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Bernd Rellinghaus

Publications and source records attributed to Bernd Rellinghaus.

At least 19 recordsLinked to original sources

Vector-field control and emergent basal-plane anisotropy of magnetic textures in noncentrosymmetric (Fe$_{0.63}$Ni$_{0.3}$Pd$_{0.07}$)$_3$P

(Fe$_{0.63}$Ni$_{0.3}$Pd$_{0.07}$)$_3$P is a room-temperature magnet with $S_4$ symmetry that hosts a rich variety of topological spin textures. Here, we report a combined resonant small-angle x-ray scattering and ptychography study of (Fe$_{0.63}$Ni$_{0.3}$Pd$_{0.07}$)$_3$P in vector magnetic fields over a broad temperature range. We demonstrate deterministic vector-field control of magnetic stripe domains, where in-plane fields continuously rotate their orientation via a transition from a chiral stripe to an achiral fan configuration. Furthermore, at 50 K and below, the stripe orientation becomes metastably pinned and retains its field-trained direction. While the magnitude of the wavevector is nearly isotropic within the basal plane at room temperature, a pronounced temperature evolution of anisotropic interactions emerges upon cooling. In particular, non-trivial anisotropy axes develop at 20-50 K reflecting the combined effects of magnetocrystalline anisotropy, anisotropic exchange, and Dzyaloshinskii-Moriya interaction (DMI), whose effective orientation is found to rotate with temperature. These results establish (Fe$_{0.63}$Ni$_{0.3}$Pd$_{0.07}$)$_3$P as a model system for vector-field control of chiral spin textures and reveal a previously unrecognized temperature-driven evolution of the effective DMI landscape in a noncentrosymmetric magnet.

cond-mat.mes-hall

Universal material basis for biocompatible printed electrolytes in Organic Electrochemical Transistors

Organic Electrochemical Transistors (OECTs) stand out for their interplay between ionic and electronic conduction, making them ideal analogues to biological synapses for neuromorphic computing and biosensing applications. Furthermore, they can be printed into integrated circuits on flexible substrates, enabling low-cost and high-throughput fabrication of complete electronic systems. However, most OECT electrolytes for integrated circuits still lack biocompatibility and suffer from rheology-related printing challenges. This paper presents a novel material basis that can be combined with an ionic liquid to fabricate an electrolyte for OECTs that only contains biocompatible materials. It allows rheological adjustments to enable the use of electrolyte in both inkjet and screen printing. Furthermore, the electrolyte is UV-curable, enabling it to transition into solid-state structures after printing. Extended ink and device lifetimes for screen-printed structures enable the fabrication of advanced OECTs that can operate in ambient air for over 30 days after fabrication. Ultimately, a fully screen-printed transistor using only biocompatible materials on a leaf substrate is shown

cond-mat.soft

Noise Estimation and Suppression in Quantitative EMCD Measurements

Quantitative electron magnetic circular dichroism (EMCD) in transmission electron microscopy (TEM) enables the measurement of magnetic moments with elemental and atomic site sensitivity, but its practical application is fundamentally limited by noise. This study presents a comprehensive methodology for noise estimation and suppression in EMCD measurements, demonstrated on Ti-doped barium hexaferrite lamellae. By employing a classical three-beam geometry and long-term acquisition of electron energy-loss spectra, we systematically analyze the signal-to-noise ratio (SNR) across individual energy channels using bootstrap statistics. A robust energy alignment procedure based on the neighboring Ba-M4,5 edges with an adequate energy upsampling is introduced to minimize systematic errors from energy misalignment. The impact of detector noise, particularly from CMOS-based EELS cameras, is evaluated through variance-to-mean analysis and described by the noise amplification coefficients, revealing that detector-amplified shot noise is the dominant noise source. We recommend a stricter SNR threshold for reliable EMCD detection and quantification, ensuring that critical spectral features such as the Fe-L2,3 peaks meet the requirements for quantitative analysis. The approach also provides a framework for determining the minimum electron dose necessary for valid measurements and can be generalized to scintillator-based or direct electron detectors. This work advances the reliability of EMCD as a quantitative tool for magnetic characterization at the nanoscale with unknown magnetic structures. The proposed procedures lay the groundwork for improved error handling and SNR optimization in future EMCD studies.

cond-mat.mtrl-sci

Characterizing the Structure of 3D DNA Origami in a Transmission Electron Microscope

DNA origami nanostructures provide programmable control over nanoscale geometry but remain challenging to image due to their low atomic number. Here, we systematically evaluate imaging strategies for both stained and unstained DNA origami deposited on carbon-coated TEM grids. Using Weber contrast as a quantitative metric, we compared different operating modes of (scanning) transmission electron microscopy, (S)TEM, in order to find optimum imaging conditions. STEM was consistently found to deliver the highest contrast, with optimal performance at a camera length of 600 mm towards the high angle annular dark field (HAADF) detector. As expected, the contrast was higher for the thicker three-dimensional nanotubes as compared to DNA 6-helix bundles (6HBs) due to the larger projected thickness of the former. The contrast was effectively enhanced by heavy metal staining with uranyl formate. Notably, 3D molds preserved their designated dimensions upon staining and also largely retained their structural integrity upon complexation with palladium, which also improved the visibility of the structures. These results establish STEM as the optimal approach for high-contrast imaging of DNA origami even of unstained samples and provide practical guidelines for sample preparation and imaging conditions that promote reliable structural visualization.

cond-mat.mtrl-sci

DNA mold-based fabrication of continuous silver nanostructures

Bottom-up fabrication of inorganic nanostructures is emerging as an alternative to classical top-down approaches, offering precise nanometer-scale control at relatively low cost and effort. In particular, DNA nanostructures provide versatile scaffolds for directly templating the growth of metal structures. Previously, a DNA mold-based method for metal nanostructure synthesis has been established that supports a modular structure design and a high control over the structure formation. So far, this method was limited to the growth of gold and palladium nanostructures. Here, we report the successful adaptation of the DNA mold-based fabrication method to produce continuous silver nanowires. By optimizing reagent concentrations and applying gentle thermal annealing, we obtain continuous wire structures of several hundred nanometer length, overcoming limitations in anisotropic growth. Despite the strong interaction of silver ions with DNA, we can control the growth without increasing the complexity of our approach. Our structures are not oxidized yet they did not exhibit conductivity. This work demonstrates the versatility of DNA-templated metallization and opens new opportunities for constructing self-assembled hybrid nanostructures with controlled shape and composition.

cond-mat.mtrl-sci

Spin-to-charge conversion in orthorhombic RhSi topological semimetal crystalline thin films

The rise of non-magnetic topological semimetals, which provide a promising platform for observing and controlling various spin-orbit effects, has led to significant advancements in the field of topological spintronics. RhSi exists in two distinct polymorphs: cubic and orthorhombic crystal structures. The noncentrosymmetric B20 cubic structure has been extensively studied for hosting unconventional multifold fermions. In contrast, the orthorhombic structure, which crystallizes in the Pnma space group (No. 62), remains less explored and belongs to the family of topological Dirac semimetals. In this work, we investigate the structural, magnetic, and electrical properties of RhSi textured-epitaxial films grown on Si(111) substrates, which crystallize in the orthorhombic structure. We investigate the efficiency of pure spin current transport across RhSi/permalloy interfaces and the subsequent spin-to-charge current conversion via inverse spin Hall effect measurements. The xperimentally determined spin Hall conductivity in orthorhombic RhSi reaches a maximum value of 126 ($\hbar$/e)($\Omega$.cm)$^{-1}$ at 10 K, which aligns reasonably well with first-principles calculations that attribute the spin Hall effect in RhSi to the spin Berry curvature mechanism. Additionally, we demonstrate the ability to achieve a sizable spin-mixing conductance (34.7 nm$^{-2}$) and an exceptionally high interfacial spin transparency of 88$%$ in this heterostructure, underlining its potential for spin-orbit torque switching applications. Overall, this study broadens the scope of topological spintronics, emphasizing the controlled interfacial spin-transport processes and subsequent spin-to-charge conversion in a previously unexplored topological Dirac semimetal RhSi/ferromagnet heterostructure.

cond-mat.mtrl-sci

In-situ monitoring the magnetotransport signature of topological transitions in the chiral magnet Mn$_{1.4}$PtSn

Emerging magnetic fields related to the presence of topologically protected spin textures such as skyrmions are expected to give rise to additional, topology-related contributions to the Hall effect. In order to doubtlessly identify this so-called topological Hall effect, it is crucial to disentangle such contributions from the anomalous Hall effect. This necessitates a direct correlation of the transversal Hall voltage with the underlying magnetic textures. We utilize a novel measurement platform that allows to acquire high-resolution Lorentz transmission electron microscopy images of magnetic textures as a function of an external magnetic field and to concurrently measure the (anomalous) Hall voltage in-situ in the microscope on one and the same specimen. We use this approach to investigate the transport signatures of the chiral soliton lattice and antiskyrmions in Mn$_{1.4}$PtSn. Notably, the observed textures allow to fully understand the measured Hall voltage without the need of any additional contributions due to a topological Hall effect, and the field-controlled formation and annihilation of anstiskyrmions are found to have no effect on the measurend Hall voltage.

cond-mat.mes-hall

Competing anisotropies in the chiral cubic magnet Co$_8$Zn$_8$Mn$_4$ unveiled by resonant x-ray magnetic scattering

The cubic $β$-Mn-type alloy Co$_8$Zn$_8$Mn$_4$ is a chiral helimagnet that exhibits a peculiar temperature-dependent behavior in the spiral pitch, which decreases from 130 nm at room temperature to 70 nm below 20 K. Notably, this shortening is also accompanied by a structural transition of the metastable skyrmion texture, transforming from a hexagonal lattice to a square lattice of elongated skyrmions. The underlying mechanism of these transformations remain unknown, with interactions potentially involved including temperature-dependent Dzyaloshinskii-Moriya interaction, magnetocrystalline anisotropy, and exchange anisotropy. Here, x-ray resonant magnetic small-angle scattering in vectorial magnetic fields was employed to investigate the temperature dependence of the anisotropic properties of the helical phase in Co$_8$Zn$_8$Mn$_4$. Our results reveal quantitatively that the magnitude of the anisotropic exchange interaction increases by a factor of 4 on cooling from room temperature to 20 K, leading to a 5% variation in the helical pitch within the (001) plane at 20 K. While anisotropic exchange interaction contributes to the shortening of the spiral pitch, its magnitude is insufficient to explain the variation in the spiral periodicity from room to low temperatures. Finally, we demonstrate that magnetocrystalline and exchange anisotropies compete, favoring different orientations of the helical vector in the ground state.

cond-mat.mes-hall

Lateral Solid Phase Epitaxy of Yttrium Iron Garnet

Solid phase epitaxy is a crystallization technique used to produce high quality thin films. Lateral solid phase epitaxy furthermore enables the realization of non-planar structures, which are interesting, e.g., in the field of spintronics. Here, we demonstrate lateral solid phase epitaxy of yttrium iron garnet over an artificial edge, such that the crystallization direction is perpendicular to the initial seed. We use single crystalline garnet seed substrates partially covered by a SiOx film to study the lateral crystallization over the SiOx mesa. The yttrium iron garnet layer retains the crystal orientation of the substrate not only when in direct contact with the substrate, but also across the edge on top of the SiOx mesa. By controlling the crystallization dynamics it is possible to almost completely suppress the formation of polycrystals and to enable epitaxial growth of single crystalline yttrium iron garnet on top of mesas made from arbitrary materials. From a series of annealing experiments, we extract an activation energy of 3.0 eV and a velocity prefactor of $6.5 \times 10^{14}$ nm/s for the lateral epitaxial crystallization along the <100> direction. Our results pave the way to engineer single crystalline non-planar yttrium iron garnet structures with controlled crystal orientation.

cond-mat.mtrl-sci

Structural Reinforcement in Mechanically Interlocked Two-Dimensional Polymers by Suppressing Interlayer Sliding

Preserving the superior mechanical properties of monolayer two-dimensional (2D) materials when transitioning to bilayer and layer-stacked structures poses a great challenge, primarily arising from the weak van der Waals (vdW) forces that facilitate interlayer sliding and decoupling. Here, we discover that mechanically interlocked 2D polymers (2DPs) offer a means for structural reinforcement from monolayer to bilayer. Incorporating macrocyclic molecules with one and two cavities into 2DPs backbones enables the precision synthesis of mechanically interlocked monolayer (MI-M2DP) and bilayer (MI-B2DP). Intriguingly, we have observed an exceptionally high effective Young's modulus of 222.4 GPa for MI-B2DP, surpassing those of MI-M2DP (130.1 GPa), vdW-stacked MI-M2DPs (2 MI-M2DP, 8.1 GPa) and other reported multilayer 2DPs. Modeling studies demonstrate the extraordinary effectiveness of mechanically interlocked structures in minimizing interlayer sliding (~0.1 Å) and energy penalty (320 kcal/mol) in MI-B2DP compared to 2 MI-M2DP (~1.2 Å, 550 kcal/mol), thereby suppressing mechanical relaxation and resulting in prominent structural reinforcement.

physics.chem-ph

Multilayer metamaterials with mixed ferromagnetic domain core and antiferromagnetic domain wall structure

Magnetic nano-objects possess great potential for more efficient data processing, storage and neuromorphic type of applications. Using high perpendicular magnetic anisotropy synthetic antiferromagnets in the form of multilayer-based metamaterials we purposely reduce the antiferromagnetic (AF) interlayer exchange energy below the out-of-plane demagnetization energy, which controls the magnetic domain formation. As we show via macroscopic magnetometry as well as microscopic Lorentz transmission electron microscopy, in this unusual magnetic energy regime, it becomes possible to stabilize nanometer scale stripe and bubble textures consisting of ferromagnetic (FM) out-of-plane domain cores separated by AF in-plane Bloch-type domain walls. This unique coexistence of mixed FM/AF order on the nanometer scale opens so far unexplored perspectives in the architecture of magnetic domain landscapes as well as the design and functionality of individual magnetic textures, such as bubble domains with alternating chirality.

cond-mat.mtrl-sci

Probing magnetic properties at the nanoscale: In-situ Hall measurements in a TEM

We report on advanced in-situ magneto-transport measurements in a transmission electron microscope. The approach allows for concurrent magnetic imaging and high resolution structural and chemical characterization of the same sample. Proof-of-principle in-situ Hall measurements on presumably undemanding nickel thin films supported by micromagnetic simulations reveal that in samples with non-trivial structures and/or compositions, detailed knowledge of the latter is indispensable for a thorough understanding and reliable interpretation of the magneto-transport data. The proposed in-situ approach is thus expected to contribute to a better understanding of the Hall signatures in more complex magnetic textures.

cond-mat.other

Control of stripe domain wall magnetization in perpendicular anisotropy multilayers

We report on the controlled switching of domain wall (DW) magnetization in aligned stripe domain structures, stabilized in [Co (0.44 nm)/Pt (0.7 nm)]$_X$ ($X = 48$, 100, 150) multilayers with perpendicular magnetic anisotropy. The switching process, induced by an external magnetic field, is monitored by measuring the evolution of the in-plane magnetization. % We show that the remanent in-plane magnetization originates from the polarization of the Bloch-type DWs. With micromagnetic simulations, we reveal that the reversal of the DW polarization is the result of the emergence and collapse of horizontal Bloch lines within the DWs at particular strengths of the external magnetic field, applied opposite to the DW polarization. Our findings are relevant for DW-based magnonics and bubble skyrmion applications in magnetic multilayers.

physics.app-ph

Unveiling the three-dimensional spin texture of skyrmion tubes

Magnetic skyrmions are stable topological solitons with complex non-coplanar spin structures. Their nanoscopic size and the low electric currents required to initiate and control their motion has opened a new field of research, skyrmionics, that aims at using skyrmions as information carriers for data storage and manipulation. Recent advances in skyrmionics prompt for a thorough understanding of the detailed three-dimensional (3D) spin texture of a skyrmion including skyrmion-skyrmion interactions and their coupling to surfaces and interfaces. These properties crucially affect application-related aspects such as the stability and mobility of skyrmions in confined structures. To date, however, experimental techniques to measure the three-dimensional spin texture with nanometer resolution are largely missing. We therefore adapt holographic vector field electron tomography to the problem and report on the first quantitative reconstruction of the 3D spin texture of skyrmions with sub-10 nanometer resolution. The reconstructed textures reveal a variety of previously unseen local deviations from a homogeneous Bloch character within the skyrmion tubes (SkTs), details of the collapse of the skyrmion texture at surfaces, and a correlated modulation of the SkT in FeGe along their tube axes. The quantitative 3D data of the magnetic induction also allow to experimentally confirm some principles of skyrmion formation by deriving spatially resolved maps of the magnetic energy density across these magnetic solitons.

cond-mat.mtrl-sci

Topological Hall effect arising from the mesoscopic and microscopic non-coplanar magnetic structure in MnBi

The topological Hall effect (THE), induced by the Berry curvature, which originates from non-zero scalar spin chirality, is an important feature for mesoscopic topological structures, such as skyrmions. However, the THE might also arise from other microscopic non-coplanar spin structures in the lattice. Thus, the origin of the THE inevitably needs to be determined to fully understand skyrmions and find new host materials. Here, we examine the Hall effect in both bulk- and micron-sized lamellar samples of MnBi. The sample size affects the temperature and field range in which the THE is detectable. Although bulk sample exhibits the THE only upon exposure to weak fields in the easy-cone state, in thin lamella the THE exists across a wide temperature range and occurs at fields near saturation. Our results show that both the non-coplanar spin structure in the lattice and topologically non-trivial skyrmion bubbles are responsible for the THE, and that the dominant mechanism depends on the sample size. Hence, the magnetic phase diagram for MnBi is strongly size-dependent. Our study provides an example in which the THE is simultaneously induced by two mechanisms, and builds a bridge between mesoscopic and microscopic magnetic structures.

cond-mat.mes-hall

Direct Observation of Plasmon Band Formation and Delocalization in Quasi-Infinite Nanoparticle Chains

Chains of metallic nanoparticles sustain strongly confined surface plasmons with relatively low dielectric losses. To exploit these properties in applications,such as waveguides, the fabrication of long chains of low disorder and a thorough understanding of the plasmon-mode properties, such as dispersion relations, are indispensable. Here, we use a wrinkled template for directed self-assembly to assemble chains of gold nanoparticles. With this up-scalable method, chain lengths from two particles (140 nm) to 20 particles (1500 nm) and beyond can be fabricated. Electron energy-loss spectroscopy supported by boundary element simulations, finite-difference time-domain, and a simplified dipole coupling model reveal the evolution of a band of plasmonic waveguide modes from degenerated single-particle modes in detail. In striking difference from plasmonic rod-like structures, the plasmon band is confined in excitation energy, which allows light manipulations below the diffraction limit. The non-degenerated surface plasmon modes show suppressed radiative losses for efficient energy propagation over a distance of 1500 nm.

cond-mat.mes-hall

Antiferromagnetic Domain Wall Control via the Surface Spin Flop in Fully Tunable Synthetic Antiferromagnets with Perpendicular Magnetic Anisotropy

Antiferromagnetic (AF) domain walls have recently attracted revived attention, not only in the emerging field of AF spintronics, but also more specifically for offering fast domain wall velocities and dynamic excitations up to the terahertz frequency regime. Here we introduce an approach to nucleate and stabilize an AF domain wall in a synthetic antiferromagnet (SAF). We present experimental and micromagnetic studies of the magnetization reversal in [(Co/Pt)$_{X-1}$/Co/Ir]$_{N-1}$(Co/Pt)$_X$ SAFs, where interface induced perpendicular magnetic anisotropy (PMA) and AF interlayer exchange coupling (IEC) are completely controlled via the individual layer thicknesses within the multilayer stack. By combining strong PMA with even stronger AF IEC, the SAF reveals a collective response to an external magnetic field applied normal to the surface, and we stabilize the characteristic surface spin flop (SSF) state for an even number N of AF-coupled (Co/Pt)$_{X-1}$/Co multilayer blocks. In the SSF state our system provides a well-controlled and fully tunable vertical AF domain wall, easy to integrate as no single crystal substrates are required and with uniform 2D-magnetization in the film plane for further functionalization options, such as for example lateral patterning via lithography.

cond-mat.mtrl-sci

Detuning the Honeycomb of the α-RuCl3 Kitaev lattice: A case of Cr3+ dopant

Fine-tuning chemistry by doping with transition metals enables new perspectives for exploring Kitaev physics on a two-dimensional (2D) honeycomb lattice of α-RuCl3, which is promising in the field of quantum information protection and quantum computation. The key parameters to vary by doping are both Heisenberg and Kitaev components of the nearest-neighbor exchange interaction between the Jeff = 1/2 Ru3+ spins, depending strongly on the peculiarities of the crystal structure. Here, we successfully grew single crystals of the solid solution series Ru1-xCrxCl3 with Cr3+ ions coupled to the Ru3+ Kitaev host using chemical vapour transport reaction. The Cr3+ substitution preserves the honeycomb type lattice of α-RuCl3 with mixed occupancy of Ru/Cr sites, no hints on cationic order within the layers were found by single crystal X-ray diffraction and transmission electron microscopy investigations. In contrast to the high quality single crystals of α-RuCl3 with ABAB ordered layers, the ternary compounds demonstrate a significant stacking disorder along the c-axis direction evidenced by X-ray diffraction and high resolution scanning transmission electron microscopy (HR-STEM). Raman spectra of substituted samples are in line with a symmetry conservation of the parent lattice upon chromium doping. At the same time, magnetic susceptibility data indicate that the Kitaev physics of α-RuCl3 is increasingly repressed by the dominant spin-only driven magnetism of Cr3+ in Ru1-xCrxCl3.

cond-mat.str-el