arXiv subjects

C. A. Gottlieb

Publications and source records attributed to C. A. Gottlieb.

28 records · Page 2Linked to original sources

arXiv2015

Discovery of SiCSi in IRC+10216: A missing link between gas and dust carriers of SiC bonds

We report the discovery in space of a disilicon species, SiCSi, from observations between 80 and 350 GHz with the IRAM 30m radio telescope. Owing to the close coordination between laboratory experiments and astrophysics, 112 lines have now been detected in the carbon-rich star CWLeo. The derived frequencies yield improved rotational and centrifugal distortion constants up to sixth order. From the line profiles and interferometric maps with the Submillimeter Array, the bulk of the SiCSi emis- sion arises from a region of 6 arcseconds in radius. The derived abundance is comparable to that of SiC2. As expected from chemical equilibrium calculations, SiCSi and SiC2 are the most abundant species harboring a SiC bond in the dust formation zone and certainly both play a key role in the formation of SiC dust grains.

astro-ph.GA↗

arXiv2015

Vibrationally Excited C$_4$H

Rotational spectra in four new excited vibrational levels of the linear carbon chain radical C$_4$H radical were observed in the millimeter band between 69 and 364 GHz in a low pressure glow discharge, and two of these were observed in a supersonic molecular beam between 19 and 38 GHz. All have rotational constants within 0.4% of the $^2Σ^+$ ground vibrational state of C$_4$H and were assigned to new bending vibrational levels, two each with $^2Σ$ and $^2Π$ vibrational symmetry. The new levels are tentatively assigned to the $1ν_6$ and $1ν_5$ bending vibrational modes (both with $^2Π$ symmetry), and the $1ν_6 + 1ν_7$ and $1ν_5 + 1ν_6$ combination levels ($^2Σ$ symmetry) on the basis of the derived spectroscopic constants, relative intensities in our discharge source, and published laser spectroscopic and quantum calculations. Prior spectroscopic constants in the $1ν_7$ and $2ν_7$ levels were refined. Also presented are interferometric maps of the ground state and the $1ν_7$ level obtained with the SMA near 257 GHz which show that C$_4$H is present near the central star in IRC+10216. We found no evidence with the SMA for the new vibrationally excited levels of C$_4$H at a peak flux density averaged over a $3^{\prime\prime}$ synthesized beam of $\ge 0.15$ Jy/beam in the 294-296 and 304-306 GHz range, but it is anticipated that rotational lines in the new levels might be observed in IRC+10216 when ALMA attains its full design capability.

astro-ph.SR↗

arXiv2013

An Interferometric Spectral-Line and Imaging Survey of VY Canis Majoris in the 345 GHz Band

A spectral line survey of the oxygen-rich red supergiant VY Canis Majoris was made between 279 and 355 GHz with the Submillimeter Array. Two hundred twenty three spectral features from 19 molecules (not counting isotopic species of some of them) were observed, including the rotational spectra of TiO, TiO2, and AlCl for the first time in this source. The parameters and an atlas of all spectral features is presented. Observations of each line with a synthesized beam of ~0.9 arcsec, reveal the complex kinematics and morphology of the nebula surrounding VY CMa. Many of the molecules are observed in high lying rotational levels or in excited vibrational levels. From these, it was established that the main source of the submillimeter-wave continuum (dust) and the high excitation molecular gas (the star) are separated by about 0.15 arcsec. Apparent coincidences between the molecular gas observed with the SMA, and some of the arcs and knots observed at infrared wavelengths and in the optical scattered light by the Hubble Space Telescope are identified. The observations presented here provide important constraints on the molecular chemistry in oxygen-dominated circumstellar environments and a deeper picture of the complex circumstellar environment of VY CMa.

astro-ph.SR↗

arXiv2013

PO and PN in the wind of the oxygen-rich AGB star IK Tau

Phosphorus-bearing compounds have only been studied in the circumstellar environments (CSEs) of the asymptotic giant branch (AGB) star IRC +10216 and the protoplanetary nebula CRL 2688, both C-rich objects, and the O-rich red supergiant VY CMa. The current chemical models cannot reproduce the high abundances of PO and PN derived from observations of VY CMa. No observations have been reported of phosphorus in the CSEs of O-rich AGB stars. We aim to set observational constraints on the phosphorous chemistry in the CSEs of O-rich AGB stars, by focussing on the Mira-type variable star IK Tau. Using the IRAM 30m telescope and the Submillimeter Array (SMA), we observed four rotational transitions of PN (J=2-1,3-2,6-5,7-6) and four of PO (J=5/2-3/2,7/2-5/2,13/2-11/2,15/2-13/2). The IRAM 30m observations were dedicated line observations, while the SMA data come from an unbiased spectral survey in the frequency range 279-355 GHz. We present the first detections of PN and PO in an O-rich AGB star and estimate abundances X(PN/H2) of about 3x10^-7 and X(PO/H2) in the range 0.5-6.0x10^-7. This is several orders of magnitude higher than what is found for the C-rich AGB star IRC +10216. The diameter (<=0.7") of the PN and PO emission distributions measured in the interferometric data corresponds to a maximum radial extent of about 40 stellar radii. The abundances and the spatial occurrence of the molecules are in very good agreement with the results reported for VY CMa. We did not detect PS or PH3 in the survey. We suggest that PN and PO are the main carriers of phosphorus in the gas phase, with abundances possibly up to several 10^-7. The current chemical models cannot account for this, underlining the strong need for updated chemical models that include phosphorous compounds.

astro-ph.SR↗

arXiv2013

Dust-forming molecules in VY Canis Majoris (and Betelgeuse)

The formation of inorganic dust in circumstellar environments of evolved stars is poorly understood. Spectra of molecules thought to be most important for the nucleation, i.e. AlO, TiO, and TiO2, have been recently detected in the red supergiant VY CMa. These molecules are effectively formed in VY CMa and the observations suggest that non-equilibrium chemistry must be involved in their formation and nucleation into dust. In addition to exploring the recent observations of VY CMa, we briefly discuss the possibility of detecting these molecules in the dust-poor circumstellar environment of Betelgeuse.

astro-ph.SR↗

arXiv2013

Pure rotational spectra of TiO and TiO_2 in VY Canis Majoris

We report the first detection of pure rotational transitions of TiO and TiO_2 at (sub-)millimeter wavelengths towards the red supergiant VY CMa. A rotational temperature, T_rot, of about 250 K was derived for TiO_2. Although T_rot was not well constrained for TiO, it is likely somewhat higher than that of TiO_2. The detection of the Ti oxides confirms that they are formed in the circumstellar envelopes of cool oxygen-rich stars and may be the "seeds" of inorganic-dust formation, but alternative explanations for our observation of TiO and TiO_2 in the cooler regions of the envelope cannot be ruled out at this time. The observations suggest that a significant fraction of the oxides is not converted to dust, but instead remains in the gas phase throughout the outflow.

astro-ph.SR↗

arXiv2010

Astronomical identification of CN-, the smallest observed molecular anion

We present the first astronomical detection of a diatomic negative ion, the cyanide anion CN-, as well as quantum mechanical calculations of the excitation of this anion through collisions with para-H2. CN- is identified through the observation of the J = 2-1 and J = 3-2 rotational transitions in the C-star envelope IRC +10216 with the IRAM 30-m telescope. The U-shaped line profiles indicate that CN-, like the large anion C6H-, is formed in the outer regions of the envelope. Chemical and excitation model calculations suggest that this species forms from the reaction of large carbon anions with N atoms, rather than from the radiative attachment of an electron to CN, as is the case for large molecular anions. The unexpectedly large abundance derived for CN-, 0.25 % relative to CN, makes likely its detection in other astronomical sources. A parallel search for the small anion C2H- remains so far unconclusive, despite the previous tentative identification of the J = 1-0 rotational transition. The abundance of C2H- in IRC +10216 is found to be vanishingly small, < 0.0014 % relative to C2H.

astro-ph.GA↗

arXiv2005

Rotational Spectroscopy of PAHs: Acenaphthene, Acenaphthylene and Fluorene

Pure rotational spectra of three polycyclic aromatic hydrocarbons - acenaphthene, acenaphthylene and fluorene - have been obtained by Fourier transform microwave spectroscopy of a molecular beam and subsequently by millimeter wave absorption spectroscopy for acenaphthene and fluorene. The data presented here will be useful for deep radio astronomical searches for PAHs employing large radio telecopes.

astro-ph↗

arXiv1997

Detection of HC11N in the Cold Dust Cloud TMC-1

Two consecutive rotational transitions of the long cyanopolyyne HC11N, J=39-38, and J=38-37, have been detected in the cold dust cloud TMC-1 at the frequencies expected from recent laboratory measurements by Travers et al. (1996), and at about the expected intensities. The astronomical lines have a mean radial velocity of 5.8(1) km/s, in good agreement with the shorter cyanopolyynes HC7N and HC9N observed in this very sharp-lined source [5.82(5) and 5.83(5) km/s, respectively]. The column density of HC11N is calculated to be 2.8x10^(11) cm^(-2). The abundance of the cyanopolyynes decreases smoothly with length to HC11N, the decrement from one to the next being about 6 for the longer carbon chains.

astro-ph↗

arXiv1997

First Astronomical Detection of the Cumulene Carbon Chain Molecule H_2C_6 in TMC1

The cumulene carbenes are important components of hydrocarbon chemistry in low mass star forming cores. Here we report the first astronomical detection of the long chain cumulene carbene H_2C_6 in the interstellar cloud TMC1, from observations of two of its rotational transitions: $J_{K,K'} = 7_{1,7} \rightarrow 6_{1,6}$ at 18.8 GHz and $8_{1,8} \rightarrow 7_{1,7}$ at 21.5 GHz, using NASA's Deep Space Network 70 m antenna at Goldstone, California. In addition we also observed the shorter cumulene carbene, H_2C_4 at the same position. The fractional abundance of H_2C_6 relative to H_2 is about $4.7 \times 10^{-11}$ and H_2C_4 is about $1.1 \times 10^{-9}$. The abundance of H_2C_6 is in fairly good agreement with gas phase chemical models for young molecular cloud cores, but the abundance of H_2C_4 is significantly larger than predicted.

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