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C. Favre

Publications and source records attributed to C. Favre.

At least 37 records · Page 2Linked to original sources

ALMA polarimetric studies of rotating jet/disk systems

We have recently obtained polarimetric data at mm wavelengths with ALMA for the young systems DG Tau and CW Tau, for which the rotation properties of jet and disk have been investigated in previous high angular resolution studies. The motivation was to test the models of magneto-centrifugal launch of jets via the determination of the magnetic configuration at the disk surface. The analysis of these data, however, reveals that self-scattering of dust thermal radiation dominates the polarization pattern. It is shown that even if no information on the magnetic field can be derived in this case, the polarization data are a powerful tool for the diagnostics of the properties and the evolution of dust in protoplanetary disks.

astro-ph.SR↗

First Hot Corino detected around an Isolated Intermediate-Mass Protostar: Cep\,E-mm

Intermediate-mass (IM) protostars provide a bridge between the low- and high-mass protostars. Despite their relevance, little is known about their chemical diversity. We want to investigate the molecular richness towards the envelope of IM protostars and to compare their properties with other sources. We have selected the isolated IM Class 0 protostar CepE-mm to carry out an unbiased molecular survey with the IRAM 30m telescope between 72 and 350 GHz with an angular resolution lying in the range 7-34". These data were complemented with NOEMA observations of the spectral bands 85.9 - 89.6 GHz and 216.8 - 220.4 GHz at an angular resolution of 2.3 and 1.4", respectively. 30m spectra show bright emission of O- and N-bearing COMs. We identify three components in the spectral signature: an extremely broad line component associated with the outflowing gas, a narrow line component associated with the cold envelope, and a broad line component tracing the hot corino. NOEMA observations reveal CepE-mm as a binary protostellar system CepE-A and B, separated by 1.7". CepE-A dominates the core continuum emission and powers the high-velocity jet associated with HH377. Our interferometric maps show that COMs arises from a region of 0.7" size around CepE-A. Rotational temperatures were found to lie in the range 20-40 K with column densities ranging from a few 10^15 cm-2 for O-bearing species, down to a few 10^14 cm-2 for N-bearing species. Molecular abundances are similar to those measured towards other low- and intermediate-mass protostars. High-mass hot cores are significantly less abundant in methanol and N-bearing species are more abundant by 3 orders of magnitude.CepE-mm reveals itself as a binary protostellar system with a strong chemical differentiation. The brightest component of the binary is associated with a hot corino. Its properties are similar to those of low-mass hot corinos.

astro-ph.SR↗

Chemistry in disks. XI. Sulfur-bearing species as tracers of protoplanetary disk physics and chemistry: the DM Tau case

Context. Several sulfur-bearing molecules are observed in the interstellar medium and in comets, in strong contrast to protoplanetary disks where only CS, H$_2$CS and SO have been detected so far. Aims. We combine observations and chemical models to constrain the sulfur abundances and their sensitivity to physical and chemical conditions in the DM Tau protoplanetary disk. Methods. We obtained $0.5^{"}$ ALMA observations of DM Tau in Bands 4 and 6 in lines of CS, SO, SO$_2$, OCS, CCS, H$_2$CS and H$_2$S, achieving a $\sim 5$ mJy sensitivity. Using the non-LTE radiative transfer code RADEX and the forward-modeling tool DiskFit, disk-averaged CS column densities and upper limits for the other species were derived. Results. Only CS was detected with a derived column density of $\sim 2-6 \times 10^{12}$ cm$^{-2}$. We report a first tentative detection of SO$_2$ in DM Tau. The upper limits range between $\sim 10^{11}$ and $10^{14}$ cm$^{-2}$ for the other S-bearing species. The best-fit chemical model matching these values requires a gas-phase C/O ratio of > 1 at $r \sim 50-100$ au. With chemical modeling we demonstrate that sulfur-bearing species could be robust tracers of the gas-phase C/O ratio, surface reaction rates, grain size and UV intensities. Conclusions. The lack of detections of a variety of sulfur-bearing molecules in DM Tau other than CS implies a dearth of reactive sulfur in the gas phase, either through efficient freeze-out or because most of the elemental sulfur is in other large species, as found in comets. The inferred high CS/SO and CS/SO$_2$ ratios require a non-solar C/O gas-phase ratio of > 1, consistent with the recent observations of hydrocarbon rings in DM Tau. The stronger depletion of oxygen-bearing S-species compared to CS is likely linked to the low observed abundances of gaseous water in DM Tau and points to a removal mechanism of oxygen from the gas.

astro-ph.GA↗

SOLIS IV. Hydrocarbons in the OMC-2 FIR 4 region, a probe of energetic particle irradiation of the region

We report new interferometric images of cyclopropenylidene, c-C$_3$H$_2$, towards the young protocluster OMC-2 FIR\,4. The observations were performed at 82 and 85 GHz with the NOrthern Extended Millimeter Array (NOEMA) as part of the project Seeds Of Life In Space (SOLIS). In addition, IRAM-30m data observations were used to investigate the physical structure of OMC-2 FIR\,4. We find that the c-C$_3$H$_2$ gas emits from the same region where previous SOLIS observations showed bright HC$_5$N emission. From a non-LTE analysis of the IRAM-30m data, the c-C$_3$H$_2$ gas has an average temperature of $\sim$40K, a H$_2$ density of $\sim$3$\times$10$^{5}$~cm$^{-3}$, and a c-C$_3$H$_2$ abundance relative to H$_2$ of ($7\pm1$)$\times$10$^{-12}$. In addition, the NOEMA observations provide no sign of significant c-C$_3$H$_2$ excitation temperature gradients across the region (about 3-4 beams), with T$_{ex}$ in the range 8$\pm$3 up to 16$\pm$7K. We thus infer that our observations are inconsistent with a physical interaction of the OMC-2 FIR\,4 envelope with the outflow arising from OMC-2 FIR\,3, as claimed by previous studies. The comparison of the measured c-C$_3$H$_2$ abundance with the predictions from an astrochemical PDR model indicates that OMC-2 FIR\,4 is irradiated by a FUV field $\sim$1000 times larger than the interstellar one, and by a flux of ionising particles $\sim$4000 times larger than the canonical value of $1\times10^{-17}$~s$^{-1}$ from the Galaxy cosmic rays, which is consistent with our previous HC$_5$N observations. This provides an important and independent confirmation of other studies that one or more sources inside the OMC-2 FIR\,4 region emit energetic ($\geq10$~MeV) particles.

astro-ph.GA↗

Astrochemical evolution along star formation: Overview of the IRAM Large Program ASAI

Evidence is mounting that the small bodies of our Solar System, such as comets and asteroids, have at least partially inherited their chemical composition from the first phases of the Solar System formation. It then appears that the molecular complexity of these small bodies is most likely related to the earliest stages of star formation. It is therefore important to characterize and to understand how the chemical evolution changes with solar-type protostellar evolution. We present here the Large Program "Astrochemical Surveys At IRAM" (ASAI). Its goal is to carry out unbiased millimeter line surveys between 80 and 272 GHz of a sample of ten template sources, which fully cover the first stages of the formation process of solar-type stars, from prestellar cores to the late protostellar phase. In this article, we present an overview of the surveys and results obtained from the analysis of the 3 mm band observations. The number of detected main isotopic species barely varies with the evolutionary stage and is found to be very similar to that of massive star-forming regions. The molecular content in O- and C- bearing species allows us to define two chemical classes of envelopes, whose composition is dominated by either a) a rich content in O-rich complex organic molecules, associated with hot corino sources, or b) a rich content in hydrocarbons, typical of Warm Carbon Chain Chemistry sources. Overall, a high chemical richness is found to be present already in the initial phases of solar-type star formation.

astro-ph.GA↗

Probing midplane CO abundance and gas temperature with DCO$^+$ in the protoplanetary disk around HD 169142

This work aims to understand which midplane conditions are probed by the DCO$^+$ emission in the disk around the Herbig Ae star HD 169142. We explore the sensitivity of the DCO$^+$ formation pathways to the gas temperature and the CO abundance. The DCO$^+$ $J$=3-2 transition was observed with ALMA at a spatial resolution of 0.3". The HD 169142 DCO$^+$ radial intensity profile reveals a warm, inner component at radii <30 AU and a broad, ring-like structure from ~50-230 AU with a peak at 100 AU just beyond the millimeter grain edge. We modeled DCO$^+$ emission in HD 169142 with a physical disk structure adapted from the literature, and employed a simple deuterium chemical network to investigate the formation of DCO$^+$ through the cold deuterium fractionation pathway via H$_2$D$^+$. Contributions from the warm deuterium fractionation pathway via CH$_2$D$^+$ are approximated using a constant abundance in the intermediate disk layers. Parameterized models show that alterations to the midplane gas temperature and CO abundance of the literature model are both needed to recover the observed DCO$^+$ radial intensity profile. The best-fit model contains a shadowed, cold midplane in the region z/r < 0.1 with an 8 K decrease in gas temperature and a factor of five CO depletion just beyond the millimeter grain edge, and a 2 K decrease in gas temperature for r > 120 AU. The warm deuterium fractionation pathway is implemented as a constant DCO$^+$ abundance of 2.0$\times$10$^{-12}$ between 30-70 K. The DCO$^+$ emission probes a reservoir of cold material in the HD 169142 outer disk that is not revealed by the millimeter continuum, the SED, nor the emission from the 12CO, 13CO, or C18O $J$=2-1 lines.

astro-ph.SR↗

Nitrogen oxide in protostellar envelopes and shocks: the ASAI survey

The high-sensitivity of the IRAM 30-m ASAI unbiased spectral survey in the mm-window allows us to detect NO emission towards both the Class I object SVS13-A and the protostellar outflow shock L1157-B1. We detect the hyperfine components of the $^2Π_{\rm 1/2}$ $J$ = 3/2 $\to$ 1/2 (at 151 GHz) and the $^2Π_{\rm 1/2}$ $J$ = 5/2 $\to$ 3/2 (250 GHz) spectral pattern. The two objects show different NO profiles: (i) SVS13-A emits through narrow (1.5 km s$^{-1}$) lines at the systemic velocity, while (ii) L1157-B1 shows broad ($\sim$ 5 km s$^{-1}$) blue-shifted emission. For SVS13-A the analysis leads to $T_{\rm ex}$ $\geq$ 4 K, $N(\rm NO)$ $\leq$ 3 $\times$ 10$^{15}$ cm$^{-2}$, and indicates the association of NO with the protostellar envelope. In L1157-B1, NO is tracing the extended outflow cavity: $T_{\rm ex}$ $\simeq$ 4--5 K, and $N(\rm NO)$ = 5.5$\pm$1.5 $\times$ 10$^{15}$ cm$^{-2}$. Using C$^{18}$O, $^{13}$C$^{18}$O, C$^{17}$O, and $^{13}$C$^{17}$O ASAI observations we derive an NO fractional abundance less than $\sim$ 10$^{-7}$ for the SVS13-A envelope, in agreement with previous measurements towards extended PDRs and prestellar objects. Conversely, a definite $X(NO)$ enhancement is measured towards L1157-B1, $\sim$ 6 $\times$ 10$^{-6}$, showing that the NO production increases in shocks. The public code UCLCHEM was used to interpret the NO observations, confirming that the abundance observed in SVS13-A can be attained in an envelope with a gas density of 10$^5$ cm$^{-3}$ and a kinetic temperature of 40 K. The NO abundance in L1157-B1 is reproduced with pre-shock densities of 10$^5$ cm$^{-3}$ subjected to a $\sim$ 45 km s$^{-1}$ shock.

astro-ph.GA↗

Seeds Of Life In Space (SOLIS): The organic composition diversity at 300--1000 au scale in Solar-type star forming regions

Complex organic molecules have been observed for decades in the interstellar medium. Some of them might be considered as small bricks of the macromolecules at the base of terrestrial life. It is hence particularly important to understand organic chemistry in Solar-like star forming regions. In this article, we present a new observational project: SOLIS (Seeds Of Life In Space). This is a Large Project at the IRAM-NOEMA interferometer, and its scope is to image the emission of several crucial organic molecules in a sample of Solar-like star forming regions in different evolutionary stage and environments. Here, we report the first SOLIS results, obtained from analysing the spectra of different regions of the Class 0 source NGC1333-IRAS4A, the protocluster OMC-2 FIR4, and the shock site L1157-B1. The different regions were identified based on the images of formamide (NH2CHO) and cyanodiacetylene (HC5N) lines. We discuss the observed large diversity in the molecular and organic content, both on large (3000-10000 au) and relatively small (300-1000 au) scales. Finally, we derive upper limits to the methoxy fractional abundance in the three observed regions of the same order of magnitude of that measured in few cold prestellar objects, namely ~10^-12-10^-11 with respect to H2 molecules.

astro-ph.SR↗

The onset of energetic particle irradiation in Class 0 protostars

The early stages of low-mass star formation are likely to be subject to intense ionization by protostellar energetic MeV particles. As a result, the surrounding gas is enriched in molecular ions, such as HCO$^{+}$ and N$_{2}$H$^{+}$. Nonetheless, this phenomenon remains poorly understood for Class 0 objects. Recently, based on Herschel observations taken as part of the key program Chemical HErschel Surveys of Star forming regions (CHESS), a very low HCO$^{+}$/N$_{2}$H$^{+}$ abundance ratio of about 3-4, has been reported toward the protocluster OMC-2 FIR4. This finding suggests a cosmic-ray ionization rate in excess of 10$^{-14}$ s$^{-1}$, much higher than the canonical value of $ζ$ = 3$\times$10$^{-17}$ s$^{-1}$ (value expected in quiescent dense clouds). To assess the specificity of OMC-2 FIR4, we have extended this study to a sample of sources in low- and intermediate mass. More specifically, we seek to measure the HCO$^{+}$/N$_2$H$^{+}$ abundance ratio from high energy lines (J $\ge$ 6) toward this source sample in order to infer the flux of energetic particles in the warm and dense gas surrounding the protostars. We use observations performed with the Heterodyne Instrument for the FarInfrared spectrometer on board the Herschel Space Observatory toward a sample of 9 protostars. We report HCO$^{+}$/N$_2$H$^{+}$ abundance ratios in the range of 5 up to 73 toward our source sample. The large error bars do not allow us to conclude whether OMC-2~FIR4 is a peculiar source. Nonetheless, an important result is that the measured HCO$^{+}$/N$_2$H$^{+}$ ratio does not vary with the source luminosity. At the present time, OMC-2 FIR4 remains the only source where a high flux of energetic particles is clearly evident. More sensitive and higher angular resolution observations are required to further investigate this process.

astro-ph.GA↗

Seeds of Life in Space (SOLIS) III. Formamide in protostellar shocks: evidence for gas-phase formation

Context: Modern versions of the Miller-Urey experiment claim that formamide (NH$_2$CHO) could be the starting point for the formation of metabolic and genetic macromolecules. Intriguingly, formamide is indeed observed in regions forming Solar-type stars as well as in external galaxies. Aims: How NH$_2$CHO is formed has been a puzzle for decades: our goal is to contribute to the hotly debated question of whether formamide is mostly formed via gas-phase or grain surface chemistry. Methods: We used the NOEMA interferometer to image NH$_2$CHO towards the L1157-B1 blue-shifted shock, a well known interstellar laboratory, to study how the components of dust mantles and cores released into the gas phase triggers the formation of formamide. Results: We report the first spatially resolved image (size $\sim$ 9", $\sim$ 2300 AU) of formamide emission in a shocked region around a Sun-like protostar: the line profiles are blueshifted and have a FWHM $\simeq$ 5 km s$^{-1}$. A column density of $N_{\rm NH_2CHO}$ = 8 $\times$ 10$^{12}$ cm$^{-1}$, and an abundance (with respect to H-nuclei) of 4 $\times$ 10$^{-9}$ are derived. We show a spatial segregation of formamide with respect to other organic species. Our observations, coupled with a chemical modelling analysis, indicate that the formamide observed in L1157-B1 is formed by gas-phase chemical process, and not on grain surfaces as previously suggested. Conclusions: The SOLIS interferometric observations of formamide provide direct evidence that this potentially crucial brick of life is efficiently formed in the gas-phase around Sun-like protostars.

astro-ph.EP↗

SOLIS II. Carbon-chain growth in the Solar-type protocluster OMC2-FIR4

The interstellar delivery of carbon atoms locked into molecules might be one of the key ingredients for the emergence of life. Cyanopolyynes are carbon chains delimited at their two extremities by an atom of hydrogen and a cyano group, so that they might be excellent reservoirs of carbon. The simplest member, HC3N, is ubiquitous in the galactic interstellar medium and found also in external galaxies. Thus, understanding the growth of cyanopolyynes in regions forming stars similar to our Sun, and what affects it, is particularly relevant. In the framework of the IRAM/NOEMA Large Program SOLIS (Seeds Of Life In Space), we have obtained a map of two cyanopolyynes, HC3N and HC5N, in the protocluster OMC2-FIR4. Because our Sun is thought to be born in a rich cluster, OMC2-FIR4 is one of the closest and best known representatives of the environment in which the Sun may have been born. We find a HC3N/HC5N abundance ratio across the source in the range ~ 1 - 30, with the smallest values (< 10) in FIR5 and in the Eastern region of FIR4. The ratios < 10 can be reproduced by chemical models only if: (1) the cosmic-ray ionisation rate $ζ$ is ~ $4 \times 10^{-14}$ s$^{-1}$; (2) the gaseous elemental ratio C/O is close to unity; (3) O and C are largely depleted. The large $ζ$ is comparable to that measured in FIR4 by previous works and was interpreted as due to a flux of energetic (> 10 MeV) particles from embedded sources. We suggest that these sources could lie East of FIR4 and FIR5. A temperature gradient across FIR4, with T decreasing by about 10 K, could also explain the observed change in the HC3N/HC5N line ratio, without the need of a cosmic ray ionisation rate gradient. However, even in this case, a high constant cosmic-ray ionisation rate (of the order of $10^{-14}$ s$^{-1}$) is necessary to reproduce the observations.

astro-ph.GA↗

L1157-B1, a factory of complex organic molecules in a Solar-type star forming region

We report on a systematic search for oxygen-bearing Complex Organic Molecules (COMs) in the Solar-like protostellar shock region L1157-B1, as part of the IRAM Large Program "Astrochemical Surveys At IRAM" (ASAI). Several COMs are unambiguously detected, some for the first time, such as ketene H$_2$CCO, dimethyl ether (CH$_3$OCH$_3$) and glycolaldehyde (HCOCH$_2$OH), and others firmly confirmed, such as formic acid (HCOOH) and ethanol (C$_2$H$_5$OH). Thanks to the high sensitivity of the observations and full coverage of the 1, 2 and 3mm wavelength bands, we detected numerous (10--125) lines from each of the detected species. Based on a simple rotational diagram analysis, we derive the excitation conditions and the column densities of the detected COMs. Combining our new results with those previously obtained towards other protostellar objects, we found a good correlation between ethanol, methanol and glycolaldehyde. We discuss the implications of these results on the possible formation routes of ethanol and glycolaldehyde.

astro-ph.GA↗

The ALMA-PILS survey: First detections of ethylene oxide, acetone and propanal toward the low-mass protostar IRAS 16293-2422

One of the open questions in astrochemistry is how complex organic and prebiotic molecules are formed. Aims. Our aim is to start the process of compiling an inventory of oxygen-bearing complex organic molecules toward the solar-type Class 0 protostellar binary IRAS16293-2422 from an unbiased spectral survey with ALMA (PILS). Here we focus on the new detections of ethylene oxide (c-C$_2$H$_4$O), acetone (CH$_3$COCH$_3$), and propanal (C$_2$H$_5$CHO). Methods. With ALMA, we surveyed the spectral range from 329 to 363 GHz at 0.5$"$ (60 AU diameter) resolution. Using a simple model for the molecular emission in LTE, the excitation temperatures and column densities of each species were constrained. Results. We successfully detect propanal (44 lines), ethylene oxide (20 lines) and acetone (186 lines) toward one component of the protostellar binary, IRAS16293B. The high resolution maps demonstrate that the emission for all investigated species originates from the compact central region close to the protostar. This, along with a derived common excitation temperature of $\sim$ 125 K, is consistent with a coexistence of these molecules in the same gas. Conclusions. The observations mark the first detections of acetone, propanal and ethylene oxide toward a low-mass protostar. The relative abundance ratios of the two sets of isomers (CH$_3$COCH$_3$/C$_2$H$_5$CHO $\sim$ 8 and CH$_3$CHO/c-C$_2$H$_4$O $\sim$ 12) are comparable to previous observations toward high-mass protostars. The majority of observed abundance ratios from these results as well as those measured toward high-mass protostars are up to an order of magnitude above the predictions from chemical models. This may reflect either missing reactions or uncertain rates in the chemical networks. The physical conditions, such as temperatures or densities, used in the models, may not be applicable to solar-type protostars either.

astro-ph.SR↗

The ALMA Protostellar Interferometric Line Survey (PILS): First results from an unbiased submillimeter wavelength line survey of the Class 0 protostellar binary IRAS 16293-2422 with ALMA

The inner regions of the envelopes surrounding young protostars are characterised by a complex chemistry, with prebiotic molecules present on the scales where protoplanetary disks eventually may form. This paper introduces a systematic survey, "Protostellar Interferometric Line Survey (PILS)" of the Class 0 protostellar binary IRAS 16293-2422 using the Atacama Large Millimeter/submillimeter Array (ALMA). The survey covers the full frequency range from 329 to 363 GHz (0.8 mm) with additional targeted observations at 3.0 and 1.3 mm. More than 10,000 features are detected toward one component in the protostellar binary. Glycolaldehyde, its isomers, methyl formate and acetic acid, and its reduced alcohol, ethylene glycol, are clearly detected. For ethylene glycol both lowest state conformers, aGg' and gGg', are detected, the latter for the first time in the ISM. The abundance of glycolaldehyde is comparable to or slightly larger than that of ethylene glycol. In comparison to the Galactic Center, these two species are over-abundant relative to methanol, possibly an indication of formation at low temperatures in CO-rich ices. Both 13C and deuterated isotopologues of glycolaldehyde are detected, also for the first time ever in the ISM. For the deuterated species, a D/H ratio of approximately 5% is found with no differences between the deuteration in the different functional groups of glycolaldehyde. Measurements of the 13C-species lead to a 12C:13C ratio of approximately 30, lower than the typical ISM value. This low ratio may reflect an enhancement of 13CO in the ice due to either ion-molecule reactions in the gas before freeze-out or differences in the temperatures where 12CO and 13CO ices sublimate. The results reinforce the importance of low-temperature grain surface chemistry for the formation of prebiotic molecules seen here in the gas after sublimation of the entire ice mantle.

astro-ph.SR↗

The ALMA-PILS survey: First detections of deuterated formamide and deuterated isocyanic acid in the interstellar medium

Formamide (NH$_2$CHO) has previously been detected in several star-forming regions and is thought to be a precursor for different prebiotic molecules. Its formation mechanism is still debated, however. Observations of formamide, related species and their isopotologues may provide useful clues to the chemical pathways leading to their formation. The Protostellar Interferometric Line Survey (PILS) represents an unbiased high angular resolution and sensitivity spectral survey of the low-mass protostellar binary IRAS 16293-2422 with the Atacama Large Millimeter/submillimeter Array (ALMA). We detect for the first time the three singly deuterated forms of NH$_2$CHO (NH$_2$CDO, cis- and trans-NHDCHO) as well as DNCO towards the component B of this binary source. The images reveal that the different isotopologues are all present in the same region. Based on observations of the $^{13}$C isotopologues of formamide and a standard $^{12}$C/$^{13}$C ratio, the deuterium fractionation is found to be similar for the three different forms with a value of about 2%. The DNCO/HNCO ratio is also comparable to the D/H ratio of formamide ($\sim$1%). These results are in agreement with the hypothesis that NH$_2$CHO and HNCO are chemically related through grain surface formation.

astro-ph.SR↗

Singular semipositive metrics in non-Archimedean geometry

Let X be a smooth projective Berkovich space over a complete discrete valuation field K of residue characteristic zero, endowed with an ample line bundle L. We introduce a general notion of (possibly singular) semipositive (or plurisubharmonic) metrics on L, and prove the analogue of the following two basic results in the complex case: the set of semipositive metrics is compact modulo constants, and each semipositive metric is a decreasing limit of smooth semipositive ones. In particular, for continuous metrics our definition agrees with the one by S.-W. Zhang. The proofs use multiplier ideals and the construction of suitable models of X over the valuation ring of K, using toroidal techniques.

math.AG↗

Acetone in Orion BN/KL - High-resolution maps of a special oxygen-bearing molecule

As one of the prime targets of interstellar chemistry study, Orion BN/KL clearly shows different molecular distributions between large nitrogen- (e.g., C2H5CN) and oxygen-bearing (e.g., HCOOCH3) molecules. However, acetone (CH3)2CO, a special complex O-bearing molecule, has been shown to have a very different distribution from other typical O-bearing molecules in the BN/KL region. We searched for acetone within our IRAM Plateau de Bure Interferometer 3 mm and 1.3 mm data sets. Twenty-two acetone lines were searched within these data sets. The angular resolution ranged from 1.8 X 0.8 to 6.0 X 2.3 arcsec^2, and the spectral resolution ranged from 0.4 to 1.9 km s-1. Nine of the acetone lines appear free of contamination. Three main acetone peaks (Ace-1, 2, and 3) are identified in Orion BN/KL. The new acetone source Ace-3 and the extended emission in the north of the hot core region have been found for the first time. An excitation temperature of about 150 K is determined toward Ace-1 and Ace-2, and the acetone column density is estimated to be 2-4 X 10^16 cm-2 with a relative abundance of 1-6 X 10^-8 toward these two peaks. Acetone is a few times less abundant toward the hot core and Ace-3 compared with Ace-1 and Ace-2. We find that the overall distribution of acetone in BN/KL is similar to that of N-bearing molecules, e.g., NH3 and C2H5CN, and very different from those of large O-bearing molecules, e.g., HCOOCH3 and (CH3)2O. Our findings show the acetone distribution is more extended than in previous studies and does not originate only in those areas where both N-bearing and O-bearing species are present. Moreover, because the N-bearing molecules may be associated with shocked gas in Orion BN/KL, this suggests that the formation and/or destruction of acetone may involve ammonia or large N-bearing molecules in a shocked-gas environment.

astro-ph.GA↗

CH3OCH3 in Orion-KL: a striking similarity with HCOOCH3

We used several data sets from the Plateau de Bure Interferometer to map the dimethyl ether emission in Orion-KL with different arcsec spatial resolutions and different energy levels to compare with our previous methyl formate maps. Our data show remarkable similarity between the dimethyl ether (CH3OCH3) and the methyl formate (HCOOCH3) distributions even on a small scale (1.8"x0.8" or about 500 AU). This long suspected similarity, seen from both observational and theoretical arguments, is demonstrated with unprecedented confidence, with a correlation coefficient of maps of 0.8. A common precursor is the simplest explanation of our correlation. Comparisons with previous laboratory work and chemical models suggest the major role of grain surface chemistry and a recent release, probably with little processing, of mantle molecules by shocks. In this case the CH3O radical produced from methanol ice would be the common precursor (whereas ethanol, C2H5OH, is produced from the radical CH2OH). The alternative gas phase scheme, where protonated methanol CH3OH2+ is the common precursor to produce methyl formate and dimethyl ether through reactions with HCOOH and CH3OH, is also compatible with our data. Our observations cannot yet definitely allow a choice between the different chemical processes, but the tight correlation between the distributions of HCOOCH3 and CH3OCH3 strongly contrasts with the different behavior we observe for the distributions of ethanol and formic acid. This provides a very significant constraint on models.

astro-ph.GA↗