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B. Damilano

Publications and source records attributed to B. Damilano.

7 recordsLinked to original sources

Enhancing solar cell efficiency of AlxIn1-xN/Si heterojunctions using an a-Si buffer: A study of material, interface and device properties

This study explores the impact of an optimized amorphous silicon (a-Si) buffer layer on AlxIn1-xN-on-Si(100) heterojunction solar cells, with Al content varying from 0% (InN) to 55%. The buffer layer improves the structural quality of the AlInN layer, as evidenced by reduced full width at half maximum values in X-ray diffraction rocking curves around the AlInN (0002) peak. Atomic force microscopy reveals that the buffer layer does not alter surface roughness. The effectiveness of the a-Si buffer is demonstrated by an enhancement of the conversion efficiency under AM1.5G illumination from 3.3 % to 3.9 % for devices with 35 % Al. Looking at the effect of the Al content in devices with the a-Si buffer, the device with 22% Al shows the best photovoltaic performance, with a conversion efficiency of 4.1 % and a VOC of 0.42 V, JSC of 15.4 mA/cm2, and FF of 63.3%. However, performance declines for Al contents above 36% due to increased resistivity and reduced carrier concentration. These findings highlight the critical role of the novel a-Si buffer layer developed by RF-sputtering and the Al content in optimizing AlInN/Si heterojunction solar cell performance.

cond-mat.mtrl-sci

InN nanowire solar cells on Si with amorphous Si interlayer deposited by sputtering

Here, we report the first experimental demonstration of InN nanowire solar cells deposited by RF sputtering with a bandgap energy of 1.78 eV. By adding an amorphous Si (a-Si) buffer to the n-InN/p-Si structure, we have improved the photovoltaic performance of the resulting devices while maintaining their material quality. We have firstly optimized the deposition of Si on Si(100) by DC sputtering, obtaining an amorphous material with bandgap energy of 1.39 eV. Then we have studied the influence of the thickness of the a-Si buffer layer (0-25 nm) on the structural, morphological, electrical, and optical properties of InN nanowires on Si (100) substrates. With the use of a 15-nm buffer, n-InN/a-Si/p-Si nanowire heterojunction solar cells exhibit a promising short-circuit current density of 17 mA/cm2, open circuit voltage of 0.37 V and fill factor of 35.5%, pointing to a power-conversion efficiency of 2.3% under 1-sun (AM 1.5G) illumination. These work demonstrated that the combination of in-situ sputtered a-Si, which could serve as potential passivation layer, and the light trapping enhancement by the nanostructured active layer leads to an improvement of the photovoltaic efficiency of sputtered III-nitride devices.

physics.app-ph

Electrostatic modulation of excitonic fluid in GaN/AlGaN quantum wells by deposition of few-layered graphene and nickel/gold films

Excitons hosted by GaN/(Al,Ga)N quantum wells (QWs) are spatially indirect due to the giant built-in electric field that separates electrons and holes along the growth direction. This electric field, and thus exciton energy, can be reduced by depositing metallic layers on the sample surface. Using spatially-resolved micro-photoluminescence spectroscopy we compare the effects of two different materials, Nickel/Gold (NiAu) and few-layered graphene (FLG), on the potential landscape experienced by the excitons. We are able to (i) determine the potential barriers imposed on QW excitons by deposition of FLG and NiAu to be $14$ and $82$~meV, respectively, and (ii) to evidence their impact on the exciton transport at appropriate densities. Optical losses and inhomogeneous broadening induced by deposition of NiAu and FLG layers are similar, and their joined implementation constitute a promising tool for electrostatic modulation of IX densities even in the absence of any applied electric bias.

cond-mat.quant-gas

Electrical control of excitons in GaN/(Al,Ga)N quantum wells

A giant built-in electric field in the growth direction makes excitons in wide GaN/(Al, Ga)N quantum wells spatially indirect even in the absence of any external bias. Significant densities of indirect excitons can accumulate in electrostatic traps imprinted in the quantum well plane by a thin metal layer deposited on top of the heterostructure. By jointly measuring spatially-resolved photoluminescence and photo-induced current, we demonstrate that exciton density in the trap can be controlled via an external electric bias, which is capable of altering the trap depth. Application of a negative bias deepens the trapping potential, but does not lead to any additional accumulation of excitons in the trap. This is due to exciton dissociation instigated by the lateral electric field at the electrode edges. The resulting carrier losses are detected as an increased photo-current and reduced photoluminescence intensity. By contrast, application of a positive bias washes out the electrode-induced trapping potential. Thus, excitons get released from the trap and recover free propagation in the plane that we reveal by spatially-resolved photoluminescence.

cond-mat.quant-gas

Complexity of dipolar exciton Mott transition in GaN/(AlGa)N nanostructures

The Mott transition from a dipolar excitonic liquid to an electron-hole plasma is demonstrated in a wide GaN/(Al,Ga)N quantum well at $T=7$K by means of spatially-resolved magneto-photoluminescence spectroscopy. Increasing optical excitation density we drive the system from the excitonic state, characterized by a diamagnetic behavior and thus a quadratic energy dependence on the magnetic field, to the unbound electron-hole state, characterized by a linear shift of the emission energy with the magnetic field. The complexity of the system requires to take into account both the density-dependence of the exciton binding energy and the exciton-exciton interaction and correlation energy that are of the same order of magnitude. We estimate the carrier density at Mott transition as $n_\mathrm{Mott}\approx 2\times 10^{11}$cm$^{-2}$ and address the role played by excitonic correlations in this process. Our results strongly rely on the spatial resolution of the photoluminescence and the assessment of the carrier transport. We show, that in contrast to GaAs/(Al,Ga)As systems, where transport of dipolar magnetoexcitons is strongly quenched by the magnetic field due to exciton mass enhancement, in GaN/(Al,Ga)N the band parameters are such that the transport is preserved up to $9$T.

cond-mat.mes-hall

Dipolar excitons offer a rich playground for both design of novel optoelectronic devices and fundamental many-body physics

Dipolar excitons offer a rich playground for both design of novel optoelectronic devices and fundamental many-body physics. Wide GaN/(AlGa)N quantum wells host a new and promising realization of dipolar excitons. We demonstrate the in-plane confinement and cooling of these excitons, when trapped in the electrostatic potential created by semitransparent electrodes of various shapes deposited on the sample surface. This result is a prerequisite for the electrical control of the exciton densities and fluxes, as well for studies of the complex phase diagram of these dipolar bosons at low temperature.

physics.app-ph

Highly resistive epitaxial Mg-doped GdN thin films

We report the growth by molecular beam epitaxy of highly resistive GdN, using intentional doping with magnesium. Mg-doped GdN layers with resistivities of 1000 Ω.cm and carrier concentrations of 10E16 cm-3 are obtained for films with Mg concentrations up to 5 x 10E19 atoms/cm3. X-ray diffraction rocking curves indicate that Mg-doped GdN films have crystalline quality very similar to undoped GdN films, showing that the Mg doping did not affect the structural properties of the films. A decrease of the Curie temperature with decreasing the electron density is observed, supporting a recently suggested magnetic polaron scenario [F. Natali et al., Phys. Rev. B 87, 035202 (2013)].

cond-mat.mtrl-sci