$) and vortex dynamics in LiFeAs single crystals. The sample exhibits a second peak (SP) in the magnetization loop only with the field $||$ c-axis. We calculate a reasonably high $J_c$, however, values are lower than in 'Ba-122' and '1111'-type FeAs-compounds. Magnetic relaxation data imply a strong pinning which appears not to be due to conventional defects. Instead, its behavior is similar to that of the triplet superconductor Sr$_2$RuO$_4$. Our data suggest that the origin of the SP may be related to a vortex lattice phase transition. We have constructed the vortex phase diagram for LiFeAs on the field-temperature plane.

cond-mat.supr-con↗

arXiv2010

YBa2Cu3O7 grain boundary junctions and low-noise superconducting quantum interference devices patterned by a focused ion beam down to 80 nm linewidth

YBa$_2$Cu$_3$O$_7$ 24$^\circ$ (30$^\circ$) bicrystal grain boundary junctions (GBJs), shunted with 60\,nm (20\,nm) thick Au, were fabricated by focused ion beam milling with widths $80\,{\rm nm} \le w \le 7.8\,μ$m. At 4.2\,K we find critical current densities $j_c$ in the $10^5\,{\rm A/cm^2}$ range %\dkc{\#1} (without a clear dependence on $w$) and an increase in resistance times junction area $ρ$ with an approximate scaling $ρ\propto w^{1/2}$. For the narrowest GBJs $j_cρ\approx 100\,μ$V, which is promising for the realization of sensitive nanoSQUIDs for the detection of small spin systems. We demonstrate that our fabrication process allows the realization of sensitive nanoscale dc SQUIDs; for a SQUID with $w\approx 100$\,nm wide GBJs we find an rms magnetic flux noise spectral density of $S_Φ^{1/2}\approx 4\,μΦ_0/{\rm Hz}^{1/2}$ in the white noise limit. We also derive an expression for the spin sensitivity $S_μ^{1/2}$, which depends on $S_Φ^{1/2}$, on the location and orientation of the magnetic moment of a magnetic particle to be detected by the SQUID, and on the SQUID geometry. For the not optimized SQUIDs presented here, we estimate $S_μ^{1/2}=390\,μ_B/\sqrt{\rm{Hz}}$, which could be further improved by at least an order of magnitude.

cond-mat.supr-con↗

arXiv2010

Non-Resonant X-ray Magnetic Scattering on Rare-Earth Iron Borates RFe$_3$(BO$_3$)$_4$

Hard x-ray scattering (HXS) experiments with a photon energy of 100keV were performed as a function of temperature and applied magnetic field on selected compounds of the RFe$_3$(BO$_3$)$_4$ family. The results show the presence of several unexpected diffraction features, in particular non-resonant magnetic reflections in the magnetically ordered phase, and structural reflections that violate the diffraction conditions for the low temperature phase $P3_121$ of the rare-earth iron borates. The temperature and field dependence of the magnetic superlattice reflections corroborate the magnetic structures of the borate compounds obtained by neutron diffraction. The detailed analysis of the intensity and scattering cross section of the magnetic reflection reveals details of the magnetic structure of these materials such as the spin domain structure of NdFe$_3$(BO$_3$)$_4$ and GdFe$_3$(BO$_3$)$_4$. Furthermore we find that the correlation length of the magnetic domains is around 100 Å for all the compounds and that the Fe moments are rotated $53^\circ\pm3^\circ$ off from the hexagonal basal plane in GdFe$_3$(BO$_3$)$_4$

cond-mat.str-el↗