arXiv subjects

Brian Skinner

Publications and source records attributed to Brian Skinner.

86 records · Page 5Linked to original sources

arXiv2012

Coulomb gap triptych in a periodic array of metal nanocrystals

The Coulomb gap in the single particle density of states (DOS) is a universal consequence of electron-electron interaction in disordered systems with localized electron states. Here we show that in arrays of monodisperse metallic nanocrystals, there is not one but three identical adjacent Coulomb gaps, which together form a structure that we call a "Coulomb gap triptych." We calculate the DOS and the conductivity in two- and three-dimensional arrays using a computer simulation. Unlike in the conventional Coulomb glass models, in nanocrystal arrays the DOS has a fixed width in the limit of large disorder. The Coulomb gap triptych can be studied via tunneling experiments.

cond-mat.mes-hall↗

arXiv2011

The problem of shot selection in basketball

In basketball, every time the offense produces a shot opportunity the player with the ball must decide whether the shot is worth taking. In this paper, I explore the question of when a team should shoot and when they should pass up the shot by considering a simple theoretical model of the shot selection process, in which the quality of shot opportunities generated by the offense is assumed to fall randomly within a uniform distribution. I derive an answer to the question "how likely must the shot be to go in before the player should take it?", and show that this "lower cutoff" for shot quality $f$ depends crucially on the number $n$ of shot opportunities remaining (say, before the shot clock expires), with larger $n$ demanding that only higher-quality shots should be taken. The function $f(n)$ is also derived in the presence of a finite turnover rate and used to predict the shooting rate of an optimal-shooting team as a function of time. This prediction is compared to observed shooting rates from the National Basketball Association (NBA), and the comparison suggests that NBA players tend to wait too long before shooting and undervalue the probability of committing a turnover.

physics.soc-ph↗

arXiv2011

The price of anarchy in basketball

Optimizing the performance of a basketball offense may be viewed as a network problem, wherein each play represents a "pathway" through which the ball and players may move from origin (the in-bounds pass) to goal (the basket). Effective field goal percentages from the resulting shot attempts can be used to characterize the efficiency of each pathway. Inspired by recent discussions of the "price of anarchy" in traffic networks, this paper makes a formal analogy between a basketball offense and a simplified traffic network. The analysis suggests that there may be a significant difference between taking the highest-percentage shot each time down the court and playing the most efficient possible game. There may also be an analogue of Braess's Paradox in basketball, such that removing a key player from a team can result in the improvement of the team's offensive efficiency.

physics.soc-ph↗

arXiv2011

Scoring Strategies for the Underdog: A general, quantitative method for determining optimal sports strategies

When facing a heavily-favored opponent, an underdog must be willing to assume greater-than-average risk. In statistical language, one would say that an underdog must be willing to adopt a strategy whose outcome has a larger-than-average variance. The difficult question is how much risk a team should be willing to accept. This is equivalent to asking how much the team should be willing to sacrifice from its mean score in order to increase the score's variance. In this paper a general, analytical method is developed for addressing this question quantitatively. Under the assumption that every play in a game is statistically independent, both the mean and the variance of a team's offensive output can be described using the binomial distribution. This description allows for direct calculations of the winning probability when a particular strategy is employed, and therefore allows one to calculate optimal offensive strategies. This paper develops this method for calculating optimal strategies exactly and then presents a simple heuristic for determining whether a given strategy should be adopted. A number of interesting and counterintuitive examples are then explored, including the merits of stalling for time, the run/pass/Hail Mary choice in American football, and the correct use of Hack-a-Shaq.

physics.soc-ph↗

arXiv2011

A model of large volumetric capacitance in graphene supercapacitors based on ion clustering

Electric double layer supercapacitors are promising devices for high-power energy storage based on the reversible absorption of ions into porous, conducting electrodes. Graphene is a particularly good candidate for the electrode material in supercapacitors due to its high conductivity and large surface area. In this paper we consider supercapacitor electrodes made from a stack of graphene sheets with randomly-inserted "spacer" molecules. We show that the large volumetric capacitances C > 100 F/cm^3 observed experimentally can be understood as a result of collective intercalation of ions into the graphene stack and the accompanying nonlinear screening by graphene electrons that renormalizes the charge of the ion clusters.

cond-mat.mes-hall↗

arXiv2011

Cooperative Charging in a Nanocrystal Assembly Gated By Ionic Liquid

In order to make a densely packed assembly of undoped semiconductor nanocrystals conductive, it is usually gated by a room temperature ionic liquid. The ionic liquid enters the pores of the super-crystal assembly under the influence of an applied voltage. We study the capacitance of such a device as a function of the gate voltage. We show that, counter-intuitively, the capacitance of the system is the sum of delta-functions located at a sequence of critical gate voltages. At each critical voltage every nanocrystal acquires one additional electron.

cond-mat.mes-hall↗

arXiv2011

Coulomb gap in the one-particle density of states in three-dimensional systems with localized electrons

The one-particle density of states (1P-DOS) in a system with localized electron states vanishes at the Fermi level due to the Coulomb interaction between electrons. Derivation of the Coulomb gap uses stability criteria of the ground state. The simplest criterion is based on the excitonic interaction of an electron and a hole and leads to a quadratic 1P-DOS in the three-dimensional (3D) case. In 3D, higher stability criteria, including two or more electrons, were predicted to exponentially deplete the 1P-DOS at energies close enough to the Fermi level. In this paper we show that there is a range of intermediate energies where this depletion is strongly compensated by the excitonic interaction between single-particle excitations, so that the crossover from quadratic to exponential behavior of the 1P-DOS is retarded. This is one of the reasons why such exponential depletion was never seen in computer simulations.

cond-mat.dis-nn↗

arXiv2011

Theory of volumetric capacitance of an electric double-layer supercapacitor

Electric double layer supercapacitors are a fast-rising class of high-power energy storage devices based on porous electrodes immersed in a concentrated electrolyte or ionic liquid. As of yet there is no microscopic theory to describe their surprisingly large capacitance per unit volume (volumetric capacitance) of ~ 100 F/cm^3, nor is there a good understanding of the fundamental limits on volumetric capacitance. In this paper we present a non-mean-field theory of the volumetric capacitance of a supercapacitor that captures the discrete nature of the ions and the exponential screening of their repulsive interaction by the electrode. We consider analytically and via Monte-Carlo simulations the case of an electrode made from a good metal and show that in this case the volumetric capacitance can reach the record values. We also study how the capacitance is reduced when the electrode is an imperfect metal characterized by some finite screening radius. Finally, we argue that a carbon electrode, despite its relatively large linear screening radius, can be approximated as a perfect metal because of its strong nonlinear screening. In this way the experimentally-measured capacitance values of ~ 100 F/cm^3 may be understood.

cond-mat.mtrl-sci↗

arXiv2010

A simple variational method for calculating energy and quantum capacitance of an electron gas with screened interactions

We describe a variational procedure for calculating the energy of an electron gas in which the long-range Coulomb interaction is truncated by the screening effect of a nearby metallic gate. We use this procedure to compute the quantum capacitance of the system as a function of electron density and spin polarization. The accuracy of the method is verified against published Monte-Carlo data. The results compare favorably with a recent experiment.

cond-mat.mes-hall↗

arXiv2010

Non-mean-field theory of anomalously large double-layer capacitance

Mean-field theories claim that the capacitance of the double-layer formed at a metal/ionic conductor interface cannot be larger than that of the Helmholtz capacitor, whose width is equal to the radius of an ion. However, in some experiments the apparent width of the double-layer capacitor is substantially smaller. We propose an alternate, non-mean-field theory of the ionic double-layer to explain such large capacitance values. Our theory allows for the binding of discrete ions to their image charges in the metal, which results in the formation of interface dipoles. We focus primarily on the case where only small cations are mobile and other ions form an oppositely-charged background. In this case, at small temperature and zero applied voltage dipoles form a correlated liquid on both contacts. We show that at small voltages the capacitance of the double-layer is determined by the transfer of dipoles from one electrode to the other and is therefore limited only by the weak dipole-dipole repulsion between bound ions, so that the capacitance is very large. At large voltages the depletion of bound ions from one of the capacitor electrodes triggers a collapse of the capacitance to the much smaller mean-field value, as seen in experimental data. We test our analytical predictions with a Monte Carlo simulation and find good agreement. We further argue that our ``one-component plasma" model should work well for strongly asymmetric ion liquids. We believe that this work also suggests an improved theory of pseudo-capacitance.

cond-mat.soft↗

arXiv2010

Anomalously large capacitance of an ionic liquid described by the restricted primitive model

We use Monte Carlo simulations to examine the simplest model of an ionic liquid, called the restricted primitive model, at a metal surface. We find that at moderately low temperatures the capacitance of the metal/ionic liquid interface is so large that the effective thickness of the electrostatic double-layer is up to 3 times smaller than the ion radius. To interpret these results we suggest an approach which is based on the interaction between discrete ions and their image charges in the metal surface and which therefore goes beyond the mean-field approximation. When a voltage is applied across the interface, the strong image attraction causes counterions to condense onto the metal surface to form compact ion-image dipoles. These dipoles repel each other to form a correlated liquid. When the surface density of these dipoles is low, the insertion of an additional dipole does not require much energy. This leads to a large capacitance $C$ that decreases monotonically with voltage $V$, producing a "bell-shaped" curve $C(V)$. We also consider what happens when the electrode is made from a semi-metal rather than a perfect metal. In this case, the finite screening radius of the electrode shifts the reflection plane for image charges to the interior of the electrode and we arrive at a "camel-shaped" $C(V)$. These predictions seem to be in qualitative agreement with experiment.

physics.chem-ph↗

arXiv2010

Capacitance of the Double Layer Formed at the Metal/Ionic-Conductor Interface: How Large Can It Be?

The capacitance of the double layer formed at a metal/ionic-conductor interface can be remarkably large, so that the apparent width of the double layer is as small as 0.3 Å. Mean-field theories fail to explain such large capacitance. We propose an alternate theory of the ionic double layer which allows for the binding of discrete ions to their image charges in the metal. We show that at small voltages the capacitance of the double layer is limited only by the weak dipole-dipole repulsion between bound ions, and is therefore very large. At large voltages the depletion of bound ions from one of the capacitor electrodes triggers a collapse of the capacitance to the mean-field value.

cond-mat.soft↗

arXiv2009

Ionic conductivity on a wetting surface

Recent experiments measuring the electrical conductivity of DNA molecules highlight the need for a theoretical model of ion transport along a charged surface. Here we present a simple theory based on the idea of unbinding of ion pairs. The strong humidity dependence of conductivity is explained by the decrease in the electrostatic self-energy of a separated pair when a layer of water (with high dielectric constant) is adsorbed to the surface. We compare our prediction for conductivity to experiment, and discuss the limits of its applicability.

cond-mat.soft↗

arXiv2009

Non-monotonic swelling of a macroion due to correlation-induced charge inversion

It is known that a large, charged body immersed in a solution of multivalent counterions may undergo charge inversion as the counterions adsorb to its surface. We use the theory of charge inversion to examine the case of a deformable, porous macroion which may adsorb multivalent ions into its bulk to form a three-dimensional strongly-correlated liquid. This adsorption may lead to non-monotonic changes in the size of the macroion as multivalent ions are added to the solution. The macroion first shrinks as its bare charge is screened and then reswells as the adsorbed ions invert the sign of the net charge. We derive a value for the outward pressure experienced by such a macroion as a function of the ion concentration in solution. We find that for small deviations in the concentration of multivalent ions away from the neutral point (where the net charge of the body is zero), the swollen size grows parabolically with the logarithm of the ratio of multivalent ion concentration to the concentration at the neutral point.

cond-mat.soft↗