arXiv subjects

Chanaprom Cholsuk

Publications and source records attributed to Chanaprom Cholsuk.

At least 19 recordsLinked to original sources

arXiv2026

Quantum Emitters at Telecommunication Wavelengths based on Carbon Defects in Transition Metal Dichalcogenides

Low-dimensional materials have emerged as promising hosts for quantum emitters, whose emission typically arises from either strain-induced band bending or defect-induced two-level systems. Among these materials, transition metal dichalcogenide (TMD) monolayers have attracted particular attention; however, their performance is limited by strong photoluminescence (PL) quenching at room temperature. As TMDs transition from a direct to an indirect bandgap when moving from monolayers to multilayers, we herein propose a strategy to overcome this quenching limitation by exploiting the indirect bandgap of TMD bilayers in combination with a point defect doping. The indirect gap suppresses excitonic PL, while specific defects enable robust defect-mediated quantum emission. Using hybrid-functional density functional theory, we investigate substitutional carbon defects at chalcogen sites (S and Se) in WS2, WSe2, MoS2, and MoSe2 bilayers and comprehensively characterize their optical properties. Both neutral and singly negative charge states are found to be thermodynamically stable. Neutral defects exhibit singlet configurations with emission in the O- and C-band telecommunication windows, whereas negatively charged defects adopt doublet configurations featuring spin-selective transitions and near-infrared emission. The electron-phonon coupling strength, radiative lifetime, and dipole orientation are found to depend sensitively on both the host material and defect site, providing distinct fingerprints for experimental identification. Our findings, therefore, establish carbon-doped TMD bilayers as promising platforms for room-temperature defect-based quantum emitters operating at telecommunication wavelengths.

quant-ph↗

arXiv2026

Transition Dipole Rotation Beyond the Condon Approximation in Single hBN Quantum Emitters

The design of polarization-encoded quantum interfaces relies on the assumption that solid-state emitters possess static transition dipoles defined by the host lattice symmetry. Here, we demonstrate that the transition dipole moment of single hexagonal boron nitride quantum emitters is not a static property but rotates as a function of photon energy. Through high-resolution energy-resolved spectroscopy, we reveal a continuous rotation of the emission dipole orientation reaching up to $40^{\circ}$ across the vibronic manifold at room temperature, driven by coupling to the phonon bath. This spectral rotation is effectively suppressed at cryogenic temperatures (6 K), where the acoustic phonon population is negligible, identifying thermally activated lattice vibrations as the primary driver of the reorientation. First-principles calculations on two representative defects spanning weak and strong electron-phonon coupling regimes confirm that phonon-displaced geometries produce a systematic deviation of the transition dipole orientation from the zero-phonon line, with the magnitude scaling with vibronic coupling strength. The experimental observations and calculations demonstrate that single quantum emitters can operate beyond the Condon approximation, with the transition dipole acquiring a dependence on the instantaneous nuclear configuration. Our results identify a fundamental limit for polarization fidelity in solid-state quantum networks and connect solid-state single-emitter physics to a class of effects previously accessible only in ensemble measurements in molecular and biological spectroscopy.

quant-ph↗

arXiv2025

A Decoy-like Protocol for Quantum Key Distribution: Enhancing the Performance with Imperfect Single Photon Sources

Quantum key distribution (QKD) relies on single photon sources (SPSs), e.g. from solid-state systems, as flying qubits, where security strongly requires sub-Poissonian photon statistics with low second-order correlation values (\$g^{(2)}(0)\$). However, achieving such low \$g^{(2)}(0)\$ remains experimentally challenging. We therefore propose a decoy-like QKD protocol that relaxes this constraint while maintaining security. This enables the use of many SPSs with \$g^{(2)}(0) > \$0.1, routinely achieved in experiments but rarely considered viable for QKD. Monte Carlo simulations and our experiment from defects in hexagonal boron nitride show that, under linear loss, \$g^{(2)}(0)\$ remains constant, whereas photon-number-splitting (PNS) attacks introduce nonlinear effects that modify the measured \$g^{(2)}(0)\$ statistics. Exploiting this \$g^{(2)}(0)\$ variation as a diagnostic tool, our protocol detects PNS attacks analogously to decoy-state methods. Both single- and two-photon pulses consequently securely contribute to the secret key rate. Our protocol outperforms the Gottesman--Lo--Lutkenhaus--Preskill (GLLP) framework under high channel loss across various solid-state SPSs and is applicable to the satellite-based communication. Since \$g^{(2)}(0)\$ can be extracted from standard QKD experiments, no additional hardware is required. The relaxed \$g^{(2)}(0)\$ requirement simplifies the laser system for SPS generation. This establishes a practical route toward high-performance QKD without the need for ultra-pure SPSs.

quant-ph↗

arXiv2025

Advancing the hBN Defects Database through Photophysical Characterization of Bulk hBN

Quantum emitters in hexagonal boron nitride (hBN) have gained significant attention due to a wide range of defects that offer high quantum efficiency and single-photon purity at room temperature. Most theoretical studies on hBN defects simulate monolayers, as this is computationally cheaper than calculating bulk structures. However, most experimental studies are carried out on multilayer to bulk hBN, which creates additional possibilities for discrepancies between theory and experiment. In this work, we present an extended database of hBN defects that includes a comprehensive set of bulk hBN defects along with their excited-state photophysical properties. The database features over 120 neutral defects, systematically evaluated across charge states ranging from -2 to 2 (600 defects in total). For each defect, the most stable charge and spin configurations are identified and used to compute the zero-phonon line, photoluminescence spectrum, absorption spectrum, Huang-Rhys (HR) factor, interactive radiative lifetimes, transition dipole moments, and polarization characteristics. Our analysis reveals that the electron-phonon coupling strength is primarily influenced by the presence of vacancies, which tend to induce stronger lattice distortions and broaden phonon sidebands. Additionally, correlation analysis shows that while most properties are independent, the HR factor strongly correlates with the configuration coordinates. All data are publicly available at https://h-bn.info, along with a new application programming interface (API) to facilitate integration with machine learning workflows. This database is therefore designed to bridge the gap between theory and experiment, aid in the reliable identification of quantum emitters, and support the development of machine-learning-driven approaches in quantum materials research.

quant-ph↗

arXiv2025

Nuclear Spin-Mediated Relaxation Mechanisms of the V$_{B}^-$ Center in hBN

The negatively charged boron vacancy $V_B^-$ defect in hexagonal boron nitride (hBN) has recently emerged as a promising spin qubit for sensing due to its high-temperature spin control and versatile integration into van der Waals structures. While extensive experiments have explored their coherence properties, much less is known about the spin relaxation time $T_1$ and its control-parameter dependence. In this work, we develop a parameter-free spin dynamics model based on the cluster-expansion technique to investigate $T_1$ relaxation mechanisms at low temperature. Our results reveal that the $V_B^-$ center constitutes a strongly coupled electron spin-nuclear spin core, which necessitates the inclusion of the coherent dynamics and derived memory effects of the three nearest-neighbor nitrogen nuclear spins. Using this framework, this work closely reproduces the experimentally observed $T_1$ time at $B = 90\,\mathrm{G}$ and further predicts the $T_1$ dependence on external magnetic field in the $0 \le B \le 2000\,\mathrm{G}$ interval, when the spin relaxation is predominantly driven by electron-nuclear and nuclear-nuclear flip-flop processes mediated by hyperfine and dipolar interactions. This study establishes a reliable and scalable approach for describing $T_1$ relaxation in $V_B^-$ centers and offers microscopic insights to support future developments in nuclear-spin-based quantum technologies.

quant-ph↗

arXiv2025

Temperature-Dependent Emission Spectroscopy of Quantum Emitters in Hexagonal Boron Nitride

Color centers in hexagonal boron nitride (hBN) have attracted significant interest due to their potential applications in future optical quantum technologies. For most applications, scalable on-demand fabrication is a key requirement. Recent advances using localized electron irradiation have demonstrated near-identical emitters in the blue and yellow spectral regions. While the blue emitters have been demonstrated in cryogenic temperatures, the yellow emitters remain uncharacterized under such conditions. In this work, we therefore extended the study of yellow emitters to cryogenic temperatures. Initially, multiple spectral features were observed, prompting a systematic investigation that led to the identification of a defect emission centered around 547.5 nm with high brightness and excellent photostability. By tuning the excitation wavelength, we are able to distinguish Raman scattering peaks from the emitter emission. Further analysis of the vibronic emissions allowed us to identify an optical phonon mode, whose contribution becomes increasingly dominant at elevated temperatures. Photoluminescence excitation spectroscopy (PLE) reveals excitation through this phonon mode enhances the emission by almost 5-fold in cryogenic temperature. Temperature-dependent studies further elucidate the role of phonons in the emission process. These observations deepen our understanding of the nature of the emitters, opening new avenues for precise tuning of quantum light sources.

physics.optics↗

arXiv2025

Photoluminescence-Based Gas Sensing with MoS2 Monolayers

Two-dimensional transition metal dichalcogenides (TMDs) are highly appealing for gas sensors, lab-on-a-chip devices and bio-sensing applications because of their strong light-matter interaction and high surface-to-volume ratio. The ability to grow these van der Waals materials on different substrates and waveguide geometries opens a horizon toward scalable on-chip photonic nanodevices. Here, we report on a versatile technique for real time remote optical gas sensing using two-dimensional TMDs. The adsorption of the gas molecules on the monolayer surface provides a gateway for gas sensing based on charge-transfer-induced photoluminescence variation. For gases that are weakly adsorbed on the surface of monolayer TMDs, purging the monolayers' surface by an inert gas like N2 can desorb gases from the monolayers at room temperature. We demonstrate CO, NO and NO2 detection by monitoring photoluminescence from semiconducting MoS2 monolayers grown on SiO2/Si chips at a level of 10 ppm with fast response time. Observations are supported by our density functional theory calculations, which predict a significant interaction between these gases and MoS2 monolayers. These findings may lead to advances in remote sensing, surface-sensitive bioanalytics and lab-on-a-chip sensors.

physics.app-ph↗

arXiv2025

Raman Signatures of Single Point Defects in Hexagonal Boron Nitride Quantum Emitters

Point defects in solid-state quantum systems are vital for enabling single-photon emission at specific wavelengths, making their precise identification essential for advancing applications in quantum technologies. However, pinpointing the microscopic origins of these defects remains a challenge. In this work, we propose Raman spectroscopy as a robust strategy for defect identification. Using density functional theory, we systematically characterize the Raman signatures of 100 defects in hexagonal boron nitride (hBN) spanning periodic groups III to VI, encompassing around 30,000 phonon modes. Our findings reveal that the local atomic environment plays a pivotal role in shaping the Raman lineshape, enabling the narrowing of potential defect candidates. Furthermore, we demonstrate that Raman spectroscopy can differentiate defects based on their spin and charge states as well as strain-induced variations, implying the versatility of this approach. Therefore, this study not only provides a comprehensive theoretical database of Raman spectra for hBN defects but also establishes a novel experiment framework for using tip-enhanced Raman spectroscopy to identify point defects. More broadly, our approach offers a universal method for defect identification in any quantum materials.

cond-mat.mtrl-sci↗

arXiv2024

Quantum Optics Applications of Hexagonal Boron Nitride Defects

Hexagonal boron nitride (hBN) has emerged as a compelling platform for both classical and quantum technologies. In particular, the past decade has witnessed a surge of novel ideas and developments, which may be overwhelming for newcomers to the field. This review provides an overview of the fundamental concepts and key applications of hBN, including quantum sensing, quantum key distribution, quantum computing, and quantum memory. Additionally, we highlight critical experimental and theoretical advances that have expanded the capabilities of hBN, in a cohesive and accessible manner. The objective is to equip readers with a comprehensive understanding of the diverse applications of hBN, and provide insights into ongoing research efforts.

quant-ph↗

arXiv2024

The hBN defects database: a theoretical compilation of color centers in hexagonal boron nitride

Color centers in hexagonal boron nitride (hBN) have become an intensively researched system due to their potential applications in quantum technologies. There has been a large variety of defects being fabricated, yet, for many of them, the atomic origin remains unclear. The direct imaging of the defect is technically very challenging, in particular since, in a diffraction-limited spot, there are many defects and then one has to identify the one that is optically active. Another approach is to compare the photophysical properties with theoretical simulations and identify which defect has a matching signature. It has been shown that a single property for this is insufficient and causes misassignments. Here, we publish a density functional theory (DFT)-based searchable online database covering the electronic structure of hBN defects (257 triplet and 211 singlet configurations), as well as their photophysical fingerprint (excited state lifetime, quantum efficiency, transition dipole moment and orientation, polarization visibility, and many more). All data is open-source and publicly accessible at https://h-bn.info and can be downloaded. It is possible to enter the experimentally observed defect signature and the database will output possible candidates which can be narrowed down by entering as many observed properties as possible. The database will be continuously updated with more defects and new photophysical properties (which can also be specifically requested by any users). The database therefore allows one to reliably identify defects but also investigate which defects might be promising for magnetic field sensing or quantum memory applications.

quant-ph↗

arXiv2024

Modeling the performance and bandwidth of single-atom adiabatic quantum memories

Quantum memories are essential for quantum repeaters that will form the backbone of the future quantum internet. Such memory can capture a signal state for a controllable amount of time after which this state can be retrieved. In this work, we theoretically investigated how atomic material and engineering parameters affect the performance and bandwidth of a quantum memory. We have applied a theoretical model for quantum memory operation based on the Lindblad master equation and adiabatic quantum state manipulation. The materials properties and their uncertainty are evaluated to determine the performance of Raman-type quantum memories by showcasing two defects in two-dimensional hexagonal boron nitride (hBN). We have derived a scheme to calculate the signal bandwidth based on the material parameters as well as the maximum efficiency that can be realized. The bandwidth depends on four factors: the signal photon frequency, the dipole transition moments in the electronic structure, cavity volume, and the strength of the external control electric field. As our scheme is general and independent of materials, it can be applied to many other quantum materials with a suitable three-level structure. We therefore provided a promising route for designing and selecting materials for quantum memories. Our work is therefore an important step toward the realization of a large-scale quantum network.

quant-ph↗

arXiv2024

Efficient Light Propagation Algorithm using Quantum Computers

Quantum algorithms can potentially overcome the boundary of computationally hard problems. One of the cornerstones in modern optics is the beam propagation algorithm, facilitating the calculation of how waves with a particular dispersion relation propagate in time and space. This algorithm solves the wave propagation equation by Fourier transformation, multiplication with a transfer function, and subsequent back transformation. This transfer function is determined from the respective dispersion relation, which can often be expanded as a polynomial. In the case of paraxial wave propagation in free space or picosecond pulse propagation, this expansion can be truncated after the quadratic term. The classical solution to the wave propagation requires $\mathcal{O}(N log N)$ computation steps, where $N$ is the number of points into which the wave function is discretized. Here, we show that the propagation can be performed as a quantum algorithm with $\mathcal{O}((log{}N)^2)$ single-controlled phase gates, indicating exponentially reduced computational complexity. We herein demonstrate this quantum beam propagation method (QBPM) and perform such propagation in both one- and two-dimensional systems for the double-slit experiment and Gaussian beam propagation. We highlight the importance of the selection of suitable observables to retain the quantum advantage in the face of the statistical nature of the quantum measurement process, which leads to sampling errors that do not exist in classical solutions.

quant-ph↗

arXiv2024

Comparative study of quantum emitter fabrication in wide bandgap materials using localized electron irradiation

Quantum light sources are crucial foundational components for various quantum technology applications. With the rapid development of quantum technology, there has been a growing demand for materials with the capability of hosting quantum emitters. One such material platform uses fluorescent defects in hexagonal boron nitride (hBN) that can host deep sublevels within the bandgap. The localized electron irradiation has shown its effectiveness in generating deep sublevels to induce single emitters in hBN. The question is whether localized (electron beam) irradiation is a reliable tool for creating emitters in other wide bandgap materials and its uniqueness to hBN. Here, we investigate and compare the fabrication of quantum emitters in hBN and exfoliated muscovite mica flakes along with other 3D crystals, such as silicon carbide and gallium nitride, which are known to host quantum emitters. We used our primary fabrication technique of localized electron irradiation using a standard scanning electron microscope. To complement our experimental work, we employed density functional theory simulations to study the atomic structures of defects in mica. While our fabrication technique allows one to create hBN quantum emitters with a high yield and high single photon purity, it is unable to fabricate single emitters in the other solid-state crystals under investigation. This allows us to draw conclusions on the emitter fabrication mechanism in hBN, which could rely on activating pre-existing defects by charge state manipulation. Therefore, we provide an essential step toward the identification of hBN emitters and their formation process.

physics.app-ph↗

arXiv2024

Polarization dynamics of solid-state quantum emitters

Quantum emitters in solid-state crystals have recently attracted a lot of attention due to their simple applicability in optical quantum technologies. The polarization of single photons generated by quantum emitters is one of the key parameters that play a crucial role in the applications, such as quantum computation that uses the indistinguishability of photons. However, the degree of single photon polarization is typically quantified using time-averaged photoluminescence intensity of single emitters, which provides limited information about the dipole properties in solids. In this work, we use single defects in hexagonal boron nitride and nanodiamond as efficient room-temperature single photon sources to reveal the origin and the temporal evolution of dipole orientation in solid-state quantum emitters. The angle of excitation and emission dipoles relative to the crystal axes are determined experimentally and then calculated using density functional theory, which results in characteristic angles for every specific defect that can be used as an efficient tool for defect identification and understanding their atomic structure. Moreover, the temporal polarization dynamics reveal a strongly modified linear polarization visibility that depends on the excited state decay time of individual excitation. This effect can be traced back potentially to the excitation of excess charges in the local crystal environment. Understanding such hidden time-dependent mechanisms can further be used to improve the performance of polarization-sensitive experiments, in particular that of quantum communication with single photon emitters.

quant-ph↗

arXiv2024

Identifying electronic transitions of defects in hexagonal boron nitride for quantum memories

A quantum memory is a crucial keystone for enabling large-scale quantum networks. Applicable to the practical implementation, specific properties, i.e., long storage time, selective efficient coupling with other systems, and a high memory efficiency are desirable. Though many quantum memory systems are developed thus far, none of them can perfectly meet all requirements. This work herein proposes a quantum memory based on color centers in hexagonal boron nitride (hBN), where its performance is evaluated based on a simple theoretical model of suitable defects in a cavity. Employing density functional theory calculations, 257 triplet and 211 singlet spin electronic transitions are investigated. Among these defects, it is found that some defects inherit the $Λ$ electronic structures desirable for a Raman-type quantum memory and optical transitions can couple with other quantum systems. Further, the required quality factor and bandwidth are examined for each defect to achieve a 95% writing efficiency. Both parameters are influenced by the radiative transition rate in the defect state. In addition, inheriting triplet-singlet spin multiplicity indicates the possibility of being a quantum sensing, in particular, optically detected magnetic resonance. This work therefore demonstrates the potential usage of hBN defects as a quantum memory in future quantum networks.

quant-ph↗

arXiv2023

The ideal wavelength for daylight free-space quantum key distribution

Quantum key distribution (QKD) has matured in recent years from laboratory proof-of-principle demonstrations to commercially available systems. One of the major bottlenecks is the limited communication distance in fiber networks due to the exponential signal damping. To bridge intercontinental distances, low Earth orbit satellites transmitting the quantum signals over the atmosphere can be used. These free-space links, however, can only operate during the night, as the sunlight otherwise saturates the detectors used to measure the quantum states. For applying QKD in a global quantum internet with continuous availability and high data rates, operation during daylight is required. In this work, we model a satellite-to-ground quantum channel for different quantum light sources to identify the optimal wavelength for free-space QKD in ambient conditions. Daylight quantum communication is possible within the Fraunhofer lines or in the near-infrared spectrum, where the intrinsic background from the sun is comparably low. The highest annual secret key length considering the finite key effect is achievable at the H\textalpha\ Fraunhofer line. More importantly, we provide the full model that can be adapted in general to any other specific link scenario. We also propose a true single-photon source based on a color center in hexagonal boron nitride coupled to a microresonator that can implement such a scheme. Our results can also be applied in roof-to-roof scenarios and are therefore relevant for near-future quantum networks.

quant-ph↗

arXiv2023

Comprehensive scheme for identifying defects in solid-state quantum systems

A solid-state quantum emitter is one of the indispensable components for optical quantum technologies. Ideally, an emitter should have a compatible wavelength for efficient coupling to other components in a quantum network. It is therefore essential to understand fluorescent defects that lead to specific emitters. In this work, we employ density functional theory (DFT) to demonstrate the calculation of the complete optical fingerprints of quantum emitters in the two-dimensional material hexagonal boron nitride. These emitters are of great interest, yet many of them are still to be identified. Our results suggest that instead of comparing a single optical property, such as the commonly used zero-phonon line energy, multiple properties should be used when comparing theoretical simulations to the experiment. This way, the entire electronic structure can be predicted and quantum emitters can be designed and tailored. Moreover, we apply this approach to predict the suitability for using the emitters in specific quantum applications, demonstrating through the examples of the Al$_{\text{N}}$ and P$_{\text{N}}$V$_{\text{B}}$ defects. We therefore combine and apply DFT calculations to identify quantum emitters in solid-state crystals with a lower risk of misassignments as well as a way to design and tailor optical quantum systems. This consequently serves as a recipe for classification and the generation of universal solid-state quantum emitter systems in future hybrid quantum networks.

quant-ph↗

arXiv2023

Localized creation of yellow single photon emitting carbon complexes in hexagonal boron nitride

Single photon emitters in solid-state crystals have received a lot of attention as building blocks for numerous quantum technology applications. Fluorescent defects in hexagonal boron nitride (hBN) stand out due to their high luminosity and robust operation at room temperature. The identical emitter fabrication at pre-defined sites is still challenging, which hampers the integration of these defects in optical systems and electro-optical devices. Here, we demonstrate the localized fabrication of hBN emitter arrays by electron beam irradiation using a standard scanning electron microscope with deep sub-micron lateral precision. The emitters are created with a high yield and a reproducible spectrum peaking at 575 nm. Our measurements of optically detected magnetic resonance have not revealed any addressable spin states. Using density functional theory, we attribute the experimentally observed emission lines to carbon-related defects, which are activated by the electron beam. Our scalable approach provides a promising pathway for fabricating room temperature single photon emitters in integrated quantum devices.

quant-ph↗