arXiv subjects

Baohua Jia

Publications and source records attributed to Baohua Jia.

At least 19 recordsLinked to original sources

arXiv2026

Building a physics-aware AI ecosystem for solid-state hydrogen storage materials

Hydrogen storage remains a central bottleneck for scalable hydrogen energy systems due to the multiscale and coupled nature of the thermodynamics, kinetics, and microstructural evolution of hydrogen storage materials (HSMs). Although artificial intelligence (AI) has accelerated materials discovery, current approaches remain constrained by fragmented data, limited physical consistency, and weak integration with experimental validation. Here, we propose a unified framework that integrates coherent data infrastructure, physics-grounded modeling, and AI-driven inverse design within a closed-loop discovery paradigm. By embedding physical constraints and experimental feedback, this approach enables adaptive, physically consistent optimization, thereby establishing a pathway toward autonomous, digital-twin-enabled discovery of HSMs.

cond-mat.mtrl-sci↗

arXiv2026

AI assisted optimization of integrated waveguide polarizers containing 2D reduced graphene oxide

Reduced graphene oxide (rGO) exhibits strong anisotropic light absorption and high compatibility with photonic integrated chips, making it a promising material for implementing high performance onchip polarization selective devices. The performance of rGO integrated waveguide polarizers is highly dependent on the waveguide geometry, and achieving optimal performance requires exploring a large parameter space, making conventional mode simulation methods computationally demanding. Here, we propose and demonstrate a machine learning framework based on fully connected neural networks (FCNNs) to map the dependence of the polarizer figure of merit (FOM) on the waveguide geometry. Once trained by using a small dataset of low resolution mode simulation results, the FCNN framework can rapidly and accurately predict FOM values across a large structural parameter space with high resolution. Results show that this method can reduce overall computing time by more than 4 orders of magnitude as compared to the mode simulation methods, and achieve high prediction accuracy with an average deviation (AD) below 0.05. These results highlight the FCNN based machine learning framework as an efficient tool for the design and optimization of rGO integrated waveguide polarizers.

physics.optics↗

arXiv2026

AI based design of 2D material integrated optical polarizers

On-chip integration of highly anisotropic two-dimensional (2D) materials offers new opportunities for realizing high performance polarization selective devices. Obtaining optimized designs for such devices requires extensively sweeping large parameter spaces, which in conventional approaches relies on massive mode simulations that demand considerable computational resources. Here, we address this limitation by developing a machine learning (ML) model based on fully connected neural networks (FCNNs). Trained by using mode simulation results for low resolution structural parameters, the FCNN model can accurately predict polarizer figures of merits (FOMs) for high resolution parameters and rapidly map the global variation trend across the entire parameter space. We test the performance of the FCNN model using two types of polarizers with 2D graphene oxide (GO) and molybdenum disulfide (MoS2). Results show that, compared to conventional mode simulation approach, our approach can not only reduce the overall computing time by about 4 orders of magnitude, but also achieve highly accurate FOM predictions with an average deviation of less than 0.04. In addition, the measured FOM values for the fabricated devices show good agreement with the predicted ones, with discrepancies remaining below 0.2. These results validate artificial intelligence (AI) as an effective approach for designing and optimizing 2D-material based optical polarizers with high efficiency.

physics.optics↗

arXiv2025

Fully automatic fabrication of fibre Bragg gratings using an AI-powered femtosecond laser inscription system

Fibre Bragg gratings (FBGs) are widely used in optical sensing and communication systems. Femtosecond laser inscription (FLI) enables hydrogen-free, thermally stable, high-resolution, and complex structures of FBG fabrication, but its practical application is limited by manual operation, low throughput, and sensitivity to laser alignment. In this study, we present an AI-powered FLI system that enables automated, stable, and efficient FBG fabrication. By integrating a Multi-Layer Perceptron (MLP) model for real-time fabrication position correction, the system maintains precise laser alignment (-0.6 to 0.2 microns of the fibre core plane) and ensures consistent processing. Strong and weak FBGs were fabricated in different types of fibres, and their spectral characteristics-including central wavelength, reflectivity, and FWHM-exhibited high stability and repeatability. The results demonstrate that the proposed AI-powered FLI system significantly reduces manual intervention while achieving reliable FBG performance. This approach holds great promise for scalable, high-throughput FBG production and can be extended to the fabrication of arbitrary FBG structures across various fibre types. With further training and model refinement, the AI-powered FLI provides a scalable and intelligent platform for next-generation automated FBG manufacturing.

physics.optics↗

arXiv2025

Unraveling longitudinal field mediated versatile Stokes polarimetry

Stokes polarimetry has been considered as an alluring platform that enables a plethora of applications ranging from single-molecule orientation to deep-space sensing. Existing polarimetry avenues, however, rely primarily on the transversely polarized field reconstruction, thus suffering from several challenges such as multiple time sequenced detections, complex demodulation algorithms, and intricate engineering procedures. To circumvent these challenges, here we first demonstrate a longitudinally polarized field mediated recipe for the realization of efficacious and refined Stokes polarimetry in situ. This is achieved by unraveling the spin-to-orbit momentum conversion under non-paraxial focusing conditions enabling the direct mapping of the polarization ellipse. Leveraging this mechanism, we reveal an analytical solution of polarization ellipse via the local sampling of longitudinal field, in which the robustness can be fairly reinforced by relevant global retrieval based on convolutional neural network. The resultant Stokes polarimetry is shown to simultaneously exhibit in-situ signal acquisition (direct discernment), unparalleled demodulation time (up tomicrosecond level), superior detection efficiency (no need of troublesome design), and ultra-high retrieved accuracy (less than 1%), which is fundamentally inaccessible with traditional polarimetry methods. Our work holds great promise for empowering an allin-one versatile vector polarimeter, which opens up a host of applications relevant to polarization control.

physics.optics↗

arXiv2025

Femtosecond low-threshold all-optical switching enabled by giant broadband optical nonlinearity from heteroatom doping

Ultrafast all-optical switching (AOS) is pivotal for advancing integrated photonic devices, from high-speed photonic information processing to next generation all-optical computing and communication networks. However, conventional nonlinear materials suffer from sluggish response time, high power threshold, weak and narrow-bandwidth optical nonlinearities, critically limiting their viability. Here, we report a heteroatom engineering strategy to overcome these limitations by designing zero-dimensional nitrogen-doped carbon quantum dots (N-CQDs) with nonlinear optical performance far exceeding the state-of-the-art. Leveraging spatial self-phase modulation (SSPM) and ultrafast pump-probe technique, we first demonstrate an all-in-one AOS platform, where femtosecond laser pulses serve dual roles as control and signal beams. The AOS simultaneously realizes ultrafast response time (520 fs), ultralow threshold energy (2.2 Wcm-2), and giant nonlinear refraction indexes (10-5 cm2/W) in the wide spectral range (400-1064 nm), yielding performance surpassing state-of-the-art nonlinear carbon materials (i.e. carbon nanotube) by orders of magnitude. Spectroscopic and bandgap analyses attribute these exotic performances to enhanced n-pi interaction enabled by nitrogen doping, which amplifies nonlinear polarization dynamics. Crucially, ultrafast fluorescence spectroscopy reveals a large two-photon absorption cross-section of the N-CQDs, challenging the conventional cognition that broadband SSPM necessitates single-photon excitation. This discovery unveils a multi-channel AOS rooted in synergistic single-photon and two-photon processes.. This work demonstrates a new paradigm for achieving ultrafast, broadband, and energy-efficient AOS by heteroatom doping engineering.

physics.optics↗

arXiv2024

Lattice Energy Reservoir in Metal Halide Perovskites

Metal halide perovskite-based technologies have been rapidly developed during the last decade. However, to date, the fundamental question, why are halide perovskites superior to conventional semiconductors? has remained elusive. Here, we propose a new theory of lattice energy reservoir (LER) in halide perovskites and elucidate that LER can comprehensively impact charge carrier dynamics and thus enhance device performance, from hot carrier cooling, carrier recombination, anomalous upconversion fluorescence, illumination induced fluorescence enhancement (photobrightening), to high efficiency solar cells and light-emitting diodes. An LER is a dynamic nanodomain in halide perovskites with suppressed thermal transport that can accumulate energy from phonon coupling and then feedback to subgap carriers and result in subgap carrier upconversion. The LER directly results in slowed cooling of hot carriers and significantly prolonged carrier recombination, anomalous upconversion fluorescence, as usually termed as defect tolerance, as well as the anomalous ultraslow phenomena including persistent polarization, memory effect, and photobrightening. The LER theory rationalizes the superior optoelectronic properties and device performance and provides a novel physical understanding for anomalous phenomena observed uniquely in halide perovskites.

cond-mat.mtrl-sci↗

arXiv2024

Waveguide optical parametric amplifiers in silicon nitride with 2D graphene oxide films

Optical parametric amplification (OPA) represents a powerful solution to achieve broadband amplification in wavelength ranges beyond the scope of conventional gain media, for generating high-power optical pulses, optical microcombs, entangled photon pairs and a wide range of other applications. Here, we demonstrate optical parametric amplifiers based on silicon nitride (Si3N4) waveguides integrated with two-dimensional (2D) layered graphene oxide (GO) films. We achieve precise control over the thickness, length, and position of the GO films using a transfer-free, layer-by-layer coating method combined with accurate window opening in the chip cladding using photolithography. Detailed OPA measurements with a pulsed pump for the fabricated devices with different GO film thicknesses and lengths show a maximum parametric gain of ~24.0 dB, representing a ~12.2 dB improvement relative to the device without GO. We perform a theoretical analysis of the device performance, achieving good agreement with experiment and showing that there is substantial room for further improvement. This work represents the first demonstration of integrating 2D materials on chips to enhance the OPA performance, providing a new way of achieving high performance photonic integrated OPA by incorporating 2D materials.

physics.optics↗

arXiv2023

Fundamental cause for superior optoelectronic properties in halide perovskites

Halide perovskites have emerged as revolutionary materials for high performance photovoltaics and optoelectronics due to their superior optoelectronic properties. The physical origin for the superior optoelectronic properties of halide perovskites so far is still poorly understood. Here we propose and demonstrate a hypothesis that electron upconversion (detrapping) driven by ionic energy reservoir is the fundamental cause for the superior optoelectronic properties of halide perovskites. We fully consider ionic influence on the electronic dynamics in mixed ionic-electronic conduction system by introducing new concepts of ionic energy reservoir, ion-electron coupling and ion-phonon scattering. We clarified that the ionic beneficial effect originates from the different mechanisms from that of the detrimental effect of mobile ion. Our hypothesis consistently interprets that the electron detrapping directly leads to significantly enhanced fluorescence efficiency, prolonged carrier lifetime, and increased diffusion length, as well as the anomalous phenomena of defect healing and defect tolerance, which are responsible for the excellent device performance of halide perovskites. By adding the ion-electron coupling into the rate equations, we establish the physical correlation between electronic dynamics in the timescale of nanosecond-microsecond and ionic dynamics in the timescales of second to hour. This finding adds the missing puzzle into the holistic physics picture and provides a deep understanding of halide perovskites and ion-electron interaction in mixed ionic-electronic semiconductors. Our results suggest the possibility of maximizing the potential of halide perovskite devices through enhancing ion-electron coupling.

physics.app-ph↗

arXiv2022

Enhanced self-phase modulation in silicon nitride waveguides integrated with 2D graphene oxide films

We experimentally demonstrate enhanced self-phase modulation (SPM) in silicon nitride (Si3N4) waveguides integrated with 2D graphene oxide (GO) films. GO films are integrated onto Si3N4 waveguides using a solution-based, transfer-free coating method that enables precise control of the film thickness. Detailed SPM measurements are carried out using both picosecond and femtosecond optical pulses. Owing to the high Kerr nonlinearity of GO, the hybrid waveguides show significantly improved spectral broadening compared to the uncoated waveguide, achieving a broadening factor of up to ~3.4 for a device with 2 layers of GO. By fitting the experimental results with theory, we obtain an improvement in the waveguide nonlinear parameter by a factor of up to 18.4 and a Kerr coefficient (n2) of GO that is about 5 orders of magnitude higher than Si3N4. Finally, we provide a theoretical analysis for the influence of GO film length, coating position, and its saturable absorption on the SPM performance. These results verify the effectiveness of on-chip integrating 2D GO films to enhance the nonlinear optical performance of Si3N4 devices.

physics.optics↗

arXiv2022

Enhanced spectral broadening via self-phase modulation with femtosecond optical pulses in silicon nanowires integrated with 2D graphene oxide films

We experimentally demonstrate enhanced spectral broadening of femtosecond optical pulses af-ter propagation through silicon-on-insulator (SOI) nanowire waveguides integrated with two-dimensional (2D) graphene oxide (GO) films. Owing to the strong mode overlap between the SOI nanowires and the GO films with a high Kerr nonlinearity, the self-phase modulation (SPM) process in the hybrid waveguides is significantly enhanced, resulting in greatly improved spectral broadening of the femtosecond optical pulses. A solution-based, transfer-free coating method is used to integrate GO films onto the SOI nanowires with precise control of the film thickness. Detailed SPM measurements using femtosecond optical pulses are carried out, achieving a broadening factor of up to ~4.3 for a device with 0.4-mm-long, 2 layers of GO. By fit-ting the experimental results with theory, we obtain an improvement in the waveguide nonlin-ear parameter by a factor of ~3.5 and the effective nonlinear figure of merit (FOM) by a factor of ~3.8, relative to the uncoated waveguide. Finally, we discuss the influence of GO film length on the spectral broadening and compare the nonlinear optical performance of different integrated waveguides coated with GO films. These results confirm the improved nonlinear optical per-formance for silicon devices integrated with 2D GO films.

physics.optics↗

arXiv2022

Observation of emergent Dirac physics at the surfaces of acoustic higher-order topological insulators

Using three-dimensional (3D) sonic crystals as acoustic higher-order topological insulators (HOTIs), we discover two-dimensional (2D) surface states described by spin-1 Dirac equations at the interfaces between the two sonic crystals with distinct topology but the same crystalline symmetry. We find that the Dirac mass can be tuned by the geometry of the two sonic crystals. The sign reversal of the Dirac mass reveals a surface topological transition where the surface states exhibit zero refractive index behavior. When the surface states are gapped, one-dimensional (1D) hinge states emerge due to the topology of the gapped surface states. We confirm experimentally the zero refractive index behavior and the emergent topological hinge states. Our study reveals a multidimensional Wannier orbital control that leads to extraordinary properties of surface states and unveils an interesting topological mechanism for the control of surface waves.

cond-mat.mes-hall↗

arXiv2021

Dual-Polarization Second-Order Photonic Topological Insulators

Second-order photonic topological insulators that host highly localized corner states resilient to defects, are opening new routes towards developing fascinating photonic devices. However, the existing works on second-order photonic topological insulators have mainly focused on either transverse magnetic or transverse electric modes. In this paper, we propose a dual-polarization topological photonic crystal structure for both transverse magnetic and transverse electric modes through topology optimization. Simple tight-binding lattice models are constructed to reveal the topological features of the optimized photonic crystal structure in a transparent way. The optimized dual-polarization second-order photonic topological insulator hosts four groups of corner states with different profiles and eigenfrequencies for both the transverse magnetic and transverse electric modes. Moreover, the robustness of theses corner states against defects is explicitly demonstrated. Our results offer opportunities for developing polarization-independent topological photonic devices.

physics.optics↗

arXiv2021

Design of microring resonators integrated with 2D graphene oxide films for four-wave mixing

We theoretically investigate and optimize the performance of four-wave mixing (FWM) in microring resonators (MRRs) integrated with two-dimensional (2D) layered graphene oxide (GO) films. Owing to the interaction between the MRRs and the highly nonlinear GO films as well as to the resonant enhancement effect, the FWM efficiency in GO-coated MRRs can be significantly improved. Based on previous experiments, we perform detailed analysis for the influence of the GO film parameters and MRR coupling strength on the FWM conversion efficiency (CE) of the hybrid MRRs. By optimizing the device parameters to balance the trade-off between the Kerr nonlinearity and loss, we achieve a high CE enhancement of ~18.6 dB relative to the uncoated MRR, which is ~8.3 dB higher than previous experimental results. The influence of photo-thermal changes in the GO films as well as variations in the MRR parameters such as the ring radius and waveguide dispersion on the FWM performance is also discussed. These results highlight the significantly improved FWM performance that can be achieved in MRRs incorporating GO films and provide a guide for optimizing their FWM performance.

physics.optics↗

arXiv2021

Design of silicon waveguides for Kerr nonlinear optical performance with graphene oxide films

The Kerr nonlinear optical performance of silicon nanowire waveguides integrated with 2D layered graphene oxide (GO) films is theoretically studied and optimized based on experimentally measured linear and nonlinear optical parameters of the GO films. The strong mode overlap between the silicon nanowires and highly nonlinear GO films yields a significantly enhanced Kerr nonlinearity for the hybrid waveguides. A detailed analysis for the influence of waveguide geometry and GO film thickness on the propagation loss, nonlinear parameter, and nonlinear figure of merit (FOM) is performed. The results show that the effective nonlinear parameter and nonlinear FOM can be increased by up to 52 and 79 times relative to bare silicon nanowires, respectively. Self-phase modulation (SPM)-induced spectral broadening of optical pulses is used as a benchmark to evaluate the nonlinear performance, examining the tradeoff between enhancing Kerr nonlinearity and minimizing loss. By optimizing the device parameters to balance this, a high spectral broadening factor of 27.8 can be achieved, more than 6 times that achieved in previous experiments. Finally, the influence of pulse chirp, material anisotropy, and the interplay between saturable absorption and SPM is also discussed, together with the comparison between the spectral broadening after going through GO-coated and graphene-coated silicon waveguides. These results provide useful guidance for optimizing the Kerr nonlinear optical performance of silicon waveguides integrated with 2D layered GO films.

physics.optics↗

arXiv2021

Graphene oxide films for ultra-flat optics and linear and nonlinear integrated photonic circuits

With superior optical properties, high flexibility in engineering its material properties, and strong capability for large-scale on-chip integration, graphene oxide (GO) is an attractive solution for on-chip integration of two-dimensional (2D) materials to implement functional integrated photonic devices capable of new features. Over the past decade, integrated GO photonics, representing an innovative merging of integrated photonic devices and thin GO films, has experienced significant development, leading to a surge in many applications covering almost every field of optical sciences. This paper reviews the recent advances in this emerging field, providing an overview of the optical properties of GO as well as methods for the on-chip integration of GO. The main achievements made in GO hybrid integrated photonic devices for diverse applications are summarized. The open challenges as well as the potential for future improvement are also discussed.

physics.optics↗

arXiv2021

Theoretical design study of FWM in silicon nitride waveguides with integrated graphene oxide films

We theoretically investigate and optimize four-wave mixing (FWM) in silicon nitride (SiN) waveguides integrated with two-dimensional (2D) layered graphene oxide (GO) films. Based on extensive previous measurements of the material parameters of the GO films, we perform detailed analysis for the influence of device parameters including waveguide geometry, GO film thickness, length, and coating position on the FWM conversion efficiency (CE) and conversion bandwidth (CB). The influence of dispersion and photo-thermal changes in the GO films is also discussed. Owing to the strong mode overlap between the SiN waveguides and the highly nonlinear GO films, FWM in the hybrid waveguides can be significantly enhanced. We obtain good agreement with previous experimental results and show that by optimizing the device parameters to balance the trade-off between Kerr nonlinearity and loss, the FWM CE can be improved by as much as ~20.7 dB and the FWM CB can be increased by ~4.4 folds, relative to the uncoated waveguides. These results highlight the significantly enhanced FWM performance that can be achieved in SiN waveguides by integrating 2D layered GO films.

physics.optics↗

arXiv2020

High performance integrated polarizers achieved by incorporating 2D layered graphene oxide films

Polarizers and polarization selective resonant cavities (e.g., ring resonators, gratings), are key components for applications to photography, coherent optical detection, polarization-division-multiplexing, optical sensing and liquid crystal displays. We demonstrate waveguide polarizers and polarization discriminating micro-ring resonators (MRRs) by integrating them with 2D graphene oxide (GO) layered thin films. We achieve precise control of the thickness, placement, and size of the films integrated onto photonic devices with a solution based, layer-by-layer transfer-free coating method combined with photolithography and lift-off. This overcomes limitations of layer transfer methods for 2D materials and is a significant advance to manufacturing integrated photonic devices incorporated with 2D materials. We measure the waveguide polarizer for different film thicknesses and lengths versus wavelength, polarization, and power, measuring a high polarization dependent loss (PDL) of ~ 53.8 dB. For GO-coated MRRs, we achieve an extinction ratio difference for TE/TM polarizations of 8.3-dB. We also present measurements of the linear optical properties of 2D layered GO films that yield the material loss anisotropy of the GO films and relative contribution of film loss anisotropy versus polarization-dependent mode overlap. Our results offer interesting physical insights into the transition of the layered GO films from 2D behaviour to quasi bulk like behavior and confirm the high performance of GO based integrated polarization selective devices.

physics.optics↗