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Chien-Lung Huang

Publications and source records attributed to Chien-Lung Huang.

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Crystal electric field excitations and an effective-spin-$1/2$ ground doublet in the hyperkagome magnet Yb$_3$Sc$_2$Ga$_3$O$_{12}$

We use inelastic neutron scattering (INS) to determine the crystal electric field (CEF) excitations of Yb$^{3+}$ in the rare-earth hyperkagome magnet Yb$_3$Sc$_2$Ga$_3$O$_{12}$. Three nearly dispersionless magnetic excitations are observed near 58, 68, and 74~meV, corresponding to transitions from the ground-state Kramers doublet to the three excited doublets of the $J=7/2$ multiplet. A Stevens-operator analysis constrained by the local $222$ ($D_2$) symmetry reproduces the excitation energies and spectral weights and yields an Ising-type ground-state $g$ tensor. The first excited doublet lies approximately 58~meV above the ground state, establishing a well-isolated effective $J_{\mathrm{eff}}=1/2$ degree of freedom over the low-temperature regime relevant to collective magnetism. Notably, the directly measured CEF spectrum substantially revises the level scheme previously inferred from bulk measurements, while preserving the essential low-energy pseudospin description. Two independent fitting protocols give consistent excitation energies, ground-doublet wave functions, and $g$ tensors, despite the nonuniqueness of the individual CEF parameters. The resulting single-ion model also reproduces the characteristic susceptibility, magnetization, and field evolution of the Schottky anomaly in specific heat. These results establish the microscopic single-ion basis needed to construct an effective exchange Hamiltonian and to interpret future measurements of low-energy collective excitations in Yb$_3$Sc$_2$Ga$_3$O$_{12}$.

cond-mat.str-el

Field-induced first order transitions and phase coexistence in the Kitaev quantum spin liquid candidate BaCo2(AsO4)2

BaCo2(AsO4)2 (BCAO) is an insulating Kitaev quantum spin liquid candidate with a rich low-temperature phase diagram. Below 5 K, it exhibits double-zigzag magnetic order. Upon application of an in-plane magnetic field, the magnetic structure first transforms into an up-up-down (UUD) state near 0.12 T and then enters a fully spin-polarized ferromagnetic (FM) state near 0.5 T. In the narrow field regime close to the polarized phase, a finite residual thermal conductivity has been reported, suggesting a possible field-induced quantum spin liquid phase. Using neutron scattering, we show that the field-induced double-zigzag-to-UUD transition near 0.15 T is accompanied by the emergence of a cluster of localized UUD spin excitations that coexist with conventional spin waves. Upon further increasing field, BCAO undergoes a first-order UUD-to-FM transition with coexistence of UUD and FM phases, accompanied by a sharp response in the spin Seebeck coefficient. These results do not support a quantum spin liquid scenario near the UUD-to-FM critical field. Instead, modeling indicates that the broad excitations arise from bound spin-flip pairs, while a low-lying dispersive branch near the FM phase boundary carries the same sign of magnetization as the FM order. These excitations naturally account for the observed sign of the spin Seebeck response and are likely relevant to the thermal conductivity near the critical field.

cond-mat.str-el

Anomalous Electrical Transport in the Kagome Magnet YbFe$_6$Ge$_6$

Two-dimensional (2D) kagome metals offer a unique platform for exploring electron correlation phenomena derived from quantum many-body effects. Here, we report a combined study of electrical magnetotransport and neutron scattering on YbFe$_6$Ge$_6$, where the Fe moments in the 2D kagome layers exhibit an $A$-type collinear antiferromagnetic order below $T_{\rm{N}} \approx 500$ K. Interactions between the Fe ions in the layers and the localized Yb magnetic ions in between reorient the $c$-axis aligned Fe moments to the kagome plane below $T_{\rm{SR}} \approx 63$ K. Our magnetotransport measurements show an intriguing anomalous Hall effect (AHE) that emerges in the spin-reorientated collinear state, accompanied by the closing of the spin anisotropy gap as revealed from inelastic neutron scattering. The gapless spin excitations and the Yb-Fe interaction are able to support a dynamic scalar spin chirality, which explains the observed AHE. Therefore, our study demonstrates spin fluctuations may provide an additional scattering channel for the conduction electrons and give rise to AHE even in a collinear antiferromagnet.

cond-mat.str-el

Vacancy-induced suppression of CDW order and its impact on magnetic order in kagome antiferromagnet FeGe

Two-dimensional (2D) kagome lattice metals are interesting because they display flat electronic bands, Dirac points, Van Hove singularities, and can have interplay between charge density wave (CDW), magnetic order, and superconductivity. In kagome lattice antiferromagnet FeGe, a short-range CDW order was found deep within an antiferromagnetically ordered state, interacting with the magnetic order. Surprisingly, post-growth annealing of FeGe at 560$^{\circ}$C can suppress the CDW order while annealing at 320$^{\circ}$C induces a long-range CDW order, with the ability to cycle between the states repeatedly by annealing. Here we perform transport, neutron scattering, scanning transmission electron microscopy (STEM), and muon spin rotation ($μ$SR) experiments to unveil the microscopic mechanism of the annealing process and its impact on magneto-transport, CDW, and magnetic properties of FeGe. We find that 560$^{\circ}$C annealing creates germanium vacancies uniformly distributed throughout the FeGe kagome lattice, which prevent the formation of Ge-Ge dimers necessary for the CDW order. Upon annealing at 320$^{\circ}$C, the system segregates into stoichiometric FeGe regions with long-range CDW order and regions with stacking faults that act as nucleation sites for the CDW. The presence or absence of CDW order greatly affects the anomalous Hall effect, incommensurate magnetic order, and spin-lattice coupling in FeGe, thus placing FeGe as the only known kagome lattice material with a tunable CDW and magnetic order, potentially useful for sensing and information transmission.

cond-mat.str-el

Quantum Simulation of an Extended Dicke Model with a Magnetic Solid

The Dicke model describes the cooperative interaction of an ensemble of two-level atoms with a single-mode photonic field and exhibits a quantum phase transition as a function of light--matter coupling strength. Extending this model by incorporating short-range atom--atom interactions makes the problem intractable but is expected to produce new phases. Here, we simulate such an extended Dicke model using a crystal of ErFeO$_3$, where the role of atoms (photons) is played by Er$^{3+}$ spins (Fe$^{3+}$ magnons). Through magnetocaloric effect and terahertz magnetospectroscopy measurements, we demonstrated the existence of a novel atomically ordered phase in addition to the superradiant and normal phases that are expected from the standard Dicke model. Further, we elucidated the nature of the phase boundaries in the temperature--magnetic-field phase diagram, identifying both first-order and second-order phase transitions. These results lay the foundation for studying multiatomic quantum optics models using well-characterized many-body condensed matter systems.

quant-ph

Disorder-induced excitation continuum in a spin-1/2 cobaltate on a triangular lattice

A spin-1/2 triangular-lattice antiferromagnet is a prototypical frustrated quantum magnet, which exhibits remarkable quantum many-body effects that arise from the synergy between geometric spin frustration and quantum fluctuations. It can host quantum frustrated magnetic topological phenomena like quantum spin liquid (QSL) states, highlighted by the presence of fractionalized quasiparticles within a continuum of magnetic excitations. In this work, we use neutron scattering to study CoZnMo$_3$O$_8$, which has a triangular lattice of Jeff = 1/2 Co2+ ions with octahedral coordination. We found a wave-vector-dependent excitation continuum at low energy that disappears with increasing temperature. Although these excitations are reminiscent of a spin excitation continuum in a QSL state, their presence in CoZnMo$_3$O$_8$ originates from magnetic intersite disorder-induced dynamic spin states with peculiar excitations. Our results, therefore, give direct experimental evidence for the presence of a disorder-induced spin excitation continuum.

cond-mat.str-el

Diffusive Excitonic Bands from Frustrated Triangular Sublattice in a Singlet-Ground-State System

Magnetic order in most materials occurs when magnetic ions with finite moments in a crystalline lattice arrange in a particular pattern below the ordering temperature determined by exchange interactions between the ions. However, when the crystal electric field (CEF) effect results in a spin-singlet ground state on individual magnetic sites, the collective ground state of the system can either remain non-magnetic, or more intriguingly, the exchange interactions between neighboring ions, provided they are sufficiently strong, can admix the excited CEF levels, resulting in a magnetically ordered ground state. The collective magnetic excitations in such a state are so-called spin excitons that describe the CEF transitions propagating through the lattice. In most cases, spin excitons originating from CEF levels of a localized single ion are dispersion-less in momentum (reciprocal) space and well-defined in both the magnetically ordered and paramagnetic states. Here we use thermodynamic and neutron scattering experiments to study stoichiometric Ni2Mo3O8 without site disorder, where Ni2+ ions form a bipartite honeycomb lattice comprised of two triangular lattices, with ions subject to the tetrahedral and octahedral crystalline environment, respectively. We find that in both types of ions, the CEF excitations have nonmagnetic singlet ground states, yet the material has long-range magnetic order. Furthermore, CEF spin excitons from the triangular-lattice arrangement of tetrahedral sites form, in both the antiferromagnetic and paramagnetic states, a dispersive diffusive pattern around the Brillouin zone boundary in reciprocal space. The present work thus demonstrates that spin excitons in an ideal triangular lattice magnet can have dispersive excitations, irrespective of the existence of static magnetic order, and this phenomenon is most likely due to spin entanglement and geometric frustrations.

cond-mat.str-el

Magnetic field effects in an octupolar quantum spin liquid candidate

Quantum spin liquid (QSL) is a disordered state of quantum-mechanically entangled spins commonly arising from frustrated magnetic dipolar interactions. However, QSL in some pyrochlore magnets can also come from frustrated magnetic octupolar interactions. Although the key signature for both dipolar and octupolar interaction-driven QSL is the presence of a spin excitation continuum (spinons) arising from the spin quantum number fractionalization, an external magnetic field-induced ferromagnetic order will transform the spinons into conventional spin waves in a dipolar QSL. By contrast, in an octupole QSL, the spin waves carry octupole moments that do not couple, in the leading order, to the external magnetic field or to neutron moments but will contribute to the field dependence of the heat capacity. Here we use neutron scattering to show that the application of a large external magnetic field to Ce2Zr2O7, an octupolar QSL candidate, induces an Anderson-Higgs transition by condensing the spinons into a static ferromagnetic ordered state with octupolar spin waves invisible to neutrons but contributing to the heat capacity. Our theoretical calculations also provide a microscopic, qualitative understanding for the presence of octupole scattering at large wavevectors in Ce2Sn2O7 pyrochlore, and its absence in Ce2Zr2O7. Therefore, our results identify Ce2Zr2O7 as a strong candidate for an octupolar U (1) QSL, establishing that frustrated magnetic octupolar interactions are responsible for QSL properties in Ce-based pyrochlore magnets.

cond-mat.str-el

Hyperscaling analysis of a disorder-induced ferromagnetic quantum critical point in Ni$_{1-x}$Rh$_{x}$ with $x = 0.375$

Here we report on hyperscaling analysis on thermodynamic measurements as a function of temperature and magnetic field for Ni$_{1-x}$Rh$_{x}$ with $x = 0.375$ where a ferromagnetic quantum critical point has been recently identified [Phys. Rev. Lett. $\textbf{124}$, 117203 (2020)]. The obtained critical exponents agree well with the theory proposed by Belitz, Kirkpatrick, and Vojta for disorder tuned quantum critical point in the preasymptotic region.

cond-mat.str-el

Spinon Fermi surface spin liquid in a triangular lattice antiferromagnet NaYbSe$_2$

Triangular lattice of rare-earth ions with interacting effective spin-$1/2$ local moments is an ideal platform to explore the physics of quantum spin liquids (QSLs) in the presence of strong spin-orbit coupling, crystal electric fields, and geometrical frustration. The Yb delafossites, NaYbCh$_2$ (Ch=O, S, Se) with Yb ions forming a perfect triangular lattice, have been suggested to be candidates for QSLs. Previous thermodynamics, nuclear magnetic resonance, and muon spin rotation measurements on NaYbCh$_2$ have supported the suggestion of the QSL ground states. The key signature of a QSL, the spin excitation continuum, arising from the spin quantum number fractionalization, has not been observed. Here we perform both elastic and inelastic neutron scattering measurements as well as detailed thermodynamic measurements on high-quality single-crystalline NaYbSe$_2$ samples to confirm the absence of long-range magnetic order down to 40 mK, and further reveal a clear signature of magnetic excitation continuum extending from 0.1 to 2.5 meV. The comparison between the structure of the magnetic excitation spectra and the theoretical expectation from the spinon continuum suggests that the ground state of NaYbSe$_2$ is a QSL with a spinon Fermi surface.

cond-mat.str-el

Metal-to-insulator transition in Pt-doped TiSe$_2$ driven by emergent network of narrow transport channels

Metal-to-insulator transitions (MIT) can be driven by a number of different mechanisms, each resulting in a different type of insulator -- Change in chemical potential can induce a transition from a metal to a band insulator; strong correlations can drive a metal into a Mott insulator with an energy gap; an Anderson transition, on the other hand, due to disorder leads to a localized insulator without a gap in the spectrum. Here we report the discovery of an alternative route for MIT driven by the creation of a network of narrow channels. Transport data on Pt substituted for Ti in TiSe$_2$ shows a dramatic increase of resistivity by five orders of magnitude for few % of Pt substitution, with a power-law dependence of the temperature-dependent resistivity $ρ(T)$. Our scanning tunneling microscopy data show that Pt induces an irregular network of nanometer-thick domain walls (DWs) of charge density wave (CDW) order, which pull charge carriers out of the bulk and into the DWs. While the CDW domains are gapped, the charges confined to the narrow DWs interact strongly, with pseudogap-like suppression in the local density of states, even when they were weakly interacting in the bulk, and scatter at the DW network interconnects thereby generating the highly resistive state. Angle-resolved photoemission spectroscopy spectra exhibit pseudogap behavior corroborating the spatial coexistence of gapped domains and narrow domain walls with excess charge carriers.

cond-mat.str-el

Experimental signatures of a three-dimensional quantum spin liquid in effective spin-1/2 Ce2Zr2O7 pyrochlore

A quantum spin liquid (QSL) is a state of matter where unpaired electrons' spins in a solid are quantum entangled, but do not show magnetic order in the zero-temperature limit. Because such a state may be important to the microscopic origin of high-transition temperature superconductivity and useful for quantum computation, the experimental realization of QSL is a long-sought goal in condensed matter physics. Although neutron scattering experiments on the two-dimensional (2D) spin-1/2 kagome-lattice ZnCu3(OD)6Cl2 and effective spin-1/2 triangular lattice YbMgGaO4 have found evidence for a continuum of magnetic excitations, the hallmark of a QSL carrying 'fractionalized quantum excitations', at very low temperature, magnetic and nonmagnetic site chemical disorder complicates the interpretation of the data. Recently, the three-dimensional (3D) Ce3+ pyrochlore lattice Ce2Sn2O7 has been suggested as a clean, effective spin-1/2 QSL candidate, but there is no evidence of a spin excitation continuum. Here we use thermodynamic, muon spin relaxation (μ SR), and neutron scattering experiments on single crystals of Ce2Zr2O7, a compound isostructural to Ce2Sn2O7, to demonstrate the absence of magnetic ordering and the presence of a spin excitation continuum at 35 mK, consistent with the expectation of a QSL. Since our neutron diffraction and diffuse scattering measurements on Ce2Zr2O7 reveal no evidence of oxygen deficiency and magnetic/nonmagnetic ion disorder as seen in other pyrochlores, Ce2Zr2O7 may be the first example of a 3D QSL material with minimum magnetic and nonmagnetic chemical disorder.

cond-mat.str-el

Influence of disorder on the signature of pseudogap and multigap superconducting behavior in FeSe

We investigated several FeSe single crystals grown by two different methods by utilizing experimental techniques namely, resistivity, magnetoresistance, specific heat, scanning tunneling microscopy, and spectroscopy. The residual resistivity ratio (RRR) shows systematic differences between samples grown by chemical vapor transport and flux vapor transport, indicating variance in the amount of scattering centers. Although the superconducting transition temperature $T_c$ is not directly related to RRR, our study evidences subtle differences in the features of an incipient ordering mode related to a depletion of density of states at the Fermi level. For instance, the onset temperature of anisotropic spin-fluctuations at $T^* \approx 75$ K, and the temperature of the opening-up of a partial gap in the density of states at $T^{**} \approx 30$ K are not discernible in the samples with lower RRR. Further, we show that the functional dependence of the electronic specific heat below 2 K, which allows to determine the nodal features as well as the small superconducting gap, differs significantly in crystals grown by these two different methods. Our investigation suggests that some of the controversies about the driving mechanism for the superconducting gap or its structure and symmetry is related to minute differences in the crystals arising due to the growth techniques used and the total amount of scattering centers present in the sample.

cond-mat.supr-con

Superconducting gap structure of FeSe

The microscopic mechanism governing the zero-resistance flow of current in some iron-based, high-temperature superconducting materials is not well understood up to now. A central issue concerning the investigation of these materials is their superconducting gap symmetry and structure. Here we present a combined study of low-temperature specific heat and scanning tunnelling microscopy measurements on single crystalline FeSe. The results reveal the existence of at least two superconducting gaps which can be represented by a phenomenological two-band model. The analysis of the specific heat suggests significant anisotropy in the gap magnitude with deep gap minima. The tunneling spectra display an overall "U"-shaped gap close to the Fermi level away as well as on top of twin boundaries. These results are compatible with the anisotropic nodeless models describing superconductivity in FeSe.

cond-mat.supr-con

Entropy evolution in the magnetic phases of partially frustrated CePdAl

In the heavy-fermion metal CePdAl long-range antiferromagnetic order coexists with geometric frustration of one third of the Ce moments. At low temperatures the Kondo effect tends to screen the frustrated moments. We use magnetic fields $B$ to suppress the Kondo screening and study the magnetic phase diagram and the evolution of the entropy with $B$ employing thermodynamic probes. We estimate the frustration by introducing a definition of the frustration parameter based on the enhanced entropy, a fundamental feature of frustrated systems. In the field range where the Kondo screening is suppressed the liberated moments tend to maximize the magnetic entropy and strongly enhance the frustration. Based on our experiments, this field range may be a promising candidate to search for a quantum spin liquid.

cond-mat.str-el