arXiv subjects

C. A. Gottlieb

Publications and source records attributed to C. A. Gottlieb.

At least 19 recordsLinked to original sources

arXiv2026

ATOMIUM: Inner circumstellar envelopes of oxygen-rich AGB stars as revealed by highly excited SiO lines

Silicon monoxide (SiO) traces the physical conditions and dynamics in the circumstellar envelopes (CSEs) of AGB stars. We present high-resolution ALMA Band 6 observations of highly excited SiO emission in 14 oxygen-rich AGB stars. We cover transitions from v = 0 to v = 8, including first detections of 28SiO v = 3, 4, 8, J = 6-5, 29SiO v = 6, J = 6-5, and 30SiO v = 4, 5, J = 6-5, some of which are masers. The v = 8 transition is the highest v-state observed in an AGB star yet. Masers in v = 0 are detected clearly in V PsA and IRC+10011 and tentatively in T Mic. R Hya exhibits the richest SiO spectrum. SiO J = 6-5 absorption is seen in R Aql, R Hya, S Pav, and T Mic, with features indicative of both infalls and outflows, and tentative detection of 28SiO v = 8, J = 6-5 absorption is found towards S Pav and R Aql. Highly excited SiO emission is often distributed in arcs or clumps with velocity gradients; components in R Hya and U Her align with predicted shock fronts. Detection rates show no significant difference between low and high mass-loss rate stars, although line overlap may affect some intensities. Maser detections appear uncorrelated with pulsation period or phase. The radius enclosing 90 per cent of compact SiO emission shows a tentative correlation with mass-loss rate. These results highlight the role of mass loss and CSE geometry in shaping high-excitation SiO emission.

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arXiv2025

ATOMIUM: Continuum emission and evidence of dust enhancement from binary motion

Low- and intermediate-mass stars on the asymptotic giant branch (AGB) account for a significant portion of the dust and chemical enrichment in their host galaxy. Here we present ALMA observations of the continuum emission at 1.24 mm around a sample of 17 stars from the ATOMIUM survey. From our analysis of the stellar contributions to the continuum flux, we find that the semi-regular variables all have smaller physical radii and fainter monochromatic luminosities than the Mira variables. Comparing these properties with pulsation periods, we find a positive trend between stellar radius and period only for the Mira variables with periods above 300 days and a positive trend between the period and the monochromatic luminosity only for the red supergiants and the most extreme AGB stars with periods above 500 days. We find that the continuum emission at 1.2 mm can be classified into four groups. "Featureless" continuum emission is confined to the (unresolved) regions close to the star for five stars in our sample, relatively uniform extended flux is seen for four stars, tentative elongated features are seen for three stars, and the remaining five stars have unique or unusual morphological features in their continuum maps. These features can be explained by binary companions to 10 out of the 14 AGB stars in our sample. Based on our results we conclude that there are two modes of dust formation: well established pulsation-enhanced dust formation and our newly proposed companion-enhanced dust formation. If the companion is located close to the AGB star, in the wind acceleration region, then additional dust formed in the wake of the companion can increase the mass lost through the dust driven wind. This explains the different dust morphologies seen around our stars and partly accounts for a large scatter in literature mass-loss rates, especially among semiregular stars with small pulsation periods.

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arXiv2024

Chemical tracers of a highly eccentric AGB-main sequence star binary

Binary interactions have been proposed to explain a variety of circumstellar structures seen around evolved stars, including asymptotic giant branch (AGB) stars and planetary nebulae. Studies resolving the circumstellar envelopes of AGB stars have revealed spirals, discs and bipolar outflows, with shaping attributed to interactions with a companion. For the first time, we have used a combined chemical and dynamical analysis to reveal a highly eccentric and long-period orbit for W Aquilae, a binary system containing an AGB star and a main sequence companion. Our results are based on anisotropic SiN emission, the first detections of NS and SiC towards an S-type star, and density structures observed in the CO emission. These features are all interpreted as having formed during periastron interactions. Our astrochemistry-based method can yield stringent constraints on the orbital parameters of long-period binaries containing AGB stars, and will be applicable to other systems.

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arXiv2023

ATOMIUM: Molecular inventory of 17 oxygen-rich evolved stars observed with ALMA

The dusty winds of cool evolved stars are a major contributor of the newly synthesised material enriching the Galaxy and future generations of stars. However, the details of the physics and chemistry behind dust formation and wind launching have yet to be pinpointed. Recent spatially resolved observations show the importance of gaining a more comprehensive view of the circumstellar chemistry, but a comparative study of the intricate interplay between chemistry and physics is still difficult because observational details such as frequencies and angular resolutions are rarely comparable. Aiming to overcome these deficiencies, ATOMIUM is an ALMA Large Programme to study the physics and chemistry of the circumstellar envelopes of a diverse set of oxygen-rich evolved stars under homogeneous observing conditions at three angular resolutions between ~0.02"-1.4". Here we summarize the molecular inventory of these sources, and the correlations between stellar parameters and molecular content. Seventeen oxygen-rich or S-type asymptotic giant branch (AGB) and red supergiant (RSG) stars have been observed in several tunings with ALMA Band 6, targeting a range of molecules to probe the circumstellar envelope and especially the chemistry of dust formation close to the star. We systematically assigned the molecular carriers of the spectral lines and measured their spectroscopic parameters and the angular extent of the emission of each line from integrated intensity maps. Across the ATOMIUM sample, we detect 291 transitions of 24 different molecules and their isotopologues. This includes several first detections in oxygen-rich AGB/RSG stars: PO v=1, SO2 v1=1 and v2=2, and several high energy H2O transitions. We also find several first detections in S-type AGB stars: vibrationally excited HCN v2=2,3 and SiS v=4,5,6, as well as first detections of the molecules SiC, AlCl, and AlF in W Aql...

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arXiv2023

Rotation-tunneling spectrum and astrochemical modeling of dimethylamine, CH$_3$NHCH$_3$, and searches for it in space

Methylamine has been the only simple alkylamine detected in the interstellar medium for a long time. With the recent secure and tentative detections of vinylamine and ethylamine, respectively, dimethylamine has become a promising target for searches in space. Its rotational spectrum, however, has been known only up to 45 GHz until now. Here we investigate the rotation-tunneling spectrum of dimethylamine in selected regions between 76 and 1091 GHz using three different spectrometers in order to facilitate its detection in space. The quantum number range is extended to $J = 61$ and $K_a = 21$, yielding an extensive set of accurate spectroscopic parameters. To search for dimethylamine, we refer to the spectral line survey ReMoCA carried out with the Atacama Large Millimeter/submillimeter Array toward the high-mass star-forming region Sagittarius B2(N) and a spectral line survey of the molecular cloud G+0.693$-$0.027 employing the IRAM 30 m and Yebes 40 m radio telescopes. We report nondetections of dimethylamine toward the hot molecular cores Sgr B2(N1S) and Sgr B2(N2b) as well as G+0.693$-$0.027 which imply that dimethylamine is at least 14, 4.5 and 39 times less abundant than methylamine toward these sources, respectively. The observational results are compared to computational results from a gas-grain astrochemical model. The modeled methylamine to dimethylamine ratios are compatible with the observational lower limits. However, the model produces too much ethylamine compared with methylamine which could mean that the already fairly low levels of dimethylamine in the models may also be too high.

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arXiv2023

ATOMIUM: Probing the inner wind of evolved O-rich stars with new, highly excited H$_2$O and OH lines

Water and the hydroxyl radical are major constituents of the envelope of O-rich late-type stars. Transitions involving energy levels that are highly excited have been observed in both H$_2$O and OH. These and more recently discovered transitions can now be observed at a high sensitivity and angular resolution with the ALMA Array. Spectra and maps of H$_2$O and OH observed with an angular resolution of 20 to $\sim$200 mas were obtained at two epochs with the ALMA array. Observations with the Compact Array were also used to check for time variability of water transitions. Radiative transfer models of water were revisited to characterize masing conditions and up-to-date chemical models were used for comparison with our observations. Ten rotational transitions of H$_2$O with energies up to 9000 K were observed in various vibrational states. All but one are new detections in space, and from these we have derived accurate rest frequencies. Hyperfine split $Λ$-doubling transitions in v = 0, J = 27/2 and 29/2 levels of the $^2Π_{3/2}$ state and, $J = 33/2$ and 35/2 of the $^2Π_{1/2}$ state of OH with excitation energies up to 8900 K were also observed. Four of these transitions are new detections in space. Combining our measurements with earlier observations of OH, the v = 0 and v = 1 $Λ$-doubling frequencies have been improved. Our H$_2$O maps show compact emission and extensions up to twelve stellar radii or more. The 268.149 GHz emission line of water in the v$_2$ = 2 state is time variable, tends to be masing with dominant radiative pumping, and is widely excited. The widespread but weaker 262.898 GHz water line in v$_2$ = 1 also shows signs of maser emission. Emission and absorption of both H$_2$O and OH reveal an infall of matter and complex kinematics influenced by binarity. From our observed column densities, we derived OH/H$_2$O abundance ratios in a few stars.

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arXiv2023

The VLT/SPHERE view of the ATOMIUM cool evolved star sample. I. Overview: Sample characterization through polarization analysis

Aims. Through the ATOMIUM project, based on an ALMA large program, we aim to present a consistent view of a sample of 17 nearby cool evolved stars (Aymptotic Giant Branch and red supergiant stars). Methods. Here we present VLT/SPHERE-ZIMPOL polarimetric maps obtained in the visible of 14 out of the 17 ATOMIUM sources. They were obtained contemporaneously with the ALMA high spatial resolution data. To help interpret the polarized signal, we produced synthetic maps of light scattering by dust, through 3D radiative transfer simulations with the RADMC3D code. Results. The degree of linear polarization (DoLP) observed by ZIMPOL spreads across several optical filters. We infer that it primarily probes dust located just outside of the point spread function, and in or near the plane of the sky, with a total optical depth close to unity in the line of sight, representing only a fraction of the total circumstellar dust. The maximum DoLP ranges from 0.03-0.38 depending on the source, fractions that can be reproduced by our 3D pilot models for grains composed of common dust species. The spatial structure of the DoLP shows a diverse set of shapes. Only for three sources do we note a correlation between the ALMA CO and SiO lines, which trace the gas density, and the DoLP, which traces the dust. Conclusion. The clumpiness of the DoLP and the lack of a consistent correlation between the gas and the dust location show that, in the inner circumstellar environment (CSE), dust formation occurs at very specific sites. This has potential consequences for the derived mass-loss rates and dust-to-gas ratio in the inner region of the CSE. Except for $π^1$~Gru and perhaps GY Aql, we do not detect interactions between the circumstellar wind and the hypothesized companions that shape the wind at larger scales. This suggests that the orbits of any other companions are tilted out of the plane of the sky.

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arXiv2021

ATOMIUM: ALMA tracing the origins of molecules in dust forming oxygen rich M-type stars: Motivation, sample, calibration, and initial results

This overview paper presents ATOMIUM, a Large Programme in Cycle 6 with the Atacama Large Millimeter-submillimeter Array (ALMA). The goal of ATOMIUM is to understand the dynamics and the gas phase and dust formation chemistry in the winds of evolved asymptotic giant branch (AGB) and red supergiant (RSG) stars. A more general aim is to identify chemical processes applicable to other astrophysical environments. 17 oxygen-rich AGB and RSG stars spanning a range in (circum)stellar parameters and evolutionary phases were observed in a homogeneous observing strategy allowing for an unambiguous comparison. Data were obtained between 213.83 and 269.71 GHz at high (0.025-0.050 arcsec), medium (0.13-0.24 arcsec), and low (about 1 arcsec) angular resolution. The sensitivity per 1.3 km/s channel was 1.5-5 mJy/beam. 13 molecules were designated as primary molecules in the survey: CO, SiO, AlO, AlOH, TiO, TiO2, HCN, SO, SO2, SiS, CS, H2O, and NaCl. The scientific motivation, survey design, sample properties, data reduction, and an overview of the data products are described; and we highlight one scientific result - the wind kinematics of the ATOMIUM sources. The ATOMIUM sources often have a slow wind acceleration, and a fraction of the gas reaches a velocity which can be up to a factor of two times larger than previously reported terminal velocities assuming isotropic expansion, and the wind kinematic profiles establish that the radial velocity described by the momentum equation for a spherical wind structure cannot capture the complexity of the velocity field. In 15 sources, some molecular transitions other than 12CO v=0 J=2-1 reach a higher outflow velocity, with a spatial emission zone that is often greater than 30 stellar radii, but much less than the extent of CO. Binary interaction with a (sub)stellar companion might (partly) explain the non-monotonic behaviour of the projected velocity field.

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arXiv2021

ATOMIUM: Halide molecules around the S-type AGB star W Aquilae

S-type asymptotic giant branch (AGB) stars are thought to be intermediates in the evolution of oxygen- to carbon-rich AGB stars. The chemical compositions of their circumstellar envelopes are also intermediate, but have not been studied in as much detail as their carbon- and oxygen-rich counterparts. We aim to determine the abundances of AlCl and AlF from rotational lines, which have been observed for the first time towards an S-type AGB star, W Aql. In combination with models based on PACS observations, we aim to update our chemical kinetics network based on these results. We analyse ALMA observations towards W Aql of AlCl in the ground and first two vibrationally excited states and AlF in the ground vibrational state. Using radiative transfer models, we determine the abundances and spatial abundance distributions of Al$^{35}$Cl, Al$^{37}$Cl, and AlF. We also model HCl and HF emission and compare these models to PACS spectra to constrain the abundances of these species. AlCl is found in clumps very close to the star, with emission confined within 0.1$^{\prime\prime}$ of the star. AlF emission is more extended, with faint emission extending 0.2$^{\prime\prime}$ to 0.6$^{\prime\prime}$ from the continuum peak. We find peak abundances, relative to H$_2$, of $1.7\times 10^{-7}$ for Al$^{35}$Cl, $7\times 10^{-8}$ for Al$^{37}$Cl and $1\times 10^{-7}$ for AlF. From the PACS spectra, we find abundances of $9.7\times 10^{-8}$ and $\leq 10^{-8}$, relative to H$_2$, for HCl and HF, respectively. The AlF abundance exceeds the solar F abundance, indicating that fluorine synthesised in the AGB star has already been dredged up to the surface of the star and ejected into the circumstellar envelope. From our analysis of chemical reactions in the wind, we conclude that AlF may participate in the dust formation process, but we cannot fully explain the rapid depletion of AlCl seen in the wind.

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arXiv2021

Atomium: The astounding complexity of the near circumstellar environment of the M-type AGB star R Hydrae. I. Morpho-kinematical interpretation of CO and SiO emission

Evolved low- to intermediate-mass stars are known to shed their gaseous envelope into a large, dusty, molecule-rich circumstellar nebula which typically develops a high degree of structural complexity. Most of the large-scale, spatially correlated structures in the nebula are thought to originate from the interaction of the stellar wind with a companion. As part of the Atomium large programme, we observed the M-type asymptotic giant branch (AGB) star R Hydrae with ALMA. The morphology of the inner wind of R Hya, which has a known companion at ~3500 au, was determined from maps of CO and SiO obtained at high angular resolution. A map of the CO emission reveals a multi-layered structure consisting of a large elliptical feature at an angular scale of ~10'' that is oriented along the north-south axis. The wind morphology within the elliptical feature is dominated by two hollow bubbles. The bubbles are on opposite sides of the AGB star and lie along an axis with a position angle of ~115 deg. Both bubbles are offset from the central star, and their appearance in the SiO channel maps indicates that they might be shock waves travelling through the AGB wind. An estimate of the dynamical age of the bubbles yields an age of the order of 100 yr, which is in agreement with the previously proposed elapsed time since the star last underwent a thermal pulse. When the CO and SiO emission is examined on subarcsecond angular scales, there is evidence for an inclined, differentially rotating equatorial density enhancement, strongly suggesting the presence of a second nearby companion. The position angle of the major axis of this disc is ~70 deg in the plane of the sky. We tentatively estimate that a lower limit on the mass of the nearby companion is ~0.65 Msol on the basis of the highest measured speeds in the disc and the location of its inner rim at ~6 au from the AGB star.

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arXiv2020

Rotational spectra of vibrationally excited AlO and TiO in oxygen rich stars

Rotational transitions in vibrationally excited AlO and TiO -- two possible precursors of dust -- were observed in the 300 GHz range (1 mm wavelength) towards the oxygen rich AGB stars R Dor and IK Tau with ALMA, and vibrationally excited AlO was observed towards the red supergiant VY CMa with the SMA. The $J=11 \to 10$ transition of TiO in the $v=1~{\rm{and}}~2$ levels, and the $N = 9 \to 8$ transition in the $v=2$ level of AlO were identified towards R Dor; the $J=11 \to 10$ line of TiO was identified in the $v=1$ level towards IK Tau; and two transitions in the $v=1~{\rm{and}}~2$ levels of AlO were identified towards VY CMa. The newly-derived high vibrational temperature of TiO and AlO in R Dor of $1800 \pm 200$ K, and prior measurements of the angular extent confirm that the majority of the emission is from a region within $\lesssim2R_{\star}$ of the central star. A full radiative transfer analysis of AlO in R Dor yielded a fractional abundance of $\sim$3% of the solar abundance of Al. From a similar analysis of TiO a fractional abundance of $\sim78$% of the solar abundance of Ti was found. The observations provide indirect evidence that TiO is present in a rotating disk close to the star. Further observations in the ground and excited vibrational levels are needed to determine whether AlO, TiO, and TiO$_2$ are seeds of the Al$_2$O$_3$ dust in R Dor, and perhaps in the gravitationally bound dust shells in other AGB stars with low mass loss rates.

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arXiv2020

(Sub)stellar companions shape the winds of evolved stars

Binary interactions dominate the evolution of massive stars, but their role is less clear for low- and intermediate-mass stars. The evolution of a spherical wind from an asymptotic giant branch (AGB) star into a nonspherical planetary nebula (PN) could be due to binary interactions. We observed a sample of AGB stars with the Atacama Large Millimeter/submillimeter Array (ALMA) and found that their winds exhibit distinct nonspherical geometries with morphological similarities to planetary nebulae (PNe). We infer that the same physics shapes both AGB winds and PNe; additionally, the morphology and AGB mass-loss rate are correlated. These characteristics can be explained by binary interaction. We propose an evolutionary scenario for AGB morphologies that is consistent with observed phenomena in AGB stars and PNe.

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arXiv2020

An ALMA view of SO and SO$_2$ around oxygen-rich AGB stars

We present and analyse SO and SO$_2$, recently observed with high angular resolution and sensitivity in a spectral line survey with ALMA, for two oxygen-rich AGB stars: the low mass-loss rate R Dor and high mass-loss rate IK Tau. We analyse 8 lines of SO detected towards both stars, 78 lines of SO$_2$detected towards R Dor and 52 lines of SO$_2$ detected towards IK Tau. We detect several lines of $^{34}$SO, $^{33}$SO and $^{34}$SO$_2$ towards both stars, and tentatively S$^{18}$O towards R Dor, and hence derive isotopic ratios for these species. The spatially resolved observations show us that the two sulphur oxides are co-located towards R Dor and trace out the same wind structures in the circumstellar envelope (CSE). Much of the emission is well reproduced with a Gaussian abundance distribution spatially centred on the star. Emission from the higher energy levels of SO and SO$_2$ towards R Dor provide evidence in support of a rotating inner region of gas identified in earlier work. The new observations allow us to refine the abundance distribution of SO in IK Tau derived from prior observations with single antennas, and confirm the distribution is shell-like with the peak in the fractional abundance not centred on the star. The confirmation of different types of SO abundance distributions will help fine-tune chemical models and allows for an additional method to discriminate between low and high mass-loss rates for oxygen-rich AGB stars.

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arXiv2018

Constraints on metal oxide and metal hydroxide abundances in the winds of AGB stars - Potential detection of FeO in R Dor

Using ALMA, we observed the stellar wind of two oxygen-rich Asymptotic Giant Branch (AGB) stars, IK Tau and R Dor, between 335 and 362 GHz. One aim was to detect metal oxides and metal hydroxides (AlO, AlOH, FeO, MgO, MgOH), some of which are thought to be direct precursors of dust nucleation and growth. We report on the potential first detection of FeO (v=0, Omega=4, J=11-10) in RDor (mass-loss rate, Mdot, ~1e-7 Msun/yr). The presence of FeO in IK Tau (Mdot~5e-6 Msun/yr) cannot be confirmed due to a blend with 29SiS, a molecule that is absent in R Dor. The detection of AlO in R Dor and of AlOH in IK Tau was reported earlier by Decin et al. (2017). All other metal oxides and hydroxides, as well as MgS, remain undetected. We derive a column density N(FeO) of 1.1+/-0.9e15 cm^{-2} in R Dor, or a fractional abundance [FeO/H]~1.5e-8 accounting for non-LTE effects. The derived fractional abundance [FeO/H] is a factor ~20 larger than conventional gas-phase chemical kinetic predictions. This discrepancy may be partly accounted for by the role of vibrationally excited OH in oxidizing Fe, or may be evidence for other currently unrecognised chemical pathways producing FeO. Assuming a constant fractional abundance w.r.t. H_2, the upper limits for the other metals are [MgO/H_2] <5.5e-10 (R Dor) and <7e-11 (IK Tau), [MgOH/H_2] <9e-9 (R Dor) and <1e-9 (IK Tau), [CaO/H_2] <2.5e-9 (R Dor) and <1e-10 (IK Tau), [CaOH/H_2] <6.5e-9 (R Dor) and <9e-10 (IK Tau), and [MgS/H_$] <4.5e-10 (R Dor) and <6e-11 (IK Tau). The retrieved upper limit abundances for these latter molecules are in accord with the chemical model predictions.

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arXiv2017

The growth of carbon chains in IRC+10216 mapped with ALMA

Linear carbon chains are common in various types of astronomical molecular sources. Possible formation mechanisms involve both bottom-up and top-down routes. We have carried out a combined observational and modeling study of the formation of carbon chains in the C-star envelope IRC+10216, where the polymerization of acetylene and hydrogen cyanide induced by ultraviolet photons can drive the formation of linear carbon chains of increasing length. We have used ALMA to map the emission of 3 mm rotational lines of the hydrocarbon radicals C2H, C4H, and C6H, and the CN-containing species CN, C3N, HC3N, and HC5N with an angular resolution of 1". The spatial distribution of all these species is a hollow, 5-10" wide, spherical shell located at a radius of 10-20" from the star, with no appreciable emission close to the star. Our observations resolve the broad shell of carbon chains into thinner sub-shells which are 1-2" wide and not fully concentric, indicating that the mass loss process has been discontinuous and not fully isotropic. The radial distributions of the species mapped reveal subtle differences: while the hydrocarbon radicals have very similar radial distributions, the CN-containing species show more diverse distributions, with HC3N appearing earlier in the expansion and the radical CN extending later than the rest of the species. The observed morphology can be rationalized by a chemical model in which the growth of polyynes is mainly produced by rapid gas-phase chemical reactions of C2H and C4H radicals with unsaturated hydrocarbons, while cyanopolyynes are mainly formed from polyynes in gas-phase reactions with CN and C3N radicals.

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arXiv2016

An observational study of dust nucleation in Mira ($o$ Ceti): II. Titanium oxides are negligible for nucleation at high temperatures

The formation of silicate dust in oxygen-rich envelopes of evolved stars is thought to be initiated by formation of seed particles that can withstand the high temperatures close to the stellar photosphere and act as condensation cores farther away from the star. Candidate species considered as first condensates are TiO and TiO$_2$. We aim to identify and characterize the circumstellar gas-phase chemistry of titanium that leads to the formation of solid titanium compounds in the envelope of $o$ Cet, the prototypical Mira, and seek an observational verification of whether titanium oxides play a major role in the onset of dust formation in M-type AGB stars. We present high angular-resolution ALMA observations at submillimeter (submm) wavelengths supplemented by APEX and Herschel spectra of the rotational features of TiO and TiO$_2$. In addition, circumstellar features of TiO and TiI are identified in optical spectra which cover multiple pulsation cycles of $o$ Cet. The submm ALMA data reveal TiO and TiO$_2$ bearing gas within the extended atmosphere of Mira. While TiO is traceable up to a radius (FWHM/2) of 4.0 R$_{\star}$, TiO$_2$ extends as far as 5.5 R$_{\star}$ and unlike TiO appears to be anisotropically distributed. Optical spectra display variable emission of TiI and TiO from inner parts of the extended atmosphere (<3 R$_{\star}$). Chemical models which include shocks are in general agreement with the observations of gas-phase titanium-bearing molecules. It is unlikely that substantial amounts of titanium is locked up in solids because the abundance of the gaseous titanium species is very high. In particular, formation of hot titanium-rich condensates is very improbable because we find no traces of their hot precursor species in the gas phase. It therefore appears unlikely that the formation of dust in Mira, and possibly other M-type AGB stars, is initiated by titanium oxides.

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arXiv2016

An observational study of dust nucleation in Mira ($o$ Ceti): I. Variable features of AlO and other Al-bearing species

Context: Dust is efficiently produced by cool giant stars, but the condensation of inorganic dust is poorly understood. Aims: Identify and characterize aluminum bearing species in the circumstellar gas of Mira ($o$ Ceti) in order to elucidate their role in the production of Al$_2$O$_3$ dust. Methods: Multiepoch spectral line observations at (sub-)millimeter, far-infrared, and optical wavelengths including: maps with ALMA which probe the gas distribution in the immediate vicinity of the star at ~30 mas; observations with ALMA, APEX, and Herschel in 2013-2015 for studying cycle and inter-cycle variability of the rotational lines of Al bearing molecules; optical records as far back as 1965 to examine variations in electronic transitions over time spans of days to decades; and velocity measurements and excitation analysis of the spectral features which constrain the physical parameters of the gas. Results: Three diatomic molecules AlO, AlOH, and AlH, and atomic Al I are the main observable aluminum species in Mira, although a significant fraction of aluminum might reside in other species that have not yet been identified. Strong irregular variability in the (sub-)millimeter and optical features of AlO (possibly the direct precursor of Al$_2$O$_3$) indicates substantial changes in the excitation conditions, or varying abundance that is likely related to shocks in the star. The inhomogeneous distribution of AlO might influence the spatial and temporal characteristics of dust production. Conclusions: We are unable to quantitatively trace aluminum depletion from the gas, but the rich observational material constrains time dependent chemical networks. Future improvements should include spectroscopic characterization of higher aluminum oxides, coordinated observations of dust and gas species at different variability phases, and tools to derive abundances in shock excited gas.

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arXiv2015

A study of the C$_3$H$_2$ isomers and isotopologues: first interstellar detection of HDCCC

The partially deuterated linear isomer HDCCC of the ubiquitous cyclic carbene ($c$-C$_3$H$_2$) was observed in the starless cores TMC-1C and L1544 at 96.9 GHz, and a confirming line was observed in TMC-1 at 19.38 GHz. To aid the identification in these narrow line sources, four centimetre-wave rotational transitions (two in the previously reported $K_a =0$ ladder, and two new ones in the $K_a =1$ ladder), and 23 transitions in the millimetre band between 96 and 272 GHz were measured in high-resolution laboratory spectra. Nine spectroscopic constants in a standard asymmetric top Hamiltonian allow the principal transitions of astronomical interest in the $K_a \le 3$ rotational ladders to be calculated to within 0.1 km s$^{-1}$ in radial velocity up to 400 GHz. Conclusive evidence for the identification of the two astronomical lines of HDCCC was provided by the $V_{\rm{LSR}}$ which is the same as that of the normal isotopic species (H$_2$CCC) in the three narrow line sources. In these sources, deuterium fractionation in singly substituted H$_2$CCC (HDCCC/H$_2$CCC $\sim4\%\text{-}19\%$) is comparable to that in $c$-C$_3$H$_2$ ($c$-C$_3$H$_2$/$c$-C$_3$HD $\sim5\%\text{-}17\%$), and similarly in doubly deuterated $c$-C$_3$H$_2$ ($c$-C$_3$D$_2$/$c$-C$_3$HD $\sim3\%\text{-}17\%$), implying that the efficiency of the deuteration processes in the H$_2$CCC and $c$-C$_3$H$_2$ isomers are comparable in dark clouds.

astro-ph.GA↗